|
|
2-oxoglutarate + D-4-hydroxyphenylglycine <=> L-glutamate + 4-hydroxyphenylglyoxylate
|
2.6.1.72
D-4-hydroxyphenylglycine transaminase
|
–
|
|
|
BRENDA:
BR47429
KEGG:
R04234
MetaCyc:
2.6.1.72-RXN
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + O2 <=> 4-hydroxyphenylglyoxylate + H2O2
|
1.1.3.46
4-hydroxymandelate oxidase
|
–
|
K
|
|
BRENDA:
BR50849
KEGG:
R06633
MetaCyc:
RXN-15300
|
|
|
|
4-hydroxyphenylglyoxylate + L-tyrosine <=> L-4-hydroxyphenylglycine + 4-hydroxyphenylpyruvate
|
2.6.1.103
(S)-3,5-dihydroxyphenylglycine transaminase
2.6.1.B17
|
–
–
|
K
|
|
BRENDA:
BR52009
KEGG:
R06626
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + acceptor <=> 4-hydroxyphenylglyoxylate + reduced_acceptor
|
1.1.99.31
(S)-mandelate dehydrogenase
1.1.99.B9
|
–
–
|
K
|
|
BRENDA:
BS438524
KEGG:
R04160
|
|
|
|
H+ + 4-hydroxyphenylglyoxylate <=> 4-hydroxybenzaldehyde + CO2
|
4.1.1.7
benzoylformate decarboxylase
|
–
|
MK
|
|
KEGG:
R02672
MetaCyc:
HYDROXYBENZOYLFORMATE-DECARBOXYLASE-RXN
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + electron-transfer_quinone <=> 4-hydroxyphenylglyoxylate + electron-transfer_quinol
|
1.1.5
|
–
|
M
|
|
MetaCyc:
4-HYDROXYMANDELATE-OXY-RXN
|
|
|
|
4-hydroxymandelate + ferricyanide <=> 4-hydroxyphenylglyoxylate + ferrocyanide + H2O
|
1.1.99.31
(S)-mandelate dehydrogenase
|
–
|
|
|
BRENDA:
BS383898
|
|
|
|
4-hydroxyphenylglyoxylate + 3-chloro-L-tyrosine <=> L-4-hydroxyphenylglycine + 3-chloro-4-hydroxyphenylpyruvate
|
2.6.1.B17
|
–
|
|
|
BRENDA:
BS436903
|
|
|
|
4-hydroxyphenylglyoxylate + L-phenylalanine <=> L-4-hydroxyphenylglycine + phenylpyruvate
|
2.6.1.B17
|
–
|
|
|
BRENDA:
BS436904
|
|