|
|
18-hydroxy-9(10)-epoxystearic_acid + H2O <=> 9,10,18-trihydroxyoctadecanoic_acid
|
3.3.2
|
–
|
| |
KEGG:
R09464
MetaCyc:
RXN-1065
|
|
|
|
16-hydroxypalmitic_acid + NADP+ <=> 16-oxohexadecanoic_acid + NADPH + H+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-9802
|
|
|
|
16-oxohexadecanoic_acid + NADP+ + H2O <=> hexadecanedioic_acid + NADPH + H+
|
1.2.1
|
–
|
| |
MetaCyc:
RXN-9803
|
|
|
|
palmitate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 16-hydroxypalmitic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-16398
|
|
|
|
trans-9,10-epoxystearate + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 18-hydroxy-9(10)-epoxystearic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-9805
|
|
|
|
omega-hydroxy_oleic_acid + NADP+ <=> 18-Oxooleate + NADPH + H+
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-16416
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|
|
|
18-Oxooleate + NADP+ + H2O <=> Octadec-9-ene-1,18-dioic-acid + NADPH + H+
|
1.2.1
|
–
|
| |
MetaCyc:
RXN-16417
|
|
|
|
oleoyl-CoA + H2O <=> H+ + oleic_acid + CoA
|
2.3.1.9
acetyl-CoA C-acetyltransferase
3.1.1.1
carboxylesterase
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
|
–
–
–
–
–
–
|
| |
BRENDA:
BS115467
KEGG:
R08176
MetaCyc:
RXN-9666
SABIO-RK:
6580
|
|
|
|
hydroperoxy-fatty-acyl-[lipid] + omega-hydroxy_oleic_acid <=> 18-hydroxy-9(10)-epoxystearic_acid + a_hydroxy-fatty-acyl-[lipid]
|
1.11.2.3
plant seed peroxygenase
|
–
|
| |
MetaCyc:
RXN-1064
|
|
|
|
16-hydroxypalmitoyl-CoA + NADPH + O2 + H+ <=> 10,16-dihydroxypalmitoyl-CoA + NADP+ + H2O
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-1062
|
|
|
|
trans-9,10-epoxystearate + H2O <=> 9,10-dihydroxystearic_acid
|
3.3.2
3.3.2.10
soluble epoxide hydrolase
3.3.2.9
microsomal epoxide hydrolase
|
–
–
–
|
| |
BRENDA:
BS372731;
BS380351
KEGG:
R09465
MetaCyc:
RXN-9806
SABIO-RK:
7921
|
|
|
|
oleic_acid + hydroperoxy-fatty-acyl-[lipid] <=> trans-9,10-epoxystearate + a_hydroxy-fatty-acyl-[lipid]
|
1.11.2.3
plant seed peroxygenase
|
–
|
| |
MetaCyc:
RXN-9804
|
|
|
|
oleic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> omega-hydroxy_oleic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-16400
|
|
|
|
9,10-dihydroxystearic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 9,10,18-trihydroxyoctadecanoic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.80
long-chain fatty acid omega-monooxygenase
|
–
|
| |
MetaCyc:
RXN-9807
|
|
|
|
16-hydroxypalmitic_acid + CoA + ATP <=> 16-hydroxypalmitoyl-CoA + diphosphate + AMP
|
6.2.1.3
long-chain-fatty-acid---CoA ligase
|
–
|
| |
BRENDA:
BS379209
MetaCyc:
RXN-16389
SABIO-RK:
13099
|
|
