|
|
1-hydroxy-2-phosphorylethylphosphonate + NAD+ <=> 1-oxo-2-phosphorylethylphosphonate + NADH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12009
|
|
|
|
S-adenosyl-L-methionine + hydrogen_(1S)-1-[(2S)-2-amino-4-methylpentanamido]ethylphosphonate <=> S-adenosyl-L-homocysteine + (1S)-1-[(2S)-2-amino-4-methylpentanamido]ethyl(methoxy)phosphinate
|
2.1.1.M5
|
–
|
|
MetaCyc:
RXN-21177
|
|
|
|
1-amino-2-phosphorylethylphosphonate + H2O + H+ <=> phosphonoacetaldehyde + phosphate + NH3
|
not assigned
|
–
|
|
MetaCyc:
RXN-21176
|
|
|
|
1-[(2S)-2-amino-4-methylpentanamido]ethenyl(methoxy)phosphinate + glycyl-[tRNAGly] <=> dehydrophos + tRNAMet + H+
|
2.3.2
|
–
|
|
MetaCyc:
RXN-12012
|
|
|
|
H+ + Phosphonopyruvate <=> phosphonoacetaldehyde + CO2
|
4.1.1.82
phosphonopyruvate decarboxylase
|
–
|
|
BRENDA:
BR48645
KEGG:
R04053
MetaCyc:
4.1.1.82-RXN
SABIO-RK:
3786
|
|
|
|
1,2-dihydroxyethylphosphonate + ATP <=> H+ + 1-hydroxy-2-phosphorylethylphosphonate + ADP
|
2.7.1
|
–
|
|
MetaCyc:
RXN-12007
|
|
|
|
2-hydroxyethylphosphonate + 2-oxoglutarate + O2 <=> 1,2-dihydroxyethylphosphonate + succinate + CO2
|
1.14.11
|
–
|
|
MetaCyc:
RXN-12008
|
|
|
|
phosphonoacetaldehyde + L-alanine <=> [(S)-1-aminoethyl]phosphonate + pyruvate + H+
|
not assigned
|
–
|
|
MetaCyc:
RXN-21175
|
|
|
|
[(S)-1-aminoethyl]phosphonate + L-leucyl-[tRNALeu] <=> hydrogen_(1S)-1-[(2S)-2-amino-4-methylpentanamido]ethylphosphonate + tRNALeu
|
2.3.2
|
–
|
|
MetaCyc:
RXN-12011
|
|
|
|
2-hydroxyethylphosphonate + NAD+ <=> phosphonoacetaldehyde + NADH + H+
|
1.1.1.309
phosphonoacetaldehyde reductase (NADH)
|
–
|
|
BRENDA:
BR49249
KEGG:
R09478
MetaCyc:
RXN-9009
|
|
|
|
(1S)-1-[(2S)-2-amino-4-methylpentanamido]ethyl(methoxy)phosphinate + 2-oxoglutarate + O2 <=> 1-[(2S)-2-amino-4-methylpentanamido]ethenyl(methoxy)phosphinate + succinate + CO2 + H2O
|
1.14.19
|
–
|
|
MetaCyc:
RXN-21178
|
|
|
|
H+ + phosphoenolpyruvate <=> Phosphonopyruvate
|
5.4.2.9
phosphoenolpyruvate mutase
|
–
|
|
BRENDA:
BR48374
KEGG:
R00661
MetaCyc:
PHOSPHOENOLPYRUVATE-MUTASE-RXN
|
|
|
|
1-amino-2-phosphorylethylphosphonate + 2-oxoglutarate <=> 1-oxo-2-phosphorylethylphosphonate + L-glutamate
|
2.6.1
|
–
|
|
MetaCyc:
RXN-12010
|
|