|
|
8-methylnonanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 1o-methyl-3-oxoundecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
| |
MetaCyc:
RXN-21690
|
|
|
|
6-methylheptanoyl-[acp] + NADP+ <=> (2E)-6-methylhept-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21684
|
|
|
|
L-valine + 2-oxoglutarate <=> L-glutamate + 2-oxoisovalerate
|
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.6
leucine transaminase
2.6.1.66
valine---pyruvate transaminase
|
–
–
–
–
|
| |
BRENDA:
BS356553
KEGG:
R01214
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERVAL-RXN
SABIO-RK:
1446
|
|
|
|
(3R)-3-hydroxy-10-methylundecanoyl-[acp] + NADP+ <=> 1o-methyl-3-oxoundecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21691
|
|
|
|
12-methyltridecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 14-methyl-3-oxopentadecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
| |
MetaCyc:
RXN-21701
|
|
|
|
10-methylundecanoyl-[acp] + NADP+ <=> (2E)-10-methylundec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21694
|
|
|
|
8-methylnonanoyl-[acyl-carrier_protein] + NADP+ <=> (2E)-8-methylnon-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21689
|
|
|
|
(3R)-3-hydroxy-12-methyltridecanoyl-[acp] <=> (2E)-12-methyltridec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21698
|
|
|
|
(3R)-3-hydroxy-12-methyltridecanoyl-[acp] + NADP+ <=> 12-methyl-3-oxotridecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21696
|
|
|
|
5-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 6-methyl-3-oxoheptanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
| |
MetaCyc:
RXN-21680
|
|
|
|
(3R)-3-hydroxy-14-methylpentadecanoyl-[acp] <=> (2E)-14-methylpentadec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21703
|
|
|
|
(3R)-3-hydroxy-6-methylheptanoyl-[acp] <=> (2E)-6-methylhept-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21682
|
|
|
|
6-methylheptanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 8-methyl-3-oxononanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
| |
MetaCyc:
RXN-21685
|
|
|
|
8-methylnonanoyl-[acyl-carrier_protein] + NAD+ <=> (2E)-8-methylnon-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21688
|
|
|
|
(3R)-3-hydroxy-4-methylpentanoyl-[acp] + NADP+ <=> 4-methyl-3-oxopentanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21676
|
|
|
|
(3R)-3-hydroxy-8-methylnonanoyl-[acp] + NADP+ <=> 8-methyl-3-oxononanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21686
|
|
|
|
(3R)-3-hydroxy-6-methylheptanoyl-[acp] + NADP+ <=> 6-methyl-3-oxoheptanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21681
|
|
|
|
10-methylundecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> 12-methyl-3-oxotridecanoyl-[acp] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
|
–
|
| |
MetaCyc:
RXN-21695
|
|
|
|
(3R)-3-hydroxy-10-methylundecanoyl-[acp] <=> (2E)-10-methylundec-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21692
|
|
|
|
(3R)-3-hydroxy-8-methylnonanoyl-[acp] <=> (2E)-8-methylnon-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21687
|
|
|
|
14-methylpentadecanoyl-[acp] + NADP+ <=> (2E)-14-methylpentadec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21705
|
|
|
|
12-methyltridecanoyl-[acp] + H2O <=> isomyristic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
| |
MetaCyc:
RXN-21714
|
|
|
|
10-methylundecanoyl-[acp] + NAD+ <=> (2E)-10-methylundec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21693
|
|
|
|
14-methylpentadecanoyl-[acp] + H2O <=> 14-methylpentadecanoate + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
| |
MetaCyc:
RXN-21706
|
|
|
|
isobutyryl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> 4-methyl-3-oxopentanoyl-[acp] + CoA + CO2
|
2.3.1.dr
|
–
|
| |
MetaCyc:
RXN-21611
|
|
|
|
(3R)-3-hydroxy-14-methylpentadecanoyl-[acp] + NADP+ <=> 14-methyl-3-oxopentadecanoyl-[acp] + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
| |
MetaCyc:
RXN-21702
|
|
|
|
12-methyltridecanoyl-[acp] + NADP+ <=> (2E)-12-methyltridec-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21700
|
|
|
|
2-oxoisovalerate + CoA + NAD+ <=> isobutyryl-CoA + CO2 + NADH
|
1.2.1.25
branched-chain alpha-keto acid dehydrogenase system
1.2.4.1
pyruvate dehydrogenase (acetyl-transferring)
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
2.7.11.4
[3-methyl-2-oxobutanoate dehydrogenase (acetyl-transferring)] kinase
|
–
–
–
–
|
| |
BRENDA:
BR36775
KEGG:
R01210
MetaCyc:
1.2.1.25-RXN
SABIO-RK:
1443;
1814
|
|
|
|
14-methylpentadecanoyl-[acp] + NAD+ <=> (2E)-14-methylpentadec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21704
|
|
|
|
12-methyltridecanoyl-[acp] + NAD+ <=> (2E)-12-methyltridec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21699
|
|
|
|
(3R)-3-hydroxy-4-methylpentanoyl-[acp] <=> (2E)-4-methylpent-2-enoyl-[acp] + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
| |
MetaCyc:
RXN-21677
|
|
|
|
6-methylheptanoyl-[acp] + NAD+ <=> (2E)-6-methylhept-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21683
|
|
|
|
5-methylhexanoyl-[acp] + NADP+ <=> (2E)-4-methylpent-2-enoyl-[acp] + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
|
–
|
| |
MetaCyc:
RXN-21679
|
|
|
|
5-methylhexanoyl-[acp] + NAD+ <=> (2E)-4-methylpent-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
MetaCyc:
RXN-21678
|
|
