|
|
2,6-Diamino-4-nitrotoluene <=> 2,4,6-Triaminotoluene
|
not assigned
|
–
|
|
KEGG:
R08030
|
|
|
|
4-hydroxylamino-2,6-dinitrotoluene + H2O + NADP+ <=> 2,4,6-trinitrotoluene + NADPH + H+
|
1
1.7.1
1.7.1.B1
1.7.1.B3
|
–
–
–
–
|
|
BRENDA:
BR49075;
BS440083
KEGG:
R08014
MetaCyc:
RXN1G01-60
|
|
|
|
4-amino-2,6-dinitrotoluene + 3 NADH + 3 H+ <=> 2,4-Diamino-6-nitrotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R08046
|
|
|
|
4 N-hydroxy-2-methyl-3,5-dinitroaniline + O2 <=> 2 4,4'',6,6''-Tetranitro-2,2''-azoxytoluene + 4 H2O
|
not assigned
|
–
|
|
KEGG:
R08038
|
|
|
|
4 4-hydroxylamino-2,6-dinitrotoluene + O2 <=> 2 2,2'',6,6''-Tetranitro-4,4''-azoxytoluene + 4 H2O
|
not assigned
|
–
|
|
KEGG:
R08020
|
|
|
|
cis,cis-2,4-Dihydroxy-5-methyl-6-oxo-2,4-hexadienoate + H2O <=> L-2-methyl-3-oxopropionate + pyruvate
|
3.7.1
|
–
|
|
KEGG:
R09238
|
|
|
|
2,4-Diamino-6-nitrotoluene + acetyl-CoA <=> 4-Acetamido-2-amino-6-nitrotoluene + CoA
|
2.3.1.5
arylamine N-acetyltransferase
|
–
|
|
KEGG:
R08036
|
|
|
|
2,4,6-trinitrotoluene + 2 NADH + 2 H+ <=> 4-hydroxylamino-2,6-dinitrotoluene + 2 NAD+ + H2O
|
1
|
–
|
|
KEGG:
R08017
|
|
|
|
2-Amino-4-nitrotoluene + 3 NADH + 3 H+ <=> 2,4-Diaminotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09230
|
|
|
|
4-methyl-5-nitrocatechol + O2 + NADH <=> H+ + 2-hydroxy-5-methylquinone + NAD+ + nitrite + H2O
|
1.14.13.210
4-methyl-5-nitrocatechol 5-monooxygenase
|
–
|
|
BRENDA:
BR51570-a
KEGG:
R11150
MetaCyc:
RXN-8821_WOP
|
|
|
|
4-amino-2-nitrotoluene + 3 NADH + 3 H+ <=> 2,4-Diaminotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09235
|
|
|
|
4-hydroxylamino-2,6-dinitrotoluene + NADH + H+ <=> 4-amino-2,6-dinitrotoluene + NAD+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08018
|
|
|
|
4-hydroxylamino-2,6-dinitrotoluene + NADPH + H+ <=> 4-amino-2,6-dinitrotoluene + NADP+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08019
|
|
|
|
4-amino-2,6-dinitrotoluene + 2 NADH + 2 H+ <=> 4-Amino-2-hydroxylamino-6-nitrotoluene + 2 NAD+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08047
|
|
|
|
2,4-Diamino-6-nitrotoluene <=> 2,4-Diamino-6-hydroxylaminotoluene
|
1.12.99.6
hydrogenase (acceptor)
1.2.7.1
pyruvate synthase
1.2.7.4
anaerobic carbon monoxide dehydrogenase
|
–
–
–
|
|
KEGG:
R08034
|
|
|
|
H+ + 2-hydroxy-5-methylquinone + NADH <=> 2,4,5-Trihydroxytoluene + NAD+
|
1.1.1
|
–
|
|
KEGG:
R09236
MetaCyc:
RXN-8822
|
|
|
|
4-methyl-5-nitrocatechol + O2 + NADPH <=> H+ + 2-hydroxy-5-methylquinone + NADP+ + nitrite + H2O
|
1.14.13.210
4-methyl-5-nitrocatechol 5-monooxygenase
|
–
|
|
BRENDA:
BR51570
KEGG:
R09234
MetaCyc:
RXN-8821
|
|
|
|
2-amino-4,6-dinitrotoluene + 3 NADH + 3 H+ <=> 2,6-Diamino-4-nitrotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R08044
|
|
|
|
