|
|
(2E,6E)-farnesyl_diphosphate <=> pentalenene + diphosphate
|
4.2.3.7
pentalenene synthase
|
–
|
| |
BRENDA:
BR48354
KEGG:
R02305
MetaCyc:
PENTALENENE-SYNTHASE-RXN
|
|
|
|
pentalen-13-al + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> (+/-)-1-deoxypentalenic_acid + oxidized_ferredoxin + H2O
|
1.14.15
|
–
|
| |
MetaCyc:
RXN-12652
|
|
|
|
neopentalenolactone_F <=> neopentalenoketolactone
|
not assigned
|
–
|
| |
MetaCyc:
RXN-12664
|
|
|
|
1-deoxy-11beta-hydroxypentalenic_acid + NAD+ <=> 1-deoxy-11-oxopentalenate + NADH + H+
|
1.1.1.340
1-deoxy-11beta-hydroxypentalenate dehydrogenase
|
–
|
| |
BRENDA:
BR50233
KEGG:
R10156
MetaCyc:
RXN-12658
|
|
|
|
1-deoxy-11-oxopentalenate + O2 + NADPH + H+ <=> neopentalenolactone_D + H2O + NADP+
|
1.14.13.171
neopentalenolactone D synthase
|
–
|
| |
BRENDA:
BR50266
KEGG:
R10155
MetaCyc:
RXN-12661
|
|
|
|
pentalenene + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> pentalen-13-ol + oxidized_ferredoxin + H2O
|
1.14.15.32
pentalenene oxygenase
|
–
|
| |
BRENDA:
BR49820
KEGG:
R09812
MetaCyc:
RXN-12649
|
|
|
|
neopentalenolactone_E + O2 + 2-oxoglutarate <=> neopentalenolactone_F + succinate + CO2
|
1.14.11
|
–
|
| |
MetaCyc:
RXN-12663
|
|
|
|
pentalen-13-ol + reduced_ferredoxin_[iron-sulfur]_cluster + H+ + O2 <=> pentalen-13-al + oxidized_ferredoxin + H2O
|
1.14.15.32
pentalenene oxygenase
|
–
|
| |
BRENDA:
BR49821
KEGG:
R09813
MetaCyc:
RXN-12650
|
|
|
|
(+/-)-1-deoxypentalenic_acid + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> pentalenate + oxidized_ferredoxin + H2O
|
1.14.15.11
pentalenic acid synthase
|
–
|
| |
BRENDA:
BR50267
KEGG:
R10158
MetaCyc:
RXNMETA-12666
|
|
|
|
(+/-)-1-deoxypentalenic_acid + 2-oxoglutarate + O2 <=> 1-deoxy-11beta-hydroxypentalenic_acid + succinate + CO2
|
1.14.11.35
1-deoxypentalenic acid 11beta-hydroxylase
|
–
|
| |
BRENDA:
BR50257
KEGG:
R10157
MetaCyc:
RXN-12651
|
|
|
|
neopentalenolactone_D + O2 + 2-oxoglutarate <=> neopentalenolactone_E + succinate + CO2 + H2O
|
1.14.20
|
–
|
| |
MetaCyc:
RXN-12662
|
|
