|
|
3-oxo-24-(isopropanoyl)-cholest-4,24-dien-26-oyl-CoA + H2O <=> 3,24-dioxo-cholest-4-en-26-oate + propionyl-CoA
|
3.1.2
|
–
|
|
MetaCyc:
RXN-12781
|
|
|
|
22-hydroxy-3-oxochol-4-en-24-oyl-CoA <=> 3-oxochol-4,22-dien-24-oyl-CoA + H2O
|
4.2.1
|
–
|
|
MetaCyc:
RXN-12708
|
|
|
|
3,24-dioxo-cholest-4-en-26-oate + ATP + CoA <=> 3,24-dioxocholest-4-en-26-oyl-CoA + AMP + diphosphate
|
6.2.1
|
–
|
|
MetaCyc:
RXN-12780
|
|
|
|
3-oxo-24-ethyl-cholest-4-ene + O2 + NADH + H+ <=> 3-oxo-24-ethyl-26-hydroxy-cholest-4-ene + H2O + NAD+
|
1.14.13
|
–
|
|
MetaCyc:
RXN-12788
|
|
|
|
3-oxo-23,24-bisnorchol-4-en-22-oic_acid-CoA + acceptor <=> 3-oxo-23,24-bisnorchol-4,17(20)-dien-22-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12743
|
|
|
|
3-oxo-24-ethyl-26-al-cholest-4-ene + NAD+ + H2O <=> 3-oxo-24-ethyl-cholest-4-en-26-oate + NADH + H+
|
1.2.1
|
–
|
|
MetaCyc:
RXN-12786
|
|
|
|
sitosterol + NAD+ <=> 3-oxo-24-ethyl-cholest-5-ene + NADH + H+
|
1.1.1.145
3beta-hydroxy-Delta5-steroid dehydrogenase
|
–
|
|
BRENDA:
BS424082
MetaCyc:
RXN-12789
|
|
|
|
3-oxo-24-ethyl-cholest-4,24-dien-26-oyl-CoA + HCO3- + ATP <=> 3-oxo-24-(isopropanoyl)-cholest-4,24-dien-26-oyl-CoA + ADP + phosphate + H+
|
6.4.1
|
–
|
|
MetaCyc:
RXN-12782
|
|
|
|
3-oxo-24-ethyl-26-hydroxy-cholest-4-ene + NAD+ <=> 3-oxo-24-ethyl-26-al-cholest-4-ene + NADH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12787
|
|
|
|
3-oxo-24-ethyl-cholest-4-en-26-oate + CoA + ATP <=> 3-oxo-24-ethyl-cholest-4-en-26-oyl-CoA + AMP + diphosphate
|
6.2.1
|
–
|
|
MetaCyc:
RXN-12785
|
|
|
|
3-oxochol-4-en-24-oyl-CoA + acceptor <=> 3-oxochol-4,22-dien-24-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12707
|
|
|
|
22-hydroxy-3-oxochol-4-en-24-oyl-CoA + NAD+ <=> 3,22-dioxochol-4-en-24-oyl-CoA + NADH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12709
|
|
|
|
3-oxochol-4-en-24-oyl-CoA + propionyl-CoA <=> 3,24-dioxocholest-4-en-26-oyl-CoA + CoA
|
2.3.1.176
propanoyl-CoA C-acyltransferase
|
–
|
|
MetaCyc:
RXN-12706
|
|
|
|
3-oxo-24-ethyl-cholest-5-ene <=> 3-oxo-24-ethyl-cholest-4-ene
|
5.3.3.1
steroid Delta-isomerase
|
–
|
|
MetaCyc:
RXN-12790
|
|
|
|
17-hydroxy-3-oxo-4-pregnane-20-carboxyl-CoA <=> 4-androstene-3,17-dione + propionyl-CoA
|
2.3.1
|
–
|
|
MetaCyc:
RXN-12745
|
|
|
|
17-hydroxy-3-oxo-4-pregnane-20-carboxyl-CoA <=> 3-oxo-23,24-bisnorchol-4,17(20)-dien-22-oyl-CoA + H2O
|
4.2.1
|
–
|
|
MetaCyc:
RXN-12744
|
|
|
|
3-oxo-23,24-bisnorchol-4-en-22-oic_acid-CoA + acetyl-CoA <=> 3,22-dioxochol-4-en-24-oyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
MetaCyc:
RXN-12710
|
|
|
|
3-oxo-24-ethyl-cholest-4-en-26-oyl-CoA + acceptor <=> 3-oxo-24-ethyl-cholest-4,24-dien-26-oyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
|
MetaCyc:
RXN-12784
|
|