|
|
(S)-2-methylbutanoyl-CoA + D-alanyl-3-O-methylprotoansatrienin <=> trienomycin_B + CoA + H+
|
2.3.1.dp
|
–
|
| |
MetaCyc:
RXN-20431
|
|
|
|
L-alanine <=> D-alanine
|
2.6.1.21
D-amino-acid transaminase
5.1.1.1
alanine racemase
5.1.1.10
amino-acid racemase
5.1.1.12
ornithine racemase
5.1.1.13
aspartate racemase
5.1.1.15
2-aminohexano-6-lactam racemase
5.1.1.18
serine racemase
5.1.1.8
4-hydroxyproline epimerase
5.1.1.9
arginine racemase
|
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR162
KEGG:
R00401
MetaCyc:
ALARACECAT-RXN
SABIO-RK:
862
|
|
|
|
3-amino-5-hydroxybenzoate + ATP + polyketide-[acp] <=> 3-amino-5-hydroxybenzoyl-[ansatrienin_PKS] + AMP + diphosphate
|
6.2.1.al
|
–
|
| |
MetaCyc:
RXN-20329
|
|
|
|
3-amino-5-hydroxybenzoyl-[ansatrienin_PKS] + (S)-methylmalonyl-CoA + malonyl-CoA + NADPH + H+ <=> nonaketide-[ansatrienin_PKS] + CoA + NADP+ + CO2 + H2O
|
2.3.1.M77
|
–
|
| |
MetaCyc:
RXN-20327
|
|
|
|
ATP + D-alanine + holo-[D-alanyl-carrier_protein] <=> D-alanyl-[D-alanyl-carrier_protein] + AMP + diphosphate
|
6.2.1.54
D-alanine---[D-alanyl-carrier protein] ligase
|
–
|
| |
BRENDA:
BR52380
MetaCyc:
RXN-18014
|
|
|
|
nonaketide-[ansatrienin_PKS] <=> protoansatrienin + polyketide-[acp]
|
2.3.1.M78
|
–
|
| |
MetaCyc:
RXN-20328
|
|
|
|
D-alanyl-[D-alanyl-carrier_protein] + 3-O-methylprotoansatrienin <=> holo-[D-alanyl-carrier_protein] + D-alanyl-3-O-methylprotoansatrienin
|
2.3.2.v
|
–
|
| |
MetaCyc:
RXN-20415
|
|
|
|
cyclohexanecarboxyl-CoA + D-alanyl-3-O-methylprotoansatrienin <=> trienomycin_A + CoA + H+
|
2.3.1.dp
|
–
|
| |
MetaCyc:
RXN-20424
|
|
|
|
S-adenosyl-L-methionine + protoansatrienin <=> S-adenosyl-L-homocysteine + 3-O-methylprotoansatrienin + H+
|
2.1.1.M52
|
–
|
| |
MetaCyc:
RXN-20425
|
|
