|
|
NADP+ + 3-oxo-2((2Z)-pentenyl)-cyclopentane-1-octanoic_acid <=> H+ + NADPH + 12-oxo-phytodienoic_acid
|
1.3.1.42
12-oxophytodienoate reductase
|
–
|
| |
BRENDA:
BR36824
KEGG:
R03401
MetaCyc:
12-OXOPHYTODIENOATE-REDUCTASE-RXN
|
|
|
|
linolenic_acid + reduced_acceptor + O2 <=> stearidonic_acid + A + H2O
|
1.14.19
1.14.19.3
acyl-CoA 6-desaturase
|
–
–
|
| |
BRENDA:
BS287979
KEGG:
R07861
|
|
|
|
3-Hydroxy-OPC4-CoA + NAD+ <=> 3-Oxo-OPC4-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
KEGG:
R07898
|
|
|
|
OPC4-CoA + FAD <=> trans-2-Enoyl-OPC4-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
| |
KEGG:
R07896
|
|
|
|
S-adenosyl-L-methionine + jasmonic_acid <=> S-adenosyl-L-homocysteine + methyl_jasmonate
|
2.1.1.141
jasmonate O-methyltransferase
2.1.1.274
salicylate 1-O-methyltransferase
2.1.1.B126
|
–
–
–
|
| |
BRENDA:
BR48123
KEGG:
R05759
MetaCyc:
RXN-10768
SABIO-RK:
5352
|
|
|
|
3-Hydroxy-OPC8-CoA <=> trans-2-Enoyl-OPC8-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
KEGG:
R07889
|
|
|
|
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate + H2O <=> 9-Hydroxy-12-oxo-10(E),15(Z)-octadecadienoic_acid
|
not assigned
|
–
|
| |
KEGG:
R12140
|
|
|
|
phosphatidylcholine + H2O <=> lysophosphatidylcholine + linolenic_acid
|
3.1.1.4
phospholipase A2
|
–
|
| |
KEGG:
R07859
|
|
|
|
acetyl-CoA + (3Z)-hex-3-en-ol <=> cis-3-hexen-1-yl_acetate + CoA
|
2.3.1.195
(Z)-3-hexen-1-ol acetyltransferase
2.3.1.224
acetyl-CoA-benzylalcohol acetyltransferase
2.3.1.84
alcohol O-acetyltransferase
|
–
–
–
|
| |
BRENDA:
BR49455
KEGG:
R09631
MetaCyc:
RXN-11852
SABIO-RK:
14832
|
|
|
|
3-Hydroxy-OPC8-CoA + NAD+ <=> 3-Oxo-OPC8-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
KEGG:
R07890
|
|
|
|
12-oxododecenoic_acid <=> traumatin
|
5.3.3
|
–
|
| |
KEGG:
R07872
MetaCyc:
RXN-1349
|
|
|
|
3-oxo-2((2Z)-pentenyl)-cyclopentane-1-octanoic_acid + CoA + ATP <=> 3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-octanoyl-CoA + AMP + diphosphate
|
6.2.1
|
–
|
| |
KEGG:
R07887
MetaCyc:
RXN-10695
|
|
|
|
(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate <=> H2O + (9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate
|
4.2.1.92
hydroperoxide dehydratase
|
–
|
| |
BRENDA:
BR48341;
BS363380
KEGG:
R07863
MetaCyc:
RXN1F-19
|
|
|
|
(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate <=> 12-oxododecenoic_acid + cis-3-hexenal
|
4.2.1.M17
4.2.1.M19
|
–
–
|
| |
KEGG:
R07870
MetaCyc:
RXN-1345
|
|
|
|
9,10-EOT <=> 10-OPDA
|
not assigned
|
–
|
| |
KEGG:
R07866
|
|
|
|
phosphatidylcholine + H2O <=> 2-acylglycerophosphocholine + linolenic_acid
|
3.1.1.32
phospholipase A1
|
–
|
| |
KEGG:
R07860
|
|
|
|
linolenic_acid + O2 <=> (9S,10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoate
|
1.13.11.12
linoleate 13S-lipoxygenase
1.13.11.58
