|
|
(S)-2-methylbutanoyl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
–
|
K
|
|
BRENDA:
BS258775
KEGG:
R03172
|
|
|
|
(S)-3-methyl-2-oxopentanoate + NAD+ + CoA <=> (S)-2-methylbutanoyl-CoA + NADH + CO2
|
1.2.1.25
branched-chain alpha-keto acid dehydrogenase system
|
–
|
M
|
|
KEGG:
R03171
MetaCyc:
2KETO-3METHYLVALERATE-RXN
|
|
|
|
(S)-3-methyl-2-oxopentanoate + CoA + oxidized_ferredoxin <=> (S)-2-methylbutanoyl-CoA + CO2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+
|
1.2.7.7
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin)
|
–
|
MK
|
|
KEGG:
R08567
MetaCyc:
RXN-19503
|
|
|
|
(S)-2-methylbutanoyl-CoA + enzyme_N6-(dihydrolipoyl)lysine <=> CoA + [dihydrolipoyllysine-residue_(2-methylpropanoyl)transferase]_S-(2-methylbutanoyl)dihydrolipoyllysine
|
2.3.1.168
dihydrolipoyllysine-residue (2-methylpropanoyl)transferase
|
–
|
K
|
|
KEGG:
R03174
|
|
|
|
(S)-2-methylbutanoyl-CoA <=> Branched_chain_fatty_acid
|
not assigned
|
–
|
K
|
|
KEGG:
R03175
|
|
|
|
(S)-2-methylbutanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> tigloyl-CoA + reduced_flavodoxin
|
1.3.8.5
2-methyl-branched-chain-enoyl-CoA reductase
|
–
|
M
|
|
MetaCyc:
2-METHYLACYL-COA-DEHYDROGENASE-RXN
|
|
|
|
(S)-2-methylbutanoyl-CoA + [apo_BCAA_dehydrogenase_E2_protein]_N6-dihydrolipoyl-L-lysine <=> [apo_BCAA_dehydrogenase_E2_protein]_N6-S-[2-methylbutanoyl]dihydrolipoyl-L-lysine + CoA
|
2.3.1.168
dihydrolipoyllysine-residue (2-methylpropanoyl)transferase
|
–
|
|
|
MetaCyc:
MBCOA-DHLIPOAMIDE-RXN
|
|
|
|
(S)-2-methylbutanoyl-CoA + H2O <=> 2-methylbutanoate + CoA + H+
|
3.1.2
|
–
|
M
|
|
MetaCyc:
RXN-15031
|
|
|
|
(S)-2-methylbutanoyl-CoA + acceptor <=> 2-methyl-3-butenoyl-CoA + reduced_acceptor
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-17596
|
|
|
|
(S)-2-methylbutanoyl-CoA + malonyl-CoA + H+ <=> 2-methyl-1-[2,4,6-trihydroxy-3-(3-methylbut-2-en-1-yl)phenyl]butan-1-one + CO2 + CoA
|
2.3.1.156
phloroisovalerophenone synthase
|
–
|
M
|
|
MetaCyc:
RXN-18439
|
|
|
|
ATP + 2-methylbutanoate + CoA <=> diphosphate + AMP + (S)-2-methylbutanoyl-CoA
|
6.2.1.1
acetate---CoA ligase
|
–
|
M
|
|
MetaCyc:
RXN-18448
|
|
|
|
(S)-2-methylbutanoyl-CoA + D-alanyl-3-O-methylprotoansatrienin <=> trienomycin_B + CoA + H+
|
2.3.1.dp
|
–
|
M
|
|
MetaCyc:
RXN-20431
|
|
|
|
(S)-2-methylbutanoyl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> (4S)-4-methyl-3-oxohhexanoyl-[acp] + CoA + CO2
|
2.3.1.dr
|
–
|
M
|
|
MetaCyc:
RXN-21612
|
|
|
|
sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(4-methyl)pentanoate + (S)-2-methylbutanoyl-CoA <=> sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(4-methyl)pentanoyl-6-(2-methyl)butyrate + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN18C3-110
|
|
|
|
sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(5-methyl)hexanoate + (S)-2-methylbutanoyl-CoA <=> sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(5-methyl)hexanoyl-6-(2-methyl)butyrate + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN18C3-112
|
|
|
|
sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(6-methyl)heptanoate + (S)-2-methylbutanoyl-CoA <=> sucrose-2-(2-methyl)butyryl-4-(2-methyl)butyryl-3-(6-methyl)heptanoyl-6-(2-methyl)butyrate + CoA
|
2.3.1
|
–
|
|
|
MetaCyc:
RXN18C3-114
|
|
|
|
sucrose + (S)-2-methylbutanoyl-CoA <=> 4-(2-methylbutanoyl)sucrose + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN18C3-26
|
|
|
|
4-(3-methylbutanoyl)sucrose + (S)-2-methylbutanoyl-CoA <=> 3-(2-methylbutanoyl)-4-(3-methylbutanoyl)sucrose + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN18C3-31
|
|
|
|
3-dodecanoyl-4-(3-methylbutanoyl)sucrose + (S)-2-methylbutanoyl-CoA <=> 3-dodecanoyl-3,4-di(3-methylbutanoyl)sucrose + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN18C3-48
|
|
|
|
(S)-2-methylbutanoyl-CoA + flavin <=> tigloyl-CoA + reduced_flavodoxin
|
1.3.8.4
isovaleryl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS425198
|
|
|
|
(S)-2-methylbutanoyl-CoA + phenazine_methosulfate + oxidized_2,6-dichlorophenolindophenol <=> (S)-2-methyl-2-butenoyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS258792
|
|