|
|
geranyl_diphosphate + umbelliferone <=> diphosphate + 8-geranylumbelliferone
|
2.5.1.138
coumarin 8-geranyltransferase
|
–
|
|
|
BRENDA:
BR51971
KEGG:
R11602
MetaCyc:
RXN-18495
|
|
|
|
dimethylallyl_diphosphate + umbelliferone <=> diphosphate + demethylsuberosin
|
2.5.1.139
umbelliferone 6-dimethylallyltransferase
|
–
|
M
|
|
BRENDA:
BR51973
KEGG:
R08996
MetaCyc:
RXN-8382
|
|
|
|
dimethylallyl_diphosphate + umbelliferone <=> diphosphate + osthenol
|
2.5.1.139
umbelliferone 6-dimethylallyltransferase
|
–
|
|
|
BRENDA:
BS439503
MetaCyc:
RXN-18497
|
|
|
|
2,4-dihydroxycinnamoyl-CoA <=> umbelliferone + CoA
|
not assigned
|
–
|
MK
|
|
KEGG:
R12310
MetaCyc:
RXN-12965
|
|
|
|
umbelliferone <=> esculetin
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-14165
|
|
|
|
(Z)-3-(2,4-dihydroxyphenyl)-prop-2-enoate <=> umbelliferone
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-14168
|
|
|
|
UDP-glucuronate + umbelliferone <=> UDP + umbelliferone_beta-D-glucuronide
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
|
BRENDA:
BS378170
|
|
|
|
umbelliferone + UDP-glucuronate <=> UDP + coumarin-7-yl-alpha-D-glucuronide
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
|
BRENDA:
BS387660
|
|
|
|
UDP-glucuronate + umbelliferone <=> UDP + umbelliferyl_beta-D-glucuronoside
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
|
BRENDA:
BS402161
|
|
|
|
7-hydroxycoumarinyl_arachidonate <=> arachidonic_acid + umbelliferone
|
3.1.1.23
acylglycerol lipase
|
–
|
|
|
BRENDA:
BS411417
|
|
|
|
UDP-glucose + umbelliferone <=> UDP + eugenyl_beta-D-glucoside
|
2.4.1.218
hydroquinone glucosyltransferase
|
–
|
|
|
BRENDA:
BS378062
|
|
|
|
UDP-glucose + umbelliferone <=> UDP + skimmin
|
2.4.1.104
o-dihydroxycoumarin 7-O-glucosyltransferase
2.4.1.218
hydroquinone glucosyltransferase
2.4.1.35
phenol beta-glucosyltransferase
2.4.1.358
acylphloroglucinol glucosyltransferase
2.4.1.91
flavonol 3-O-glucosyltransferase
|
–
–
–
–
–
|
|
|
BRENDA:
BS259646
|
|
|
|
UDP-glucose + coumarin <=> UDP + umbelliferone
|
2.4.1.104
o-dihydroxycoumarin 7-O-glucosyltransferase
|
–
|
|
|
BRENDA:
BS321951
|
|
|
|
3''-phosphoadenylyl_sulfate + umbelliferone <=> adenosine_3'',5''-bisphosphate + 7-hydroxycoumarin_sulfate
|
2.8.2.1
aryl sulfotransferase
|
–
|
|
|
BRENDA:
BS387258
|
|
|
|
O2 + NADPH + coumarin + H+ <=> NADP+ + umbelliferone + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
SABIO-RK:
6737
|
|
|
|
H+ + O2 + 4-Methylumbelliferone + NADPH <=> NADP+ + formaldehyde + umbelliferone + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
SABIO-RK:
6728
|
|
|
|
NADPH + H+ + O2 + 4-Methylumbelliferone <=> NADP+ + umbelliferone + H2O + acetaldehyde
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
|
SABIO-RK:
6726
|
|