|
|
18-hydroxystearoyl-CoA + NADPH + H+ <=> 1,18-octadecane-diol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16405
|
|
|
|
CoA + 7-hydroxydodecanoate + ATP <=> 7-hydroxylauroyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
MetaCyc:
RXN-12184
|
|
|
|
7-hydroxylauroyl-CoA + malonyl-CoA + H+ <=> 2-(8-hydroxy-2-oxotridecyl)-6-oxopyran-4-olate + CO2 + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-16407
|
|
|
|
lauroyl-CoA + H2O <=> H+ + laurate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.2.1
acetyl-CoA hydrolase
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
|
| |
BRENDA:
BS360733
MetaCyc:
RXN-9627
SABIO-RK:
6746
|
|
|
|
18-hydroxyoleoyl-CoA + NADPH + H+ <=> (9Z)-octadec-9-ene-1,18-diol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16404
|
|
|
|
fatty_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 18-hydroxystearate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-16399
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|
|
|
16-hydroxypalmitoyl-CoA + NADPH + H+ <=> hexadecan-1,16-diol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16403
|
|
|
|
18-hydroxystearate + CoA + ATP <=> 18-hydroxystearoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
MetaCyc:
RXN-16401
|
|
|
|
2-(2,8-dihydroxytridecyl)-6-oxopyran-4-olate + NADP+ <=> 2-(8-hydroxy-2-oxotridecyl)-6-oxopyran-4-olate + NADPH + H+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-16406
|
|
|
|
7-hydroxylauroyl-CoA + NADPH + H+ <=> dodecane-1,7-diol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16408
|
|
|
|
laurate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 7-hydroxydodecanoate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.130
laurate 7-monooxygenase
|
–
|
| |
MetaCyc:
RXN-12186
|
|
|
|
oleoyl-CoA + H2O <=> H+ + oleic_acid + CoA
|
2.3.1.9
acetyl-CoA C-acetyltransferase
3.1.1.1
carboxylesterase
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
|
–
–
–
–
–
–
|
| |
BRENDA:
BS115467
KEGG:
R08176
MetaCyc:
RXN-9666
SABIO-RK:
6580
|
|
|
|
palmitate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 16-hydroxypalmitic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-16398
|
|
|
|
oleic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> omega-hydroxy_oleic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-16400
|
|
|
|
omega-hydroxy_oleic_acid + CoA + ATP <=> 18-hydroxyoleoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
MetaCyc:
RXN-16402
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|
|
|
16-hydroxypalmitic_acid + CoA + ATP <=> 16-hydroxypalmitoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
BRENDA:
BS379209
MetaCyc:
RXN-16389
SABIO-RK:
13099
|
|
