|
|
7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[streptovaricin_PKS] + acceptor <=> 7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[streptovaricin_PKS] + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20271
|
|
|
|
streptovaricin_C + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> streptovaricin_G + H2O + oxidized_ferredoxin
|
1.14.15.M14
|
–
|
| |
MetaCyc:
RXN-20266
|
|
|
|
3-amino-5-hydroxybenzoyl-[streptovaricin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> tetraketide-[streptovaricin_PKS] + CoA + NADP+ + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20269
|
|
|
|
undecaketide-[streptovaricin-PKS] <=> prostreptovaricin + polyketide-[acp]
|
2.3.1.M73
|
–
|
| |
MetaCyc:
RXN-20258
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + polyketide-[acp] <=> 3-amino-5-hydroxybenzoyl-[streptovaricin_PKS] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20268
|
|
|
|
7,8-didehydro-3-methylprostreptovaricin <=> streptovaricin_C
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20275
|
|
|
|
S-adenosyl-L-methionine + prostreptovaricin <=> S-adenosyl-L-homocysteine + 3-methylprostreptovaricin + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-20259
|
|
|
|
tetraketide-[streptovaricin_PKS] + O2 + NADPH + H+ <=> 7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[streptovaricin_PKS] + H2O + NADP+
|
1.14.13.M73
|
–
|
| |
MetaCyc:
RXN-20270
|
|
|
|
7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[streptovaricin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> undecaketide-[streptovaricin-PKS] + CoA + NADP+ + CO2 + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20272
|
|
|
|
3-methylprostreptovaricin + acceptor <=> 7,8-didehydro-3-methylprostreptovaricin + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20264
|
|
|
|
3-methylprostreptovaricin <=> protostreptovaricin_I + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20260
|
|
