|
|
S-adenosyl-L-methionine + tetracenomycin_B3 <=> Tetracenomycin_E + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-15435
|
|
|
|
3,5,7,9,11,13,15,17,19-nonaoxoicosanoate <=> 3,5-dioxo-6-[4,5,7-trihydroxy-3-(3-oxobutanoyl)naphthalen-2-yl]hexanoate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15413
|
|
|
|
S-adenosyl-L-methionine + tetracenomycin_D3 <=> tetracenomycin_B3 + S-adenosyl-L-homocysteine
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-15409
|
|
|
|
S-adenosyl-L-methionine + Tetracenomycin_E <=> tetracenomycin_A2 + S-adenosyl-L-homocysteine
|
2.1.1
|
–
|
| |
KEGG:
R06703
MetaCyc:
RXN-15436
|
|
|
|
tetracenomycin_F1 + O2 <=> tetracenomycin_D3 + H2O + H+
|
1.13.12.21
tetracenomycin-F1 monooxygenase
|
–
|
| |
BRENDA:
BR50567
KEGG:
R06700
MetaCyc:
RXN-14695
|
|
|
|
tetracenomycin_F2 <=> tetracenomycin_F1 + H2O
|
4.2.1.154
tetracenomycin F2 cyclase
|
–
|
| |
BRENDA:
BR51058
KEGG:
R06699
MetaCyc:
RXN-15056
|
|
|
|
tetracenomycin_A2 + O2 + NADPH + H+ <=> tetracenomycin_C + H2O + NADP+
|
1.14.13.200
tetracenomycin A2 monooxygenase-dioxygenase
|
–
|
| |
BRENDA:
BR51077
KEGG:
R06704
MetaCyc:
RXN-15434
|
|
|
|
H+ + malonyl-CoA <=> CO2 + acetyl-CoA
|
2.3.1.226
carboxymethylproline synthase
2.3.1.74
chalcone synthase
4.1.1.87
malonyl-S-ACP decarboxylase
4.1.1.9
malonyl-CoA decarboxylase
|
–
–
–
–
|
| |
BRENDA:
BR340
KEGG:
R00233
MetaCyc:
MALONYL-COA-DECARBOXYLASE-RXN
SABIO-RK:
750
|
|
|
|
3,5-dioxo-6-[4,5,7-trihydroxy-3-(3-oxobutanoyl)naphthalen-2-yl]hexanoate <=> tetracenomycin_F2 + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15412
|
|
|
|
acetyl-CoA + malonyl-CoA + H2O + H+ <=> 3,5,7,9,11,13,15,17,19-nonaoxoicosanoate + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11975
|
|
