|
|
34a-Deoxy-rifamycin_W + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> Demethyl-desacetyl-rifamycin_S + CO2 + H2O + oxidized_ferredoxin
|
1.14.15
|
–
|
| |
MetaCyc:
RXN-20302
|
|
|
|
undecaketide-[rifamycin-PKS] <=> Proansamycin_X + polyketide-[acp]
|
2.3.1.M72
|
–
|
| |
MetaCyc:
RXN-9604
|
|
|
|
27-O-Demethyl-25-O-desacetylrifamycin_SV + acetyl-CoA <=> 27-O-demethylrifamycin_SV + CoA
|
2.3.1
|
–
|
| |
KEGG:
R06997
MetaCyc:
RXN-9610
|
|
|
|
Rifamycin_B + NADP+ <=> Rifamycin_O + NADPH
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9612
|
|
|
|
3-amino-5-hydroxybenzoyl-[rifamycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> tetraketide-[rifamycin_PKS] + CoA + NADP+ + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-9594
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + polyketide-[acp] <=> 3-amino-5-hydroxybenzoyl-[rifamycin_PKS] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20273
|
|
|
|
rifamycin_SV + O2 <=> rifamycin_S + H2O2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20243
|
|
|
|
tetraketide-[rifamycin_PKS] + O2 + NADPH + H+ <=> 7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[rifamycin_PKS] + H2O + NADP+
|
1.14.13.M73
|
–
|
| |
MetaCyc:
RXN-20247
|
|
|
|
7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[rifamycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> undecaketide-[rifamycin-PKS] + CoA + NADP+ + CO2 + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9602
|
|
|
|
Demethyl-desacetyl-rifamycin_S + reduced_acceptor <=> 27-O-Demethyl-25-O-desacetylrifamycin_SV + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9609
|
|
|
|
Proansamycin_X + NADP+ <=> 34a-Deoxy-rifamycin_W + NADPH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-9605
|
|
|
|
rifamycin_L + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> Rifamycin_O + H2O + oxidized_ferredoxin
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-20245
|
|
|
|
S-adenosyl-L-methionine + 27-O-demethylrifamycin_SV <=> S-adenosyl-L-homocysteine + rifamycin_SV + H+
|
2.1.1.315
27-O-demethylrifamycin SV methyltransferase
|
–
|
| |
BRENDA:
BR51221
KEGG:
R06998
MetaCyc:
RXN-9611
|
|
|
|
7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[rifamycin_PKS] + acceptor <=> 7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[rifamycin_PKS] + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20248
|
|
|
|
rifamycin_S + D-xylulose_5-phosphate <=> rifamycin_L + D-glyceraldehyde_3-phosphate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20244
|
|
