|
|
hexacosanoyl-CoA + phytosphingosine <=> C26:0_phytoceramide + CoA + H+
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS435520
MetaCyc:
RXN-20398
|
|
|
|
hexacosanoyl-CoA + NADP+ <=> trans-cerot-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
M
|
|
MetaCyc:
RXN-13309
|
|
|
|
malonyl-CoA + hexacosanoyl-CoA + H+ <=> 3-oxooctacosanoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
M
|
|
MetaCyc:
RXN-20332
|
|
|
|
hexacosanoyl-CoA + sphinganine <=> N-hexacosanoylsphinganine + CoA + H+
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
MetaCyc:
RXN-20372
|
|
|
|
ATP + hexacosanoyl-CoA + HCO3- <=> 2-carboxycerotoyl-CoA + ADP + phosphate + H+
|
6.4.1.3
propionyl-CoA carboxylase
|
–
|
M
|
|
MetaCyc:
RXN1G-4355
|
|
|
|
cerotoyl-[acp_domain_within_a_fatty_acid_synthase] + CoA <=> hexacosanoyl-CoA + [acyl_carrier_protein]_domain_within_a_fatty_acid_synthase
|
2.3.1.86
fatty-acyl-CoA synthase system
|
–
|
M
|
|
MetaCyc:
RXN1G-536
|
|
|
|
sphinganine + hexacosanoyl-CoA <=> N-cerotoyl-D-sphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448544
|
|
|
|
hexacosanoyl-CoA + sphinganine <=> CoA + N-cerotoyl-dihydrosphingosine
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449745
|
|
|
|
sphinganine + hexacosanoyl-CoA <=> N-cerotoylsphinganine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS448950
|
|
|
|
hexacosanoyl-CoA + sphinganine <=> N-cerotoyl-D-erythro-sphingosine + CoA
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS450042
|
|
|
|
hexacosanoyl-CoA + NADH + H+ <=> hexacosanal + CoA + NAD+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS426478-a
|
|
|
|
sphingosine + hexacosanoyl-CoA <=> N-cerotoylsphingosine + CoA
|
2.3.1.297
very-long-chain ceramide synthase
2.3.1.298
ultra-long-chain ceramide synthase
|
–
–
|
|
|
BRENDA:
BS448958
|
|
|
|
sphingosine + hexacosanoyl-CoA <=> N-hexacosanoylsphingosine + CoA
|
2.3.1.24
sphingosine N-acyltransferase
2.3.1.297
very-long-chain ceramide synthase
|
–
–
|
|
|
BRENDA:
BS450650
|
|
|
|
hexacosanoyl-CoA + sphingosine <=> N-cerotoyl-D-erythro-sphingosine + CoA
|
2.3.1.298
ultra-long-chain ceramide synthase
|
–
|
|
|
BRENDA:
BS449746
|
|
|
|
hexacosanoyl-CoA + NADPH + H+ <=> hexacosanal + CoA + NADP+
|
1.2.1.80
long-chain acyl-[acyl-carrier-protein] reductase
|
–
|
|
|
BRENDA:
BS426478
|
|
|
|
hexacosanoyl-CoA + 2 NADPH + 2 H+ <=> hexacosanoyl_alcohol + 2 NADP+ + CoA
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
|
|
BRENDA:
BS440266
|
|
|
|
ATP + cerotic_acid + CoA <=> AMP + diphosphate + hexacosanoyl-CoA
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
|
|
BRENDA:
BS428251
|
|
|
|
H2O + hexacosanoyl-CoA <=> CoA + cerotic_acid
|
3.1.2.2
palmitoyl-CoA hydrolase
|
–
|
|
|
SABIO-RK:
6592
|
|