|
|
2-methoxy-6-(all-trans-octaprenyl)phenol + O2 + NADPH + H+ <=> 2-methoxy-6-octaprenyl-1,4-benzoquinol + H2O + NADP+
|
1.14.13.M56
|
–
|
| |
MetaCyc:
2-OCTAPRENYL-6-METHOXYPHENOL-HYDROX-RXN
|
|
|
|
S-adenosyl-L-methionine + 2-octaprenyl-3-methyl-5-hydroxy-6-methoxy-1,4-benzoquinone <=> H+ + ubiquinol-8 + S-adenosyl-L-homocysteine
|
2.1.1.64
3-demethylubiquinol 3-O-methyltransferase
|
–
|
| |
BRENDA:
BS407327
MetaCyc:
DHHB-METHYLTRANSFER-RXN
|
|
|
|
4-hydroxy-3-octaprenylbenzoate + O2 + NADPH + H+ <=> 3,4-dihydroxy-5-octaprenylbenzoate + H2O + NADP+
|
1.14.13.M81
|
–
|
| |
MetaCyc:
RXN-9277
|
|
|
|
S-adenosyl-L-methionine + 3,4-dihydroxy-5-octaprenylbenzoate <=> H+ + 4-hydroxy-3-methoxy-5-octaprenylbenzoate + S-adenosyl-L-homocysteine
|
2.1.1.114
polyprenyldihydroxybenzoate methyltransferase
|
–
|
| |
BRENDA:
BS407323
MetaCyc:
RXN-9280
|
|
|
|
S-adenosyl-L-methionine + 2-methoxy-6-octaprenyl-1,4-benzoquinol <=> H+ + S-adenosyl-L-homocysteine + 6-methoxy-3-methyl-2-all-trans-octaprenyl-1,4-benzoquinol
|
2.1.1.201
2-methoxy-6-polyprenyl-1,4-benzoquinol methylase
|
–
|
| |
MetaCyc:
2-OCTAPRENYL-METHOXY-BENZOQ-METH-RXN
|
|
|
|
octaprenyl_diphosphate + 4-hydroxybenzoate <=> 4-hydroxy-3-octaprenylbenzoate + diphosphate
|
2.5.1.39
4-hydroxybenzoate polyprenyltransferase
|
–
|
| |
BRENDA:
BS409991
KEGG:
R05615
MetaCyc:
4OHBENZOATE-OCTAPRENYLTRANSFER-RXN
|
|
|
|
6-methoxy-3-methyl-2-all-trans-octaprenyl-1,4-benzoquinol + O2 + reduced_acceptor <=> 2-octaprenyl-3-methyl-5-hydroxy-6-methoxy-1,4-benzoquinone + H2O + acceptor
|
1.14.99.60
3-demethoxyubiquinol 3-hydroxylase
|
–
|
| |
MetaCyc:
OCTAPRENYL-METHYL-METHOXY-BENZOQ-OH-RXN
|
|
|
|
H+ + 4-hydroxy-3-methoxy-5-octaprenylbenzoate <=> 2-methoxy-6-(all-trans-octaprenyl)phenol + CO2
|
4.1.1
|
–
|
| |
MetaCyc:
RXN-9283
|
|
|
|
chorismate <=> 4-hydroxybenzoate + pyruvate
|
4.1.3.40
chorismate lyase
|
–
|
| |
BRENDA:
BR48792
KEGG:
R01302
MetaCyc:
CHORPYRLY-RXN
|
|
