|
|
S-adenosyl-L-methionine + 4''-O-demethylrebeccamycin <=> H+ + rebeccamycin + S-adenosyl-L-homocysteine
|
2.1.1.164
demethylrebeccamycin-D-glucose O-methyltransferase
|
–
|
| |
BRENDA:
BR49136
KEGG:
R09569
MetaCyc:
RXN-10847
|
|
|
|
dichlorochromopyrrolate + O2 + NADH + H+ <=> dichloroarcyriaflavin_A + CO2 + H2O + NAD+
|
1.13.12.17
dichloroarcyriaflavin A synthase
|
–
|
| |
BRENDA:
BR49133
KEGG:
R09567
MetaCyc:
RXN-10845
|
|
|
|
dichloroarcyriaflavin_A + D-glucose <=> 4''-O-demethylrebeccamycin + H2O
|
4.3.3.5
4'-demethylrebeccamycin synthase
|
–
|
| |
BRENDA:
BR49244
KEGG:
R09568
MetaCyc:
RXN-10846
|
|
|
|
7-chloro-L-tryptophan + O2 <=> 2-imino-3-(7-chloroindol-3-yl)propanoate + H2O2 + H+
|
1.4.3.23
7-chloro-L-tryptophan oxidase
|
–
|
| |
BRENDA:
BR49130
KEGG:
R09560
MetaCyc:
RXN-10843
|
|
|
|
2-imino-3-(7-chloroindol-3-yl)propanoate + H2O2 <=> 3,4-bis(7-chloro-1H-indol-3-yl)-2,5-diiminohexanedioate + H2O
|
1.21.98.2
dichlorochromopyrrolate synthase
|
–
|
| |
MetaCyc:
RXN-16966
|
|
|
|
3,4-bis(7-chloro-1H-indol-3-yl)-2,5-diiminohexanedioate + H+ <=> dichlorochromopyrrolate + NH3
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18336
|
|
|
|
L-tryptophan + FADH2 + Cl- + O2 <=> 7-chloro-L-tryptophan + FAD + H2O
|
1.14.19.9
tryptophan 7-halogenase
|
–
|
| |
BRENDA:
BR48866
KEGG:
R09570
MetaCyc:
RXN-10842
SABIO-RK:
14708
|
|
