|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
| |
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
trans-5-O-caffeoylshikimate + CoA <=> caffeoyl-CoA + shikimate
|
2.3.1
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BS320440
KEGG:
R07433
MetaCyc:
RXN-2621
|
|
|
|
caffeoyl-CoA + 5-hydroxyanthranilate <=> avenanthramide_C + CoA
|
2.3.1.dt
|
–
|
| |
MetaCyc:
RXN-21513
|
|
|
|
Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
| |
MetaCyc:
TRANS-CINNAMATE-4-MONOOXYGENASE-RXN
|
|
|
|
4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.140
rosmarinate synthase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BR43994
KEGG:
R02416
MetaCyc:
2.3.1.133-RXN
|
|
|
|
4-coumaroyl-CoA + 5-hydroxyanthranilate <=> avenanthramide_A + CoA
|
2.3.1.dt
|
–
|
| |
MetaCyc:
RXN-21512
|
|
|
|
4-coumaroylshikimate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> trans-5-O-caffeoylshikimate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
MetaCyc:
RXN-2581
|
|
|
|
L-phenylalanine <=> Cinnamic_acid + NH3
|
4.3.1.1
aspartate ammonia-lyase
4.3.1.23
tyrosine ammonia-lyase
4.3.1.24
phenylalanine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
4.3.1.31
L-tryptophan ammonia lyase
4.3.1.5
phenylalanine ammonia-lyase
|
–
–
–
–
–
–
|
| |
BRENDA:
BR3427;
BS445625
KEGG:
R00697
MetaCyc:
PHENYLALANINE-AMMONIA-LYASE-RXN
SABIO-RK:
1076
|
|
|
|
S-adenosyl-L-methionine + avenanthramide_C <=> avenanthramide_B + S-adenosyl-L-homocysteine + H+
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
| |
MetaCyc:
RXN-21514
|
|