linoleate 9S-lipoxygenase
|
–
–
|
| |
BRENDA:
BS408370
KEGG:
R07864
MetaCyc:
RXN-8497
|
|
|
|
OPC6-CoA + FAD <=> trans-2-Enoyl-OPC6-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
| |
KEGG:
R07892
|
|
|
|
3-Hydroxy-OPC6-CoA <=> trans-2-Enoyl-OPC6-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
KEGG:
R07893
|
|
|
|
(9S,10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoate <=> colnelenic_acid + H2O
|
4.2.1.121
colneleate synthase
|
–
|
| |
BRENDA:
BS407614
KEGG:
R07867
MetaCyc:
RXN-8498
|
|
|
|
(9Z)-(13S)-12,13-epoxyoctadeca-9,11,15-trienoate <=> 12-oxo-phytodienoic_acid
|
5.3.99.6
allene-oxide cyclase
|
–
|
| |
BRENDA:
BR13;
BS1153
KEGG:
R03402
MetaCyc:
ALLENE-OXIDE-CYCLASE-RXN
|
|
|
|
(+)-7-Isojasmonate_CoA + acetyl-CoA <=> 3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-(3-oxobutanoyl)-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
| |
KEGG:
R07899
MetaCyc:
RXN-10701
|
|
|
|
9-Hydroxy-12-oxo-10(E),15(Z)-octadecadienoic_acid + NADPH + H+ <=> 9-Hydroxy-12-oxo-15(Z)-octadecenoic_acid + NADP+
|
1.3.1
|
–
|
| |
KEGG:
R12141
|
|
|
|
3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-butanoyl-CoA + acetyl-CoA <=> 3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-(3-oxohexanoyl)-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
| |
KEGG:
R07895
MetaCyc:
RXN-10700
|
|
|
|
OPC8-CoA + FAD <=> trans-2-Enoyl-OPC8-CoA + FADH2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
| |
KEGG:
R07888
|
|
|
|
(9S,10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoate <=> 9,10-EOT + H2O
|
4.2.1.92
hydroperoxide dehydratase
|
–
|
| |
KEGG:
R07865
MetaCyc:
RXN-8500
|
|
|
|
(9S,10E,12Z,15Z)-9-hydroperoxy-10,12,15-octadecatrienoate <=> 9-Oxononanoate + 3,6-Nonadienal
|
not assigned
|
–
|
| |
KEGG:
R07868
|
|
|
|
3-Hydroxy-OPC6-CoA + NAD+ <=> 3-Oxo-OPC6-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
KEGG:
R07894
|
|
|
|
3-Hydroxy-OPC4-CoA <=> trans-2-Enoyl-OPC4-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
KEGG:
R07897
|
|
|
|
O2 + linolenic_acid <=> (9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate
|
1.13.11.12
linoleate 13S-lipoxygenase
1.13.11.45
linoleate 11-lipoxygenase
|
–
–
|
| |
BRENDA:
BR50226;
BS186660
KEGG:
R07869
MetaCyc:
RXN-1321
SABIO-RK:
9850
|
|
|
|
(3Z)-hex-3-en-ol + NAD+ <=> cis-3-hexenal + NADH + H+
|
1.1.1.1
alcohol dehydrogenase
|
–
|
| |
KEGG:
R10783
MetaCyc:
RXN-1347
|
|
|
|
(+)-7-Isojasmonate_CoA + H2O <=> H+ + (+)-7-Isojasmonate + CoA
|
3.1.2.20
acyl-CoA hydrolase
3.2.1
|
–
–
|
| |
KEGG:
R07902
MetaCyc:
RXN-10708
|
|
|
|
3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-hexanoyl-CoA + acetyl-CoA <=> 3-oxo-2-(cis-2''-pentenyl)-cyclopentane-1-(3-oxooctanoyl)-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
| |
KEGG:
R07891
MetaCyc:
RXN-10699
|
|
