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rhizocticin A and B biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
L-valyl-L-arginyl-4-hydroxy-5-phosphonopentanoate <=> Rhizocticin_B + H2O 4.2.1

2-keto-5-phospho-3-cis-pentenoate + an_L-amino_acid <=> AppA + a_2-oxo_carboxylate 2.6.1

2-amino-4-hydroxy-5-phosphonopentanoate <=> AppA + H2O 4.2.1

ATP + L-arginyl-4-hydroxy-5-phosphonopentanoate + L-valine <=> ADP + phosphate + L-valyl-L-arginyl-4-hydroxy-5-phosphonopentanoate + H+ 6.3.2

ATP + L-Arg-L-2-amino-5-phosphono-3-cis-pentenoate + L-valine <=> ADP + phosphate + Rhizocticin_B + H+ 6.3.2

2-keto-4-hydroxy-5-phosphopentanoate <=> 2-keto-5-phospho-3-cis-pentenoate + H2O 4.2.1

phosphonoacetaldehyde + oxaloacetate + H+ <=> 2-keto-4-hydroxy-5-phosphopentanoate + CO2 4.1.3

ATP + 2-amino-4-hydroxy-5-phosphonopentanoate + L-arginine <=> ADP + phosphate + L-arginyl-4-hydroxy-5-phosphonopentanoate + H+ 6.3.2

H+ + phosphoenolpyruvate <=> Phosphonopyruvate 5.4.2.9 phosphoenolpyruvate mutase

2-keto-4-hydroxy-5-phosphopentanoate + an_L-amino_acid <=> 2-amino-4-hydroxy-5-phosphonopentanoate + a_2-oxo_carboxylate 2.6.1

H+ + Phosphonopyruvate <=> phosphonoacetaldehyde + CO2 4.1.1.82 phosphonopyruvate decarboxylase

ATP + AppA + L-arginine <=> ADP + phosphate + L-Arg-L-2-amino-5-phosphono-3-cis-pentenoate + H+ 6.3.2
6.3.2.48 L-arginine-specific L-amino acid ligase


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