|
|
cis-geranyl-CoA + HCO3- + ATP <=> 3-(4-methylpent-3-en-1-yl)pent-2-enedioyl-CoA + phosphate + ADP + H+
|
6.4.1.5
geranoyl-CoA carboxylase
|
–
|
| |
BRENDA:
BR157
KEGG:
R03494
MetaCyc:
GERANOYL-COA-CARBOXYLASE-RXN
|
|
|
|
3-Hydroxy-3-(4-methylpent-3-en-1-yl)glutaryl-CoA <=> 3-(4-methylpent-3-en-1-yl)pent-2-enedioyl-CoA + H2O
|
4.2.1.57
isohexenylglutaconyl-CoA hydratase
|
–
|
| |
BRENDA:
BR435
KEGG:
R03493
MetaCyc:
ISOHEXENYLGLUTACONYL-COA-HYDRATASE-RXN
|
|
|
|
5-methylhex-4-enoyl-CoA + acceptor <=> (2E)-5-methylhexa-2,4-dienoyl-CoA + reduced_acceptor
|
1.3.99
|
–
|
| |
MetaCyc:
RXN-11918
|
|
|
|
(2E)-5-methylhexa-2,4-dienoyl-CoA + H2O <=> 3-hydroxy-5-methylhex-4-enoyl-CoA
|
4.2.1
4.2.1.17
enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BS417818
KEGG:
R08093
MetaCyc:
RXN-11919
|
|
|
|
3-Hydroxy-3-(4-methylpent-3-en-1-yl)glutaryl-CoA <=> 7-methyl-3-oxooct-6-enoyl-CoA + acetate
|
4.1.3.26
3-hydroxy-3-isohexenylglutaryl-CoA lyase
4.1.3.4
hydroxymethylglutaryl-CoA lyase
|
–
–
|
| |
BRENDA:
BR387
KEGG:
R08090
MetaCyc:
4.1.3.26-RXN
|
|
|
|
3-hydroxy-5-methylhex-4-enoyl-CoA + acceptor <=> 5-methyl-3-oxo-4-hexenoyl-CoA + reduced_acceptor
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-11920
|
|
|
|
CoA + acetate + ATP <=> acetyl-CoA + diphosphate + AMP
|
6.2.1.1
acetate---CoA ligase
6.2.1.17
propionate---CoA ligase
6.2.1.36
3-hydroxypropionyl-CoA synthase
|
–
–
–
|
| |
BRENDA:
BR60
KEGG:
R00235
MetaCyc:
ACETATE--COA-LIGASE-RXN
SABIO-RK:
179
|
|
|
|
7-methyl-3-oxooct-6-enoyl-CoA + CoA <=> 5-methylhex-4-enoyl-CoA + acetyl-CoA
|
2.3.1
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BS417874
KEGG:
R08091
MetaCyc:
RXN-11917
|
|
|
|
5-methyl-3-oxo-4-hexenoyl-CoA + CoA <=> 3-methylcrotonoyl-CoA + acetyl-CoA
|
2.3.1
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BS417867
KEGG:
R08095
MetaCyc:
RXN-11921
|
|
