|
|
H+ + trihomocitrate + CoA <=> 2-oxopimelic_acid + acetyl-CoA + H2O
|
2.3.3
4.1.3
|
–
–
|
| |
KEGG:
R08332
MetaCyc:
R215-RXN
|
|
|
|
2-oxoglutarate + H2O + acetyl-CoA <=> H+ + (R)-2-hydroxybutane-1,2,4-tricarboxylate + CoA
|
2.3.3.14
homocitrate synthase
|
–
|
| |
BRENDA:
BR44122;
BS321812
KEGG:
R00271
MetaCyc:
HOMOCITRATE-SYNTHASE-RXN
SABIO-RK:
532
|
|
|
|
(-)-threo-iso(homo)3citrate + NAD+ <=> 2-Oxosuberate + CO2 + NADH
|
1.1.1
|
–
|
| |
KEGG:
R08215
MetaCyc:
R218-RXN
|
|
|
|
trihomocitrate <=> (Z)-hex-1-ene-1,2,6-tricarboxylate + H2O
|
4.2.1.114
methanogen homoaconitase
|
–
|
| |
BRENDA:
BS424131
KEGG:
R10395
MetaCyc:
R216-RXN
|
|
|
|
dihomocitrate + CoA + H+ <=> 2-oxoadipate + acetyl-CoA + H2O
|
2.3.3
4.1.3
|
–
–
|
| |
KEGG:
R08331
MetaCyc:
R211-RXN
|
|
|
|
H+ + 2-Oxosuberate <=> pimelic_semialdehyde + CO2
|
not assigned
|
–
|
| |
KEGG:
R08328
MetaCyc:
R224-RXN
|
|
|
|
(-)-threo-iso(homo)2citrate + NAD+ <=> 2-oxopimelic_acid + CO2 + NADH
|
1.1.1
|
–
|
| |
KEGG:
R08214
MetaCyc:
R214-RXN
|
|
|
|
dihomocitrate <=> (Z)-pent-1-ene-1,2,5-tricarboxylate + H2O
|
4.2.1.114
methanogen homoaconitase
|
–
|
| |
BRENDA:
BS423311
KEGG:
R10392
MetaCyc:
R212-RXN
|
|
|
|
7-Mercaptoheptanoate + L-threonine + ATP <=> H+ + 7-Mercaptoheptanoylthreonine + ADP + phosphate
|
not assigned
|
–
|
| |
KEGG:
R08323
MetaCyc:
R226-RXN
|
|
|
|
(Z)-hex-1-ene-1,2,6-tricarboxylate + H2O <=> (-)-threo-iso(homo)3citrate
|
4.2.1.114
methanogen homoaconitase
|
–
|
| |
BRENDA:
BS421928
KEGG:
R10396
MetaCyc:
R217-RXN
|
|
|
|
homoisocitrate <=> (Z)-but-1-ene-1,2,4-tricarboxylate + H2O
|
4.2.1.114
methanogen homoaconitase
4.2.1.36
homoaconitate hydratase
|
–
–
|
| |
BRENDA:
BR416
KEGG:
R04371
MetaCyc:
HOMOACONITATE-HYDRATASE-RXN
SABIO-RK:
4067
|
|
|
|
pimelic_semialdehyde + Sulfide + reduced_acceptor <=> 7-Mercaptoheptanoate + H2O + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
R225-RXN
|
|
|
|
(Z)-pent-1-ene-1,2,5-tricarboxylate + H2O <=> (-)-threo-iso(homo)2citrate
|
4.2.1.114
methanogen homoaconitase
|
–
|
| |
BRENDA:
BS421927
KEGG:
R10393
MetaCyc:
R213-RXN
|
|
|
|
(R)-2-hydroxybutane-1,2,4-tricarboxylate <=> (Z)-but-1-ene-1,2,4-tricarboxylate + H2O
|
4.2.1
4.2.1.114
methanogen homoaconitase
4.2.1.36
homoaconitate hydratase
|
–
–
–
|
| |
BRENDA:
BR49014;
BS1972
KEGG:
R03444
MetaCyc:
RXN3O-1983
SABIO-RK:
3238
|
|
|
|
homoisocitrate + NAD+ <=> 2-oxoadipate + CO2 + NADH
|
1.1.1.286
isocitrate---homoisocitrate dehydrogenase
1.1.1.42
isocitrate dehydrogenase (NADP+)
1.1.1.87
homoisocitrate dehydrogenase
|
–
–
–
|
| |
BRENDA:
BR48021
KEGG:
R01934
MetaCyc:
RXN-7970
SABIO-RK:
1988
|
|
|
|
7-Mercaptoheptanoylthreonine + ATP <=> H+ + coenzyme_B + ADP
|
2.7.1
|
–
|
| |
KEGG:
R08217
MetaCyc:
R227-RXN
|
|
