|
|
hexanoyl-CoA + malonyl-CoA + H+ <=> 3,5-dioxodecanoyl-CoA + CoA + CO2
|
not assigned
|
–
|
|
MetaCyc:
RXN-13662
|
|
|
|
hexanoate + ATP + CoA <=> hexanoyl-CoA + AMP + diphosphate
|
6.2.1.1
acetate---CoA ligase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.44
3-(methylthio)propionyl---CoA ligase
|
–
–
–
–
–
|
|
BRENDA:
BR71
KEGG:
R00389
MetaCyc:
RXN-14172
SABIO-RK:
8094
|
|
|
|
3,5,7-trioxododecanoyl-CoA <=> CoA + 2,4-dihydroxy-6-pentylbenzoate + H+
|
4.4.1.26
olivetolic acid cyclase
|
–
|
|
BRENDA:
BR50339
KEGG:
R10278
MetaCyc:
RXN-13612
|
|
|
|
H+ + cannabidiolate <=> cannabidiol + CO2
|
not assigned
|
–
|
|
KEGG:
R12103
MetaCyc:
RXN-7858
|
|
|
|
3,5-dioxodecanoyl-CoA + malonyl-CoA + H+ <=> 3,5,7-trioxododecanoyl-CoA + CoA + CO2
|
not assigned
|
–
|
|
MetaCyc:
RXN-13663
|
|
|
|
H+ + DELTA9-tetrahydrocannabinolate <=> DELTA9-tetrahydrocannabinol + CO2
|
not assigned
|
–
|
|
KEGG:
R12102
MetaCyc:
RXN-7857
|
|
|
|
geranyl_diphosphate + 2,4-dihydroxy-6-pentylbenzoate <=> cannabigerolate + diphosphate
|
2.5.1.102
geranyl-pyrophosphate---olivetolic acid geranyltransferase
|
–
|
|
BRENDA:
BR50302
KEGG:
R10176
MetaCyc:
RXN-7853
|
|
|
|
cannabigerolate + acceptor <=> cannabichromenate + reduced_acceptor
|
1.21.99
|
–
|
|
MetaCyc:
RXN-7856
|
|
|
|
cannabigerolate + O2 <=> DELTA9-tetrahydrocannabinolate + H2O2
|
1.21.3.7
tetrahydrocannabinolic acid synthase
|
–
|
|
BRENDA:
BR50269
KEGG:
R12101
MetaCyc:
RXN-7854
|
|
|
|
H+ + cannabichromenate <=> cannabichromene + CO2
|
not assigned
|
–
|
|
MetaCyc:
RXN-7859
|
|
|
|
cannabigerolate + O2 <=> cannabidiolate + H2O2
|
1.21.3.3
reticuline oxidase
1.21.3.8
cannabidiolic acid synthase
|
–
–
|
|
BRENDA:
BR50270;
BS443261
KEGG:
R10160
MetaCyc:
RXN-7855
|
|