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hispidol and hispidol 4'-O-beta-D-glucoside biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
isoliquiritigenin + H2O2 <=> 2-[hydroperoxy(4-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one + H2O 1.11.2
–
isoliquiritigenin_4''-glucoside + H2O2 <=> 2-[hydroperoxy-(4-glucosyl-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one + H2O 1.11.2
–
6-hydroxy-2-[hydroxy-(4-hydroxyphenyl)methyl]-1-benzofuran-3-one <=> hispidol + H2O not assigned
 –
2-[hydroperoxy(4-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one <=> 6-hydroxy-2-(6-oxo-1-oxaspiro[2.5]octa-4,7-dien-2-yl)-1-benzofuran-3-one + H2O 1.11.2
–
2-[hydroperoxy-(4-glucosyl-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one + reduced_acceptor <=> 2-(6-oxo-1-oxaspiro[2.5]octa-4-glucosyl)-6-hydroxy-1-benzofuran-3-one + H2O + acceptor 1.11.2
–
6-hydroxy-2-(6-oxo-1-oxaspiro[2.5]octa-4,7-dien-2-yl)-1-benzofuran-3-one <=> 6-hydroxy-2-(4-hydroxy-phenoxymethylene)-benzofuran-3-one not assigned
 –
UDP-glucose + isoliquiritigenin <=> H+ + isoliquiritigenin_4''-glucoside + UDP 2.4.1
2.4.1.170 isoflavone 7-O-glucosyltransferase
–
–
2-[hydroperoxy-(4-glucosyl-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one + reduced_acceptor <=> 6-hydroxy-2-[(4-glucosyl-hydroxyphenyl)methyl]-1-benzofuran-3-one + H2O + acceptor 1.11.2
–
2-[hydroperoxy(4-hydroxyphenyl)methyl]-6-hydroxy-1-benzofuran-3-one + reduced_acceptor <=> 6-hydroxy-2-[hydroxy-(4-hydroxyphenyl)methyl]-1-benzofuran-3-one + H2O + acceptor 1.11.2
–
6-hydroxy-2-[(4-glucosyl-hydroxyphenyl)methyl]-1-benzofuran-3-one <=> hispidol-4''-O-beta-D-glucoside + H2O not assigned
 –
2-(6-oxo-1-oxaspiro[2.5]octa-4-glucosyl)-6-hydroxy-1-benzofuran-3-one + O2 <=> 6-hydroxy-2-(4-glucosyl-phenoxymethylene)-benzofuran-3-one + H2O2 not assigned
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