|
|
(5S)-5-hydroxycyclohex-1-ene-1-carbonyl-CoA + acceptor <=> (5R)-5-hydroxycyclohexa-1,3-diene-1-carbonyl-CoA + reduced_acceptor
|
1.3.1.M23
|
–
|
|
MetaCyc:
RXN-20420
|
|
|
|
(4R,5R)-4,5-dihydroxycyclohex-2-ene-1-carbonyl-CoA <=> (5R)-5-hydroxycyclohexa-1,3-diene-1-carbonyl-CoA + H2O
|
4.2.1.M28
|
–
|
|
MetaCyc:
RXN-20419
|
|
|
|
(4R,5R)-4,5-dihydroxycyclohex-2-ene-1-carbonyl-CoA + NADP+ <=> (3R,4R)-3,4-dihydroxycyclohexa-1,5-diene-1-carbonyl-CoA + NADPH + H+
|
1.3.1.120
cyclohexane-1-carbonyl-CoA reductase (NADP+)
|
–
|
|
MetaCyc:
RXN-20418
|
|
|
|
shikimate <=> (4R,5R)-4,5-dihydroxycyclohexa-1(6),2-diene-1-carboxylate + H2O
|
4.2.1.M27
|
–
|
|
MetaCyc:
RXN-20416
|
|
|
|
(4R,5R)-4,5-dihydroxycyclohexa-1(6),2-diene-1-carboxylate + CoA + ATP <=> (3R,4R)-3,4-dihydroxycyclohexa-1,5-diene-1-carbonyl-CoA + AMP + diphosphate
|
6.2.1.M35
|
–
|
|
MetaCyc:
RXN-20417
|
|
|
|
(3S)-3-hydroxycyclohexane-1-carbonyl-CoA <=> 2-cyclohexenylcarbonyl-CoA + H2O
|
not assigned
|
–
|
|
MetaCyc:
RXN-20422
|
|
|
|
(3S)-3-hydroxycyclohexane-1-carbonyl-CoA + NADP+ <=> (5S)-5-hydroxycyclohex-1-ene-1-carbonyl-CoA + NADPH + H+
|
1.3.1.120
cyclohexane-1-carbonyl-CoA reductase (NADP+)
|
–
|
|
MetaCyc:
RXN-20421
|
|
|
|
cyclohexanecarboxyl-CoA + NADP+ <=> cyclohex-1-ene-1-carbonyl-CoA + NADPH + H+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.120
cyclohexane-1-carbonyl-CoA reductase (NADP+)
|
–
–
|
|
BRENDA:
BR52779
KEGG:
R12453
MetaCyc:
RXN-20430
SABIO-RK:
13358
|
|
|
|
2-cyclohexenylcarbonyl-CoA <=> cyclohex-1-ene-1-carbonyl-CoA
|
5.3.3.M5
|
–
|
|
MetaCyc:
RXN-20423
|
|