|
|
2-hydroxy-2,4-hexadienedioate <=> 4-oxalocrotonate
|
5.3.2.6
2-hydroxymuconate tautomerase
5.3.2.M1
|
–
–
|
| |
BRENDA:
BR50210;
BS419260;
BS419261;
BS419897
KEGG:
R03966
MetaCyc:
RXN-12354;
RXN-8529
SABIO-RK:
3703
|
|
|
|
3,4-dihydroxybenzoate + O2 <=> 2-hydroxy-5-carboxymuconate_semialdehyde + H+
|
1.13.11
1.13.11.15
3,4-dihydroxyphenylacetate 2,3-dioxygenase
|
–
–
|
| |
BRENDA:
BS288977
MetaCyc:
RXN-10882
|
|
|
|
2-hydroxy-5-carboxymuconate_semialdehyde + H+ <=> 2-hydroxymuconate-6-semialdehyde + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-10883
|
|
|
|
2-hydroxymuconate-6-semialdehyde + H2O + NAD+ <=> 2-hydroxy-2,4-hexadienedioate + NADH + H+
|
1.2.1.32
aminomuconate-semialdehyde dehydrogenase
1.2.1.85
2-hydroxymuconate-6-semialdehyde dehydrogenase
|
–
–
|
| |
BRENDA:
BR50236;
BS258087;
BS370776
KEGG:
R02762
MetaCyc:
RXN-8527
|
|
|
|
2-oxo-3-hexenedioate + H+ <=> (2Z)-2-hydroxypenta-2,4-dienoate + CO2
|
4.1.1.77
2-oxo-3-hexenedioate decarboxylase
|
–
|
| |
MetaCyc:
4.1.1.77-RXN
|
|
