|
|
1-(3,4-Dihydroxyphenyl)-1-decene-3,5-dione <=> 1-(3,4-Dihydroxyphenyl)-5-hydroxy-3-decanone
|
not assigned
|
–
|
| |
KEGG:
R08799
|
|
|
|
trans-5-O-caffeoylshikimate + CoA <=> caffeoyl-CoA + shikimate
|
2.3.1
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BS320440
KEGG:
R07433
MetaCyc:
RXN-2621
|
|
|
|
feruloyl-CoA + malonyl-CoA + hexanoyl-CoA + H2O <=> 1-Dehydro-[6]-gingerdione + 3 CoA + 2 CO2
|
not assigned
|
–
|
| |
KEGG:
R08797
|
|
|
|
H+ + feruloyl-CoA + malonyl-CoA <=> feruloylacetyl-CoA + CoA + CO2
|
2.3.1.218
phenylpropanoylacetyl-CoA synthase
|
–
|
| |
BRENDA:
BR50410
KEGG:
R08806
MetaCyc:
RXN-11221
|
|
|
|
S-adenosyl-L-methionine + 1-(3,4-Dihydroxyphenyl)-5-hydroxy-3-decanone <=> [6]-gingerol + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R08804
MetaCyc:
RXN-12527
|
|
|
|
4-coumaroyl-CoA <=> caffeoyl-CoA
|
1.14.13
|
–
|
| |
KEGG:
R07436
|
|
|
|
1-(3,4-Dihydroxyphenyl)-1-decene-3,5-dione + S-adenosyl-L-methionine <=> 1-Dehydro-[6]-gingerdione + S-adenosyl-L-homocysteine
|
2.1.1
|
–
|
| |
KEGG:
R08803
|
|
|
|
malonyl-CoA + cinnamoyl-CoA + H+ <=> CoA + pinosylvin + CO2
|
2.3.1.146
pinosylvin synthase
2.3.1.95
trihydroxystilbene synthase
|
–
–
|
| |
BRENDA:
BR47494
KEGG:
R02505
MetaCyc:
PINOSYLVIN-SYNTHASE-RXN
SABIO-RK:
2432
|
|
|
|
S-adenosyl-L-methionine + resveratrol <=> S-adenosyl-L-homocysteine + pterostilbene + H+
|
2.1.1.240
trans-resveratrol di-O-methyltransferase
|
–
|
| |
BRENDA:
BR49881
KEGG:
R09872
MetaCyc:
RXN-12805
|
|
|
|
5-Hydroxy-1-(4-hydroxyphenyl)-3-decanone <=> 1-(3,4-Dihydroxyphenyl)-5-hydroxy-3-decanone
|
not assigned
|
–
|
| |
KEGG:
R08802
|
|
|
|
bisdemethoxycurcumin <=> demethoxycurcumin
|
not assigned
|
–
|
| |
KEGG:
R08811
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + hexanoyl-CoA + H2O <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)deca-1,4-dien-3-one + 3 CoA + 2 CO2
|
not assigned
|
–
|
| |
KEGG:
R08796
|
|
|
|
4-coumaroyl-CoA + (4-coumaroyl)acetyl-CoA + H2O <=> bisdemethoxycurcumin + CoA + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
| |
BRENDA:
BR50413
KEGG:
R08807
MetaCyc:
RXN-11223
|
|
|
|
1-Dehydro-[6]-gingerdione <=> [6]-gingerol
|
not assigned
|
–
|
| |
KEGG:
R08800
|
|
|
|
resveratrol <=> piceatannol
|
1.14
|
–
|
| |
KEGG:
R04257
|
|
|
|
4-coumaroyl-CoA + feruloylacetyl-CoA + H2O <=> demethoxycurcumin + CoA + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
| |
BRENDA:
BR50412
KEGG:
R08809
MetaCyc:
RXN-11225
|
|
|
|
(1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)deca-1,4-dien-3-one <=> 1-(3,4-Dihydroxyphenyl)-1-decene-3,5-dione
|
not assigned
|
–
|
| |
KEGG:
R08801
|
|
|
|
cinnamoyl-CoA + reduced_flavodoxin + O2 <=> 4-coumaroyl-CoA + flavin + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
| |
KEGG:
R08815
|
|
|
|
4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.140
rosmarinate synthase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BR43994
KEGG:
R02416
MetaCyc:
2.3.1.133-RXN
|
|
|
|
4-coumaroylshikimate + reduced_flavodoxin + O2 <=> trans-5-O-caffeoylshikimate + flavin + H2O
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
BRENDA:
BS260915
KEGG:
R06582
|
|
|
|
4-coumaroyl-CoA + quinate <=> 5-O-p-coumaroylquinic_acid + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
|
| |
BRENDA:
BS320439
KEGG:
R07432
MetaCyc:
RXN-2601
|
|
|
|
chlorogenic_acid + CoA <=> caffeoyl-CoA + quinate
|
2.3.1
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BS321558
KEGG:
R01945
MetaCyc:
RXN-2622
|
|
|
|
UDP-glucose + Curcumin_monoglucoside <=> H+ + Curcumin_diglucoside + UDP
|
2.4.1
|
–
|
| |
KEGG:
R08814
MetaCyc:
RXN-7063
|
|
|
|
feruloyl-CoA + (4-coumaroyl)acetyl-CoA + H2O <=> demethoxycurcumin + CoA + CO2
|
2.3.1.217
curcumin synthase
2.3.1.219
demethoxycurcumin synthase
|
–
–
|
| |
BRENDA:
BS421743
KEGG:
R08808
MetaCyc:
RXN-11224
|
|
|
|
(1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)deca-1,4-dien-3-one <=> 5-Hydroxy-1-(4-hydroxyphenyl)-3-decanone
|
not assigned
|
–
|
| |
KEGG:
R08798
|
|
|
|
UDP-glucose + curcumin <=> Curcumin_monoglucoside + UDP + H+
|
2.4.1
|
–
|
| |
KEGG:
R08813
MetaCyc:
RXN-7062
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> (4-coumaroyl)acetyl-CoA + CoA + CO2
|
2.3.1.218
phenylpropanoylacetyl-CoA synthase
|
–
|
| |
BRENDA:
BR50411
KEGG:
R08805
MetaCyc:
RXN-11220
|
|
|
|
S-adenosyl-L-methionine + caffeoyl-CoA <=> H+ + feruloyl-CoA + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
| |
BRENDA:
BR43863
KEGG:
R01942
MetaCyc:
CAFFEOYL-COA-O-METHYLTRANSFERASE-RXN
|
|
|
|
demethoxycurcumin <=> curcumin
|
not assigned
|
–
|
| |
KEGG:
R08812
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + H2O + H+ <=> CoA + bisdemethoxycurcumin + CO2
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
| |
BRENDA:
BR50403
KEGG:
R10233
MetaCyc:
RXN-13958
|
|
|
|
5-O-p-coumaroylquinic_acid + reduced_flavodoxin + O2 <=> chlorogenic_acid + flavin + H2O
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
BRENDA:
BR37109
KEGG:
R04342
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> resveratrol + CoA + CO2
|
2.3.1.146
pinosylvin synthase
2.3.1.95
trihydroxystilbene synthase
|
–
–
|
| |
BRENDA:
BR44098
KEGG:
R01614
MetaCyc:
RXN-87
|
|
|
|
feruloyl-CoA + feruloylacetyl-CoA + H2O <=> curcumin + CoA + CO2
|
2.3.1.217
curcumin synthase
|
–
|
| |
BRENDA:
BR50409
KEGG:
R08810
MetaCyc:
RXN-11226
|
|
