|
|
tetradecaketide-[naphthomycin-PKS] <=> pronaphthomycin + polyketide-[acp]
|
2.3.1.M75
|
–
|
| |
MetaCyc:
RXN-20304
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + polyketide-[acp] <=> 3-amino-5-hydroxybenzoyl-[naphthomycin_PKS] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20309
|
|
|
|
7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[naphthomycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> tetradecaketide-[naphthomycin-PKS] + CoA + NADP+ + CO2 + H2O
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20305
|
|
|
|
7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[naphthomycin_PKS] + acceptor <=> 7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[naphthomycin_PKS] + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20306
|
|
|
|
naphthomycin_E + FADH2 + Cl- + O2 <=> naphthomycin_A + FAD + H2O
|
1.14.19.M25
|
–
|
| |
MetaCyc:
RXN-20303
|
|
|
|
tetraketide-[naphthomycin_PKS] + O2 + NADPH + H+ <=> 7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[naphthomycin_PKS] + H2O + NADP+
|
1.14.13.M73
|
–
|
| |
MetaCyc:
RXN-20307
|
|
|
|
pronaphthomycin <=> naphthomycin_E + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20297
|
|
|
|
3-amino-5-hydroxybenzoyl-[naphthomycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> tetraketide-[naphthomycin_PKS] + CoA + NADP+ + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20308
|
|
