|
|
3-amino-5-hydroxybenzoate + ATP + polyketide-[acp] <=> 3-amino-5-hydroxybenzoyl-[chaxamycin_PKS] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20291
|
|
|
|
3-amino-5-hydroxybenzoyl-[chaxamycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> tetraketide-[chaxamycin_PKS] + CoA + NADP+ + CO2
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20290
|
|
|
|
S-adenosyl-L-methionine + 3-demethylchaxamycin_B <=> S-adenosyl-L-homocysteine + chaxamycin_B + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-20294
|
|
|
|
25-acetylchaxamycin_C + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> chaxamycin_D + CO2 + H2O + oxidized_ferredoxin
|
1.14.15
|
–
|
| |
MetaCyc:
RXN-20295
|
|
|
|
prochaxamycin + acceptor <=> 3-demethylchaxamycin_A + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20284
|
|
|
|
S-adenosyl-L-methionine + 3-demethylchaxamycin_A <=> S-adenosyl-L-homocysteine + chaxamycin_A + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-20283
|
|
|
|
7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[chaxamycin_PKS] + acceptor <=> 7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[chaxamycin_PKS] + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20288
|
|
|
|
tetraketide-[chaxamycin_PKS] + O2 + NADPH + H+ <=> 7-(3-amino-2,5-dihydroxyphenyl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[chaxamycin_PKS] + H2O + NADP+
|
1.14.13.M73
|
–
|
| |
MetaCyc:
RXN-20289
|
|
|
|
chaxamycin_A + O2 + reduced_ferredoxin_[iron-sulfur]_cluster + H+ <=> chaxamycin_C + H2O + oxidized_ferredoxin
|
1.14.15
|
–
|
| |
MetaCyc:
RXN-20292
|
|
|
|
prochaxamycin <=> 3-demethylchaxamycin_B + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20293
|
|
|
|
undecaketide-[chaxamycin-PKS] <=> prochaxamycin + polyketide-[acp]
|
2.3.1.M74
|
–
|
| |
MetaCyc:
RXN-20286
|
|
|
|
acetyl-CoA + chaxamycin_C <=> 25-acetylchaxamycin_C + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20296
|
|
|
|
7-(5-amino-3,6-dioxocyclohexa-1,4-dien-1-yl)-7-hydroxy-2,6-dimethyl-3,5-dioxoheptanoyl-[chaxamycin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> undecaketide-[chaxamycin-PKS] + CoA + NADP+ + CO2 + H2O
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-20287
|
|
