|
|
delta-tocotrienol <=> 6-geranylgeranyl-2-methylbenzene-1,4-diol
|
5.5.1.24
tocopherol cyclase
|
–
|
| |
BRENDA:
BR50793
KEGG:
R10623
MetaCyc:
RXN-14921
|
|
|
|
S-adenosyl-L-methionine + gamma-tocotrienol <=> S-adenosyl-L-homocysteine + alpha-tocotrienol + H+
|
2.1.1.95
tocopherol C-methyltransferase
|
–
|
| |
BRENDA:
BR52801
KEGG:
R10491
MetaCyc:
RXN-14918
|
|
|
|
geranylgeranyl_diphosphate + homogentisate + H+ <=> diphosphate + 6-geranylgeranyl-2-methylbenzene-1,4-diol + CO2
|
2.5.1.115
homogentisate phytyltransferase
2.5.1.116
homogentisate geranylgeranyltransferase
|
–
–
|
| |
BRENDA:
BR50959
KEGG:
R10708
MetaCyc:
RXN-14929
|
|
|
|
S-adenosyl-L-methionine + delta-tocotrienol <=> S-adenosyl-L-homocysteine + beta-tocotrienol + H+
|
2.1.1.95
tocopherol C-methyltransferase
|
–
|
| |
BRENDA:
BR52802
KEGG:
R10492
MetaCyc:
RXN-14919
|
|
|
|
gamma-tocotrienol <=> 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
|
5.5.1.24
tocopherol cyclase
|
–
|
| |
BRENDA:
BR50794;
BS427883
KEGG:
R10624
MetaCyc:
RXN-14922
|
|
|
|
S-adenosyl-L-methionine + 6-geranylgeranyl-2-methylbenzene-1,4-diol <=> S-adenosyl-L-homocysteine + 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol + H+
|
2.1.1.295
2-methyl-6-phytyl-1,4-hydroquinone methyltransferase
|
–
|
| |
BRENDA:
BR50941
KEGG:
R10710
MetaCyc:
RXN-14917
|
|