4-amino-2-nitrotoluene + 3 NADPH + 3 H+ <=> 2,4-Diaminotoluene + 3 NADP+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09243
|
|
|
|
2,4-dinitrotoluene + O2 + NADH <=> 4-methyl-5-nitrocatechol + NAD+ + nitrite
|
1.14.12.24
2,4-dinitrotoluene dioxygenase
|
–
|
|
BRENDA:
BR51493
KEGG:
R09233
MetaCyc:
RXN-8820
|
|
|
|
2,4-dinitrotoluene + 3 NADPH + 3 H+ <=> 2-Amino-4-nitrotoluene + 3 NADP+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09241
|
|
|
|
2,4-dinitrotoluene + 3 NADPH + 3 H+ <=> 4-amino-2-nitrotoluene + 3 NADP+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09242
|
|
|
|
2-amino-4,6-dinitrotoluene <=> 2-Amino-4-nitrotoluene
|
not assigned
|
–
|
|
KEGG:
R08033
|
|
|
|
2,4,5-Trihydroxytoluene + O2 <=> H+ + cis,cis-2,4-Dihydroxy-5-methyl-6-oxo-2,4-hexadienoate
|
1.13.11
|
–
|
|
KEGG:
R09237
MetaCyc:
RXN-8823
|
|
|
|
2,4-Dihydroxylamino-6-nitrotoluene <=> 2-Amino-5-hydroxyl-4-hydroxylamino-6-nitrotoluene
|
not assigned
|
–
|
|
KEGG:
R08048
|
|
|
|
2,4-dinitrotoluene + 3 NADH + 3 H+ <=> 2-Amino-4-nitrotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09231
|
|
|
|
2,4-Diamino-6-nitrotoluene <=> 2,4,6-Triaminotoluene
|
not assigned
|
–
|
|
KEGG:
R08027
|
|
|
|
N-hydroxy-2-methyl-3,5-dinitroaniline + NADH + H+ <=> 2-amino-4,6-dinitrotoluene + NAD+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08043
|
|
|
|
2,4,6-Triaminotoluene <=> 2,4,6-Trihydroxytoluene
|
not assigned
|
–
|
|
KEGG:
R08040
|
|
|
|
2-Amino-4-nitrotoluene + 3 NADPH + 3 H+ <=> 2,4-Diaminotoluene + 3 NADP+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09240
|
|
|
|
2,4,6-trinitrotoluene + 2 NADH + 2 H+ <=> N-hydroxy-2-methyl-3,5-dinitroaniline + 2 NAD+ + H2O
|
1
|
–
|
|
KEGG:
R08042
|
|
|
|
2,4-Dihydroxylamino-6-nitrotoluene + NADPH + H+ <=> 4-Amino-2-hydroxylamino-6-nitrotoluene + NADP+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08016
|
|
|
|
4-Amino-2-hydroxylamino-6-nitrotoluene <=> 2,4-Diamino-6-nitrotoluene
|
not assigned
|
–
|
|
KEGG:
R08049
|
|
|
|
2-amino-4,6-dinitrotoluene + 3 NADH + 3 H+ <=> 2,4-Diamino-6-nitrotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R08045
|
|
|
|
2,4,6-Trihydroxytoluene <=> p-Cresol
|
not assigned
|
–
|
|
KEGG:
R08041
|
|
|
|
2,4-dinitrotoluene + 3 NADH + 3 H+ <=> 4-amino-2-nitrotoluene + 3 NAD+ + 2 H2O
|
1.7.1
|
–
|
|
KEGG:
R09232
|
|
|
|
4-hydroxylamino-2,6-dinitrotoluene + 2 NADPH + 2 H+ <=> 2,4-Dihydroxylamino-6-nitrotoluene + 2 NADP+ + H2O
|
1.7.1
|
–
|
|
KEGG:
R08015
|
|
|
|
2,4-Diamino-6-hydroxylaminotoluene <=> 2,4,6-Triaminotoluene
|
1.8.99.5
dissimilatory sulfite reductase
|
–
|
|
KEGG:
R08035
|
|
|
|
2 4-hydroxylamino-2,6-dinitrotoluene + 2 N-hydroxy-2-methyl-3,5-dinitroaniline + O2 <=> 2 2,4'',6,6''-Tetranitro-2'',4-azoxytoluene + 4 H2O
|
not assigned
|
–
|
|
KEGG:
R08037
|
|