|
|
gluconapin + O2 + reduced_acceptor <=> xi-progoitrin + H2O + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4343
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
MetaCyc:
RXN-11431
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)pentyl-thiohydroximate + pyruvate + NH3
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
| |
MetaCyc:
RXNQT-4319
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)pentyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11439
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19588
|
|
|
|
4-hydroxybutylglucosinolate + sinapoyl-CoA <=> 4-sinapoyloxybutylglucosinolate + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11449
|
|
|
|
(E)-5-(methylsulfanyl)pentanal_oxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> a_1-aci-nitro-omega-(methylthio)alkane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11415
|
|
|
|
glucoerucin + O2 + NADPH + H+ <=> 4-methylsulfinylbutylglucosinolate + H2O + NADP+
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
| |
BRENDA:
BS440251;
BS440869
MetaCyc:
RXNQT-4334
|
|
|
|
4-methylsulfinylbutylglucosinolate <=> 4-hydroxybutylglucosinolate
|
not assigned
|
–
|
| |
MetaCyc:
RXNQT-4340
|
|
|
|
UDP-glucose + (E)-omega-(methylsulfanyl)pentyl-thiohydroximate <=> H+ + desulfo-4-methylthiobutylglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
MetaCyc:
RXNQT-4324
|
|
|
|
4-methylsulfinylbutylglucosinolate + O2 <=> H+ + gluconapin + methanesulfonate
|
1.14.11.M8
|
–
|
| |
MetaCyc:
RXNQT-4341
|
|
|
|
L-dihomomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (E)-5-(methylsulfanyl)pentanal_oxime + H2O + CO2 + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
MetaCyc:
RXNQT-4309
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-4-methylthiobutylglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + glucoerucin
|
2.8.2
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BS407934
KEGG:
R08671
MetaCyc:
RXNQT-4329
|
|
|
|
4-hydroxybutylglucosinolate + benzoyl-CoA <=> 4-benzoyloxybutylglucosinolate + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11447
|
|
|
|
xi-progoitrin + benzoyl-CoA <=> 2-benzoyloxy-3-butenylglucosinolate + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11448
|
|
|
|
a_1-aci-nitro-omega-(methylthio)alkane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)pentan-1-imine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11423
|
|
|
|
xi-progoitrin + sinapoyl-CoA <=> 2-sinapoyloxy-3-butenylglucosinolate + CoA
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11450
|
|
