|
|
17-O-acetylnorajmaline + NADP+ <=> 1,2-dihydrovomilenine + NADPH + H+
|
1.3.1.73
1,2-dihydrovomilenine reductase
|
–
|
| |
BRENDA:
BR40540
KEGG:
R05879
MetaCyc:
1.3.1.73-RXN
|
|
|
|
S-adenosyl-L-methionine + 17-O-acetylnorajmaline <=> 17-O-acetylajmaline + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R12138
MetaCyc:
RXN-8219
|
|
|
|
UDP-glucose + Vomilenine <=> H+ + Raucaffricine + UDP
|
2.4.1.219
vomilenine glucosyltransferase
|
–
|
| |
BRENDA:
BR44195
KEGG:
R05882
MetaCyc:
2.4.1.219-RXN
|
|
|
|
Vomilenine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> perakine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.104
vinorine hydroxylase
|
–
|
| |
MetaCyc:
RXN-19991
|
|
|
|
21-epi-vomilenine <=> Vomilenine
|
not assigned
|
–
|
| |
MetaCyc:
RXN-19992
|
|
|
|
(20alphaS)-19,20--dihydrovomilenine + NADP+ <=> Vomilenine + NADPH + H+
|
1.3.1.M19
|
–
|
| |
MetaCyc:
RXN-19993
|
|
|
|
raucaffrinoline + NADP+ <=> perakine + NADPH + H+
|
1.1.1.317
perakine reductase
|
–
|
| |
BRENDA:
BR49869
KEGG:
R09806
MetaCyc:
RXN-12673
|
|
|
|
gardneral + acetyl-CoA <=> vinorine + CoA
|
2.3.1.160
vinorine synthase
|
–
|
| |
BRENDA:
BR44010
KEGG:
R05876
MetaCyc:
2.3.1.160-RXN
|
|
|
|
strictosidine_aglycone <=> cathenamine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-8223
|
|
|
|
17-O-acetylajmaline + H2O <=> ajmaline + acetate + H+
|
3.1.1.80
acetylajmaline esterase
|
–
|
| |
BRENDA:
BR48751
KEGG:
R07513
MetaCyc:
RXN-8222
|
|
|
|
10-deoxysarpagine + NADP+ <=> gardneral + NADPH + H+
|
1.1.1.273
vellosimine dehydrogenase
|
–
|
| |
BRENDA:
BR40502
KEGG:
R05827
MetaCyc:
1.1.1.273-RXN
|
|
|
|
19E-geissoschizine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> polyneuridine_aldehyde + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.M24
|
–
|
| |
MetaCyc:
RXN-8224
|
|
|
|
S-adenosyl-L-methionine + norajmaline <=> ajmaline + S-adenosyl-L-homocysteine + H+
|
2.1.1.M48
|
–
|
| |
KEGG:
R05881
MetaCyc:
RXN-8221
|
|
|
|
H2O + polyneuridine_aldehyde <=> methanol + CO2 + gardneral
|
3.1.1.78
polyneuridine-aldehyde esterase
|
–
|
| |
BRENDA:
BR47579
KEGG:
R05825
MetaCyc:
3.1.1.78-RXN
|
|
|
|
10-deoxysarpagine + reduced_[NADPH-hemoprotein_reductase] + O2 <=> sarpagine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.136
deoxysarpagine hydroxylase
|
–
|
| |
MetaCyc:
1.14.13.91-RXN
|
|
|
|
17-O-acetylnorajmaline + H2O <=> norajmaline + acetate + H+
|
3.1.1.80
acetylajmaline esterase
|
–
|
| |
BRENDA:
BR48752
KEGG:
R05880
MetaCyc:
RXN-8220
|
|
|
|
cathenamine <=> 4,21-Dehydrogeissoschizine
|
not assigned
|
–
|
| |
KEGG:
R05846
MetaCyc:
RXN-19979
|
|
|
|
vinorine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 21-epi-vomilenine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.104
vinorine hydroxylase
|
–
|
| |
MetaCyc:
1.14.13.75-RXN
|
|
|
|
17-O-acetylnorajmaline + NADP+ <=> (20alphaS)-19,20--dihydrovomilenine + NADPH + H+
|
1.5.1
|
–
|
| |
MetaCyc:
RXN-19994
|
|
|
|
strictosidine + H2O <=> strictosidine_aglycone + D-glucose
|
3.2.1.105
3alpha(S)-strictosidine beta-glucosidase
3.2.1.125
raucaffricine beta-glucosidase
|
–
–
|
| |
BRENDA:
BR15979
KEGG:
R03820
MetaCyc:
STRICTOSIDINE-BETA-GLUCOSIDASE-RXN
|
|
|
|
1,2-dihydrovomilenine + NADP+ <=> Vomilenine + NADPH + H+
|
1.5.1.32
vomilenine reductase
|
–
|
| |
BRENDA:
BR40354
KEGG:
R05878
MetaCyc:
1.5.1.32-RXN
|
|
|
|
19E-geissoschizine + NADP+ <=> 4,21-Dehydrogeissoschizine + NADPH
|
1.3.1.36
geissoschizine dehydrogenase
|
–
|
| |
MetaCyc:
GEISSOSCHIZINE-DEHYDROGENASE-RXN
|
|
|
|
gardneral <=> gardneral
|
not assigned
|
–
|
| |
KEGG:
R05826
MetaCyc:
RXN-8225
|
|
