|
|
iridotrial + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 7-deoxyloganetate + H2O + oxidized_[NADPH-hemoprotein_reductase] + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15237
|
|
|
|
H+ + L-tryptophan <=> CO2 + tryptamine
|
4.1.1.105
L-tryptophan decarboxylase
4.1.1.28
aromatic-L-amino-acid decarboxylase
4.1.1.53
phenylalanine decarboxylase
|
–
–
–
|
| |
BRENDA:
BR52265
KEGG:
R00685
MetaCyc:
AROMATIC-L-AMINO-ACID-DECARBOXYLASE-RXN
SABIO-RK:
1065
|
|
|
|
(6E)-8-oxogeraniol + NADP+ <=> (6E)-8-oxogeranial + NADPH + H+
|
1.1.1.324
8-hydroxygeraniol dehydrogenase
|
–
|
| |
BRENDA:
BR50018
KEGG:
R09929
MetaCyc:
RXN-9370
|
|
|
|
geranyl_diphosphate + H2O <=> geraniol + diphosphate
|
3.1.7.11
geranyl diphosphate diphosphatase
3.1.7.3
monoterpenyl-diphosphatase
4.2.3.104
alpha-humulene synthase
|
–
–
–
|
| |
BRENDA:
BR50059
KEGG:
R08396
MetaCyc:
RXN-17103;
RXN-8618
SABIO-RK:
12967
|
|
|
|
tryptamine + secologanin <=> strictosidine + H2O
|
4.3.3.2
strictosidine synthase
|
–
|
| |
BRENDA:
BR48360
KEGG:
R03738
MetaCyc:
STRICTOSIDINE-SYNTHASE-RXN
|
|
|
|
7-deoxyloganate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> loganic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.85
7-deoxyloganate 7-hydroxylase
|
–
|
| |
MetaCyc:
RXN-4521
|
|
|
|
cis-trans-nepetalactol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 7-deoxyloganetic_alcohol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-19644
|
|
|
|
7-deoxyloganetic_alcohol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> iridotrial + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9371
|
|
|
|
loganin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> secologanin + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.62
secologanin synthase
|
–
|
| |
MetaCyc:
1.3.3.9-RXN
|
|
|
|
(6E)-8-hydroxygeranial + NADP+ <=> (6E)-8-oxogeranial + NADPH + H+
|
1.1.1.324
8-hydroxygeraniol dehydrogenase
|
–
|
| |
BRENDA:
BR50017
KEGG:
R09927
MetaCyc:
RXN-9369
|
|
|
|
S-adenosyl-L-methionine + loganic_acid <=> S-adenosyl-L-homocysteine + loganin
|
2.1.1.50
loganate O-methyltransferase
|
–
|
| |
BRENDA:
BR40557
KEGG:
R03554
MetaCyc:
LOGANATE-O-METHYLTRANSFERASE-RXN
|
|
|
|
UDP-glucose + 7-deoxyloganetate <=> H+ + 7-deoxyloganate + UDP
|
2.4.1.323
7-deoxyloganetic acid glucosyltransferase
|
–
|
| |
BRENDA:
BR50953
KEGG:
R10834
MetaCyc:
RXN-9372
|
|
|
|
(S)-8-oxocitronellyl_enol + NADP+ <=> (6E)-8-oxogeranial + NADPH + H+
|
1.3.1.122
(S)-8-oxocitronellyl enol synthase
|
–
|
| |
BRENDA:
BR52966
KEGG:
R12518
MetaCyc:
RXN-20745
|
|
|
|
(S)-8-oxocitronellyl_enol <=> cis-trans-nepetalactol
|
5.5.1.34
(+)-cis,trans-nepetalactol synthase
|
–
|
| |
BRENDA:
BR52967
KEGG:
R12520
MetaCyc:
RXN-20744
|
|
|
|
(6E)-8-hydroxygeraniol + NADP+ <=> (6E)-8-hydroxygeranial + NADPH + H+
|
1.1.1.324
8-hydroxygeraniol dehydrogenase
|
–
|
| |
BRENDA:
BR50015
KEGG:
R09926
MetaCyc:
RXN-9367
SABIO-RK:
12976
|
|
|
|
geraniol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (6E)-8-hydroxygeraniol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.83
geraniol 8-hydroxylase
|
–
|
| |
MetaCyc:
RXN-8197
|
|
|
|
(6E)-8-hydroxygeraniol + NADP+ <=> (6E)-8-oxogeraniol + NADPH + H+
|
1.1.1.324
8-hydroxygeraniol dehydrogenase
|
–
|
| |
BRENDA:
BR50016
KEGG:
R09928
MetaCyc:
RXN-9368
SABIO-RK:
12977
|
|
