|
|
L-glutamyl_gamma-phosphinic_acid + acetyl-CoA <=> H+ + N-acetyldemethylphosphinothricin + CoA
|
2.3.1.183
phosphinothricin acetyltransferase
|
–
|
| |
KEGG:
R08871
MetaCyc:
RXN-10837
|
|
|
|
Phosphonoformate + CTP <=> CMP-5''-phosphonoformate + diphosphate
|
2.7.7.93
phosphonoformate cytidylyltransferase
|
–
|
| |
BRENDA:
BR51763
KEGG:
R08867
MetaCyc:
RXN-10834
|
|
|
|
2-hydroxyethylphosphonate + O2 <=> H+ + hydroxymethylphosphonate + formate
|
1.13.11.72
2-hydroxyethylphosphonate dioxygenase
|
–
|
| |
BRENDA:
BR50255
KEGG:
R08864
MetaCyc:
RXN-10824
|
|
|
|
Deamino-alpha-keto-demethylphosphinothricin + aminated_amino_group_donor <=> L-glutamyl_gamma-phosphinic_acid + deaminated_amino_group_donor
|
2.6.1
|
–
|
| |
MetaCyc:
RXN-10832
|
|
|
|
H+ + phosphoenolpyruvate <=> Phosphonopyruvate
|
5.4.2.9
phosphoenolpyruvate mutase
|
–
|
| |
BRENDA:
BR48374
KEGG:
R00661
MetaCyc:
PHOSPHOENOLPYRUVATE-MUTASE-RXN
|
|
|
|
Formylphosphonate + H2O + NADP+ <=> Phosphonoformate + NADPH + H+
|
1.2.1
|
–
|
| |
MetaCyc:
RXN-10835
|
|
|
|
3-(hydroxyphosphonoylmethyl)malate + acceptor + H+ <=> Deamino-alpha-keto-demethylphosphinothricin + CO2 + reduced_acceptor
|
4.1.1
|
–
|
| |
MetaCyc:
RXN-10831
|
|
|
|
(hydroxyphosphinyl)pyruvate + acetyl-CoA + H2O <=> H+ + 2-(hydroxyphosphonoylmethyl)malate + CoA
|
2.3.3.18
2-phosphinomethylmalate synthase
|
–
|
| |
BRENDA:
BR51965
KEGG:
R08870
MetaCyc:
RXN-10829
|
|
|
|
2-phosphono-formylglycerate <=> 1-carboxyvinyl_carboxyphosphonate + H2O
|
4.2.1
|
–
|
| |
MetaCyc:
RXN-10826
|
|
|
|
N-acetyldemethylphosphinothricinyl-[PhsA_non-ribosomal_peptide_synthase] + L-alanyl-[PhsB_non-ribosomal_peptide_synthase] <=> N-acetyldemethylphosphinothricinyl-L-alanyl-[PhsB_non-ribosomal_peptide_synthase] + PhsA_non-ribosomal_peptide_synthase + H+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-17192
|
|
|
|
carboxyphosphinopyruvate + H+ <=> (hydroxyphosphinyl)pyruvate + CO2
|
2.7.8.23
carboxyvinyl-carboxyphosphonate phosphorylmutase
|
–
|
| |
BRENDA:
BS358714
KEGG:
R08869
MetaCyc:
RXN-10828
|
|
|
|
L-alanine + ATP + H+ <=> (L-alanyl)adenylate + diphosphate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-17190
|
|
|
|
2-hydroxyethylphosphonate + NAD+ <=> phosphonoacetaldehyde + NADH + H+
|
1.1.1.309
phosphonoacetaldehyde reductase (NADH)
|
–
|
| |
BRENDA:
BR49249
KEGG:
R09478
MetaCyc:
RXN-9009
|
|
|
|
H+ + Phosphonopyruvate <=> phosphonoacetaldehyde + CO2
|
4.1.1.82
phosphonopyruvate decarboxylase
|
–
|
| |
BRENDA:
BR48645
KEGG:
R04053
MetaCyc:
4.1.1.82-RXN
SABIO-RK:
3786
|
|
|
|
N-acetyldemethylphosphinothricinyl-L-alanyl-[PhsB_non-ribosomal_peptide_synthase] + L-alanine + PhsC_non-ribosomal_peptide_synthase + ATP <=> N-acetyldemethylphosphinothricinyl-L-alanyl-L-alanyl-[PhsC_non-ribosomal_peptide_synthase] + AMP + diphosphate + PhsB_non-ribosomal_peptide_synthase + H+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-17193
|
|
|
|
N-acetyldemethylphosphinothricin_adenylate + PhsA_non-ribosomal_peptide_synthase <=> N-acetyldemethylphosphinothricinyl-[PhsA_non-ribosomal_peptide_synthase] + AMP + H+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-17189
|
|
|
|
L-N-acetylphosphinothricin_bialophos + H2O <=> phosphinotricyl-alanyl-alanine/out + acetate
|
3.1.1
|
–
|
| |
KEGG:
R08876
MetaCyc:
RXN-10840
|
|
|
|
2-(hydroxyphosphonoylmethyl)malate <=> 3-(hydroxyphosphonoylmethyl)malate
|
4.2.1.166
phosphinomethylmalate isomerase
|
–
|
| |
BRENDA:
BR51657
KEGG:
R11408
MetaCyc:
RXN-10830
|
|
|
|
CMP-5''-phosphonoformate + 3-phospho-D-glycerate + H2O <=> H+ + 2-phosphono-formylglycerate + CMP + phosphate
|
2.7.1
|
–
|
| |
MetaCyc:
RXN-10833
|
|
|
|
(L-alanyl)adenylate + PhsB_non-ribosomal_peptide_synthase <=> L-alanyl-[PhsB_non-ribosomal_peptide_synthase] + AMP + H+
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-17191
|
|
|
|
hydroxymethylphosphonate + NADP+ <=> Formylphosphonate + NADPH + H+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-10836
|
|
|
|
N-acetyldemethylphosphinothricin + ATP + H+ <=> N-acetyldemethylphosphinothricin_adenylate + diphosphate
|
2.7.7
|
–
|
| |
MetaCyc:
RXN-17188
|
|
|
|
1-carboxyvinyl_carboxyphosphonate <=> carboxyphosphinopyruvate
|
2.7.8.23
carboxyvinyl-carboxyphosphonate phosphorylmutase
|
–
|
| |
KEGG:
R08868
MetaCyc:
RXN-10827
|
|
|
|
S-adenosyl-L-methionine + N-acetyldemethyl_phosphinothricin_tripeptide + reduced_acceptor <=> L-N-acetylphosphinothricin_bialophos + 5''-deoxyadenosine + L-methionine + S-adenosyl-L-homocysteine + H+ + acceptor
|
2.1.1.326
N-acetyldemethylphosphinothricin P-methyltransferase
|
–
|
| |
MetaCyc:
RXN-10839
|
|
|
|
N-acetyldemethylphosphinothricinyl-L-alanyl-L-alanyl-[PhsC_non-ribosomal_peptide_synthase] + H2O <=> N-acetyldemethyl_phosphinothricin_tripeptide + PhsC_non-ribosomal_peptide_synthase + H+
|
3.1.2
|
–
|
| |
MetaCyc:
RXN-17194
|
|
