|
|
(S)-2-methylbutanoyl-CoA + malonyl-CoA + H+ <=> 2-methyl-1-[2,4,6-trihydroxy-3-(3-methylbut-2-en-1-yl)phenyl]butan-1-one + CO2 + CoA
|
2.3.1.156
phloroisovalerophenone synthase
|
–
|
| |
MetaCyc:
RXN-18439
|
|
|
|
ATP + 2-methylbutanoate + CoA <=> diphosphate + AMP + (S)-2-methylbutanoyl-CoA
|
6.2.1.1
acetate---CoA ligase
|
–
|
| |
MetaCyc:
RXN-18448
|
|
|
|
dimethylallyl_diphosphate + 2-methyl-1-[2,4,6-trihydroxy-3-(3-methylbut-2-en-1-yl)phenyl]butan-1-one <=> diphosphate + 4-prenylphlormethylbutanophenone + H+
|
2.5.1.136
2-acylphloroglucinol 4-prenyltransferase
|
–
|
| |
MetaCyc:
RXN-18442
|
|
|
|
dimethylallyl_diphosphate + 4-prenylphlormethylbutanophenone <=> diphosphate + deoxyadlupulone
|
2.5.1.137
2-acyl-4-prenylphloroglucinol 6-prenyltransferase
|
–
|
| |
MetaCyc:
RXN-18445
|
|
|
|
dimethylallyl_diphosphate + deoxyadlupulone <=> diphosphate + adlupulone
|
2.5.1.137
2-acyl-4-prenylphloroglucinol 6-prenyltransferase
|
–
|
| |
MetaCyc:
RXN-18450
|
|
|
|
deoxyadlupulone + O2 + reduced_acceptor <=> adhumulone + H2O + acceptor
|
1.14.99.M4
|
–
|
| |
MetaCyc:
RXN-18452
|
|
