|
|
17-(4-hydroxyphenyl)heptadecanoyl-[4-hydroxyphenylalkanoate_synthase] + H2O <=> 17-(4-hydroxyphenyl)heptadecanoate + holo-[4-hydroxyphenylalkanoate_synthase] + H+
|
3.1.2.M1
|
–
|
| |
MetaCyc:
RXN-17212
|
|
|
|
C37-phenolcarboxyphthiodiolenone + H+ <=> C36-phenolphthiodiolenone_A + CO2
|
4.1.1.M4
|
–
|
| |
MetaCyc:
RXN-17264
|
|
|
|
C35-phenolcarboxyphthiodiolenone + H+ <=> C34-phenolphthiodiolenone_A + CO2
|
4.1.1.M4
|
–
|
| |
MetaCyc:
RXN-17262
|
|
|
|
19-(4-hydroxyphenyl)nonadecanoyl-[(phenol)carboxyphthiodiolenone_synthase] + malonyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> C37-(phenol)carboxyphthiodiolenone-[(phenol)carboxyphthiodiolenone_synthase] + CO2 + CoA + NADP+ + H2O
|
2.3.1.292
(phenol)carboxyphthiodiolenone synthase
|
–
|
| |
BRENDA:
BR52913
MetaCyc:
RXN-17246
|
|
|
|
4-hydroxybenzoyl_adenylate + holo-[4-hydroxyphenylalkanoate_synthase] <=> 4-hydroxybenzoyl-[4-hydroxyphenylalkanoate_synthase] + AMP + H+
|
6.2.1.50
4-hydroxybenzoate adenylyltransferase FadD22
|
–
|
| |
BRENDA:
BR52174
MetaCyc:
RXN-17210
|
|
|
|
S-adenosyl-L-methionine + C36-phenolphthiotriol_A <=> C37-phenolphthiocerol_A + S-adenosyl-L-homocysteine + H+
|
2.1.1.M12
|
–
|
| |
MetaCyc:
RXN-17306
|
|
|
|
S-adenosyl-L-methionine + C34-phenolphthiotriol_A <=> C35-phenolphthiocerol_A + S-adenosyl-L-homocysteine + H+
|
2.1.1.M12
|
–
|
| |
MetaCyc:
RXN-17233
|
|
|
|
19-(4-hydroxyphenyl)nonadecanoyl_adenylate + holo-[(phenol)carboxyphthiodiolenone_synthase] <=> 19-(4-hydroxyphenyl)nonadecanoyl-[(phenol)carboxyphthiodiolenone_synthase] + AMP + H+
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
| |
BRENDA:
BR52263
MetaCyc:
RXN-18536
|
|
|
|
4-hydroxybenzoyl-[4-hydroxyphenylalkanoate_synthase] + malonyl-CoA + NADPH + H+ <=> 19-(4-hydroxyphenyl)nonadecanoyl-[4-hydroxyphenylalkanoate_synthase] + CoA + CO2 + NADP+ + H2O
|
2.3.1.261
(4-hydroxyphenyl)alkanoate synthase
|
–
|
| |
MetaCyc:
RXN-17236
|
|
|
|
C34-phenolphthiodiolone_A + NADP+ <=> C34-phenolphthiodiolenone_A + NADPH + H+
|
1.1.1.M10
|
–
|
| |
MetaCyc:
RXN-17235
|
|
|
|
C37-(phenol)carboxyphthiodiolenone-[(phenol)carboxyphthiodiolenone_synthase] + H2O <=> C37-phenolcarboxyphthiodiolenone + holo-[(phenol)carboxyphthiodiolenone_synthase] + H+
|
3.1.2.M1
|
–
|
| |
MetaCyc:
RXN-17263
|
|
|
|
4-hydroxybenzoate + ATP + H+ <=> 4-hydroxybenzoyl_adenylate + diphosphate
|
6.2.1.50
4-hydroxybenzoate adenylyltransferase FadD22
