|
|
N-hydroxy-L-valine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N,N-dihydroxy-L-valine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-5064
|
|
|
|
L-valine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-hydroxy-L-valine + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-5063
|
|
|
|
UDP-glucose + acetone_cyanohydrin <=> H+ + linamarin + UDP
|
2.4.1.63
linamarin synthase
|
–
|
| |
BRENDA:
BR44240
KEGG:
R03625
MetaCyc:
LINAMARIN-SYNTHASE-RXN
|
|
|
|
Isobutyraldoxime <=> Isobutyronitrile + H2O
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
| |
BRENDA:
BR51945
KEGG:
R11641
MetaCyc:
RXN-5081
|
|
|
|
(E)-2-methylpropanal-oxime <=> Isobutyraldoxime
|
1.14.14.41
(E)-2-methylbutanal oxime monooxygenase
|
–
|
| |
BRENDA:
BR51944
KEGG:
R10034
MetaCyc:
RXN-5066
|
|
|
|
N,N-dihydroxy-L-valine + H+ <=> (E)-2-methylpropanal-oxime + CO2 + H2O
|
1.14.14.38
valine N-monooxygenase
1.14.14.39
isoleucine N-monooxygenase
|
–
–
|
| |
BRENDA:
BR49383
KEGG:
R10033
MetaCyc:
RXN-5065
|
|
|
|
Isobutyronitrile + O2 + reduced_[NADPH-hemoprotein_reductase] <=> acetone_cyanohydrin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-5082
|
|
