|
|
S-adenosyl-L-methionine + rhamnosyl_tetracyclic_spinosyn_pseudoaglycone <=> 2''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone + S-adenosyl-L-homocysteine + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-13631
|
|
|
|
rhamnosyl_tricyclic_spinosyn_pseudoaglycone <=> rhamnosyl_tetracyclic_spinosyn_pseudoaglycone
|
not assigned
|
–
|
|
MetaCyc:
RXN-13630
|
|
|
|
malonyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> spinosyn_macrolactone + CO2 + CoA + H2O + NADP+
|
2.3.1
|
–
|
|
MetaCyc:
RXN-13625
|
|
|
|
15-oxo_spinosyn_macrolactone <=> 11-dehydro-15-oxo_spinosyn_macrolactone + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-13627
|
|
|
|
2,3,4''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone + dTDP-alpha-D-forosamine <=> spinosyn_A + dTDP + H+
|
2.4.1
|
–
|
|
MetaCyc:
RXN-13634
|
|
|
|
S-adenosyl-L-methionine + 2''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone <=> 2,3''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone + S-adenosyl-L-homocysteine + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-13632
|
|
|
|
spinosyn_macrolactone + FAD + H+ <=> 15-oxo_spinosyn_macrolactone + FADH2
|
not assigned
|
–
|
|
MetaCyc:
RXN-13626
|
|
|
|
(2R,3aS,5aS,6E,10S,14S,15R,17E,18aS,18bR)-10-ethyl-2,14-dihydroxy-15-methyl-2,3,3a,5a,10,11,12,13,14,15,18a,18b-dodecahydro-1H-indeno[5,4-e]oxacyclopentadecine-8,16-dione + dTDP-L-rhamnose <=> rhamnosyl_tricyclic_spinosyn_pseudoaglycone + dTDP + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-13629
|
|
|
|
11-dehydro-15-oxo_spinosyn_macrolactone <=> (2R,3aS,5aS,6E,10S,14S,15R,17E,18aS,18bR)-10-ethyl-2,14-dihydroxy-15-methyl-2,3,3a,5a,10,11,12,13,14,15,18a,18b-dodecahydro-1H-indeno[5,4-e]oxacyclopentadecine-8,16-dione
|
not assigned
|
–
|
|
MetaCyc:
RXN-13628
|
|
|
|
S-adenosyl-L-methionine + 2,3''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone <=> 2,3,4''-O-methyl-rhamnosyl_tetracyclic_spinosyn_pseudoaglycone + S-adenosyl-L-homocysteine + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-13633
|
|