|
|
D-2-hydroxyisocaproyl-CoA <=> 2-isocaprenoyl-CoA + H2O
|
4.2.1.157
(R)-2-hydroxyisocaproyl-CoA dehydratase
|
–
|
| |
BRENDA:
BR51460
KEGG:
R11076
MetaCyc:
RXN-16247
|
|
|
|
(R)-2-hydroxyisocaproate + NAD+ <=> 4-methyl-2-oxopentanoate + NADH + H+
|
1.1.1.272
D-2-hydroxyacid dehydrogenase (NADP+)
1.1.1.345
D-2-hydroxyacid dehydrogenase (NAD+)
|
–
–
|
| |
BRENDA:
BS387200-a
MetaCyc:
RXN-16245
SABIO-RK:
12853
|
|
|
|
L-leucine + 2-oxoglutarate <=> L-glutamate + 4-methyl-2-oxopentanoate
|
2.6.1.1
aspartate transaminase
2.6.1.2
alanine transaminase
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.57
aromatic-amino-acid transaminase
2.6.1.6
leucine transaminase
2.6.1.67
2-aminohexanoate transaminase
2.6.1.9
histidinol-phosphate transaminase
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR47691
KEGG:
R01090
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERLEU-RXN
SABIO-RK:
1352
|
|
|
|
4-methylpentanoyl-CoA + (R)-2-hydroxyisocaproate <=> 4-methylpentanoate + D-2-hydroxyisocaproyl-CoA
|
2.8.3.24
(R)-2-hydroxy-4-methylpentanoate CoA-transferase
|
–
|
| |
BRENDA:
BR51714
KEGG:
R11462
MetaCyc:
RXN-16246
|
|
|
|
4-methylpentanoyl-CoA + NAD+ <=> 2-isocaprenoyl-CoA + NADH + H+
|
1.3.1.44
trans-2-enoyl-CoA reductase (NAD+)
|
–
|
| |
MetaCyc:
RXN-17524
|
|