|
–
|
| |
BRENDA:
BR52173
KEGG:
R11608
MetaCyc:
RXN-17209
|
|
|
|
C35-(phenol)carboxyphthiodiolenone-[(phenol)carboxyphthiodiolenone_synthase] + H2O <=> C35-phenolcarboxyphthiodiolenone + holo-[(phenol)carboxyphthiodiolenone_synthase] + H+
|
3.1.2.M1
|
–
|
| |
MetaCyc:
RXN-17261
|
|
|
|
17-(4-hydroxyphenyl)heptadecanoyl-[(phenol)carboxyphthiodiolenone_synthase] + malonyl-CoA + (S)-methylmalonyl-CoA + NADPH + H+ <=> C35-(phenol)carboxyphthiodiolenone-[(phenol)carboxyphthiodiolenone_synthase] + CO2 + CoA + NADP+ + H2O
|
2.3.1.292
(phenol)carboxyphthiodiolenone synthase
|
–
|
| |
BRENDA:
BR52914
MetaCyc:
RXN-17215
|
|
|
|
4-hydroxybenzoyl-[4-hydroxyphenylalkanoate_synthase] + malonyl-CoA + NADPH + H+ <=> 17-(4-hydroxyphenyl)heptadecanoyl-[4-hydroxyphenylalkanoate_synthase] + CoA + CO2 + NADP+ + H2O
|
2.3.1.261
(4-hydroxyphenyl)alkanoate synthase
|
–
|
| |
BRENDA:
BR51960;
BS438109
MetaCyc:
RXN-17211
|
|
|
|
19-(4-hydroxyphenyl)nonadecanoyl-[4-hydroxyphenylalkanoate_synthase] + H2O <=> 19-(4-hydroxyphenyl)nonadecanoate + holo-[4-hydroxyphenylalkanoate_synthase] + H+
|
3.1.2.M1
|
–
|
| |
MetaCyc:
RXN-17237
|
|
|
|
C34-phenolphthiotriol_A + NADP+ <=> C34-phenolphthiodiolone_A + NADPH + H+
|
1.1.1.M11
|
–
|
| |
MetaCyc:
RXN-17234
|
|
|
|
ATP + 17-(4-hydroxyphenyl)heptadecanoate + H+ <=> diphosphate + 17-(4-hydroxyphenyl)heptadecanoyl_adenylate
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
| |
BRENDA:
BR52260
KEGG:
R11537
MetaCyc:
RXN-17213
|
|
|
|
17-(4-hydroxyphenyl)heptadecanoyl_adenylate + holo-[(phenol)carboxyphthiodiolenone_synthase] <=> 17-(4-hydroxyphenyl)heptadecanoyl-[(phenol)carboxyphthiodiolenone_synthase] + AMP + H+
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
| |
BRENDA:
BR52261
MetaCyc:
RXN-18538
|
|
|
|
C36-phenolphthiotriol_A + NADP+ <=> C36-phenolphthiodiolone_A + NADPH + H+
|
1.1.1.M11
|
–
|
| |
MetaCyc:
RXN-17305
|
|
|
|
C36-phenolphthiodiolone_A + NADP+ <=> C36-phenolphthiodiolenone_A + NADPH + H+
|
1.1.1.M10
|
–
|
| |
MetaCyc:
RXN-17304
|
|
|
|
ATP + 19-(4-hydroxyphenyl)nonadecanoate + H+ <=> diphosphate + 19-(4-hydroxyphenyl)nonadecanoyl_adenylate
|
6.2.1.51
4-hydroxyphenylalkanoate adenylyltransferase FadD29
|
–
|
| |
BRENDA:
BR52262
KEGG:
R11538
MetaCyc:
RXN-17238
|
|
|
|
chorismate <=> 4-hydroxybenzoate + pyruvate
|
4.1.3.40
chorismate lyase
|
–
|
| |
BRENDA:
BR48792
KEGG:
R01302
MetaCyc:
CHORPYRLY-RXN
|
|
