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avenanthramide biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate 6.2.1.12 4-coumarate---CoA ligase
6.2.1.2 medium-chain acyl-CoA ligase
6.2.1.30 phenylacetate---CoA ligase



trans-5-O-caffeoylshikimate + CoA <=> caffeoyl-CoA + shikimate 2.3.1
2.3.1.133 shikimate O-hydroxycinnamoyltransferase
2.3.1.99 quinate O-hydroxycinnamoyltransferase



caffeoyl-CoA + 5-hydroxyanthranilate <=> avenanthramide_C + CoA 2.3.1.dt

Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase] 1.14.14.91 trans-cinnamate 4-monooxygenase

4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA 2.3.1.133 shikimate O-hydroxycinnamoyltransferase
2.3.1.140 rosmarinate synthase
2.3.1.99 quinate O-hydroxycinnamoyltransferase



4-coumaroyl-CoA + 5-hydroxyanthranilate <=> avenanthramide_A + CoA 2.3.1.dt

4-coumaroylshikimate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> trans-5-O-caffeoylshikimate + oxidized_[NADPH-hemoprotein_reductase] + H2O 1.14.14.96 5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase

L-phenylalanine <=> Cinnamic_acid + NH3 4.3.1.1 aspartate ammonia-lyase
4.3.1.23 tyrosine ammonia-lyase
4.3.1.24 phenylalanine ammonia-lyase
4.3.1.25 phenylalanine/tyrosine ammonia-lyase
4.3.1.31 L-tryptophan ammonia lyase
4.3.1.5 phenylalanine ammonia-lyase






S-adenosyl-L-methionine + avenanthramide_C <=> avenanthramide_B + S-adenosyl-L-homocysteine + H+ 2.1.1.104 caffeoyl-CoA O-methyltransferase

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