|
|
decanoyl-[acyl-carrier_protein] + NAD+ <=> (2E)-dec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-9660
|
|
|
|
(3R)-3-hydroxyoctanoyl-[acyl-carrier_protein] <=> 2-octenoyl-[acyl-carrier_protein] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
BRENDA:
BR437
KEGG:
R04537
MetaCyc:
4.2.1.59-RXN
|
|
|
|
3-oxo-3-(1H-pyrrol-2-yl)propanoyl-[RedN] + L-serine <=> 4-hydroxy-2,2''-bipyrrole-5-methanol + CO2 + holo-[RedN_acyl-carrier_protein/polyketide_synthase] + H2O
|
2.3.1
|
–
|
| |
MetaCyc:
RXN1A0-6114
|
|
|
|
L-proline + ATP + holo-[RedO_prolyl-carrier_protein] <=> L-prolyl-[RedO_prolyl-carrier_protein] + diphosphate + AMP + H+
|
6.2.1.53
L-proline---[L-prolyl-carrier protein] ligase
|
–
|
| |
MetaCyc:
RXN1A0-6104
|
|
|
|
S-adenosyl-L-methionine + 4-hydroxy-2,2''-bipyrrole-5-carbaldehyde <=> 4-methoxy-2,2''-bipyrrole-5-carbaldehyde + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R11670
MetaCyc:
RXN-15786
|
|
|
|
malonyl-CoA + holo-[RedN_acyl-carrier_protein/polyketide_synthase] <=> malonyl-[RedN] + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN1UA-7905
|
|
|
|
malonyl-CoA + RedL_polyketide_synthase <=> malonyl-[RedL_polyketide_synthase] + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN1UA-7906
|
|
|
|
4-hydroxy-2,2''-bipyrrole-5-methanol + NADP+ <=> 4-hydroxy-2,2''-bipyrrole-5-carbaldehyde + NADPH + H+
|
1.1.1
|
–
|
| |
KEGG:
R11668
MetaCyc:
RXN-15785
|
|
|
|
octanoyl-[acyl-carrier_protein] + NAD+ <=> 2-octenoyl-[acyl-carrier_protein] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
BRENDA:
BS258652
KEGG:
R04958
MetaCyc:
RXN-9659
|
|
|
|
Undecylprodigiosin + O2 + reduced_acceptor <=> streptorubin_B + H2O + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6102
|
|
|
|
1H-pyrrole-2-carbonyl-[RedO_prolyl-carrier_protein] + [RedX_protein]-L-cysteine <=> [RedX_acyl-carrier_protein]-(1H-pyrrole-2-carbonyl)-L-cysteine + holo-[RedO_prolyl-carrier_protein]
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6110
|
|
|
|
(3R)-3-hydroxybutanoyl-[acyl-carrier_protein] <=> H2O + trans-but-2-enoyl-[acyl-carrier_protein]
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
4.2.1.58-RXN
|
|
|
|
(3R)-3-hydroxyhexanoyl-[acp] <=> trans-Hex-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-9520
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320869
KEGG:
R04957
MetaCyc:
RXN-9523
SABIO-RK:
4595
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxodecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04534
MetaCyc:
RXN-9528
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] <=> (2E)-dec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-9655
|
|
|
|
butyryl-[acyl-carrier_protein] + NAD+ <=> trans-but-2-enoyl-[acyl-carrier_protein] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
BRENDA:
BS374746
KEGG:
R04429
MetaCyc:
RXN-9657
SABIO-RK:
4116
|
|
|
|
octanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxodecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320870
KEGG:
R04960
MetaCyc:
RXN-9527
SABIO-RK:
4598
|
|
|
|
decanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxododecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04963
MetaCyc:
RXN-9531
SABIO-RK:
4601
|
|
|
|
butyryl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxohexanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320867
KEGG:
R04952
MetaCyc:
RXN-9516
SABIO-RK:
4590
|
|
|
|
(3R)-3-hydroxyoctanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxooctanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04536
MetaCyc:
RXN-9524
|
|
|
|
ATP + 4-methoxy-2,2''-bipyrrole-5-carbaldehyde + 2-Undecylpyrrole <=> ADP + phosphate + Undecylprodigiosin + H+
|
6.4.1
|
–
|
| |
KEGG:
R11673
MetaCyc:
RXN-15800
|
|
|
|
(3R)-3-hydroxydodecanoyl-[acp] <=> dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-9533
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + NAD+ <=> dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + NADH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
–
–
|
| |
BRENDA:
BS258654
KEGG:
R04724
MetaCyc:
RXN-9661
SABIO-RK:
4380
|
|
|
|
acetyl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> acetoacetyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
| |
BRENDA:
BR48666
KEGG:
R10707
MetaCyc:
2.3.1.180-RXN
|
|
|
|
[RedX_acyl-carrier_protein]-(1H-pyrrole-2-carbonyl)-L-cysteine + malonyl-[RedN] + H+ <=> 3-oxo-3-(1H-pyrrol-2-yl)propanoyl-[RedN] + CO2 + [RedX_protein]-L-cysteine
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6112
|
|
|
|
2-Undecylpyrrole + NADP+ + H2O <=> 4-Keto-2-undecylpyrroline + NADPH + H+
|
1.17.1
|
–
|
| |
KEGG:
R11663
MetaCyc:
RXN1A0-6098
|
|
|
|
(3R)-3-hydroxyhexanoyl-[acp] + NADP+ <=> 3-oxohexanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-9518
|
|
|
|
(3R)-3-hydroxydodecanoyl-[acp] + NADP+ <=> 3-oxododecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-9532
|
|
|
|
(3R)-3-hydroxybutanoyl-[acyl-carrier_protein] + NADP+ <=> acetoacetyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS186945
KEGG:
R04533
MetaCyc:
RXN-9514
|
|
|
|
3-oxotetradecanoyl-[RedL_polyketide_synthase] + glycine <=> 4-Keto-2-undecylpyrroline + CO2 + RedL_polyketide_synthase + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6097
|
|
|
|
dodecanoyl-[RedQ_acyl-carrier_protein] + malonyl-[RedL_polyketide_synthase] + H+ <=> 3-oxotetradecanoyl-[RedL_polyketide_synthase] + CO2 + holo-[RedQ_acyl-carrier_protein]
|
not assigned
|
–
|
| |
MetaCyc:
RXN1A0-6094
|
|
|
|
L-prolyl-[RedO_prolyl-carrier_protein] + oxidized_electron_transfer_flavoprotein + H+ <=> 1H-pyrrole-2-carbonyl-[RedO_prolyl-carrier_protein] + reduced_flavodoxin
|
1.3.8.14
L-prolyl-[peptidyl-carrier protein] dehydrogenase
|
–
|
| |
MetaCyc:
RXN1A0-6108
|
|
|
|
hexanoyl-[acyl-carrier_protein] + NAD+ <=> trans-Hex-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
KEGG:
R04955
MetaCyc:
RXN-9658
|
|
