|
|
(2S,3S)-3-hydroxy-2-methylbutanoyl-CoA <=> tigloyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
| |
BRENDA:
BS444413
KEGG:
R04204
MetaCyc:
TIGLYLCOA-HYDROXY-RXN
SABIO-RK:
3920
|
|
|
|
L-isoleucine + 2-oxoglutarate <=> L-glutamate + (S)-3-methyl-2-oxopentanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.67
2-aminohexanoate transaminase
|
–
–
|
| |
BRENDA:
BS356522;
BS452227
KEGG:
R02199
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERILEU-RXN
SABIO-RK:
2171;
9086
|
|
|
|
(S)-2-methylbutanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> tigloyl-CoA + reduced_flavodoxin
|
1.3.8.5
2-methyl-branched-chain-enoyl-CoA reductase
|
–
|
| |
MetaCyc:
2-METHYLACYL-COA-DEHYDROGENASE-RXN
|
|
|
|
2-methylacetoacetyl-CoA + CoA <=> propionyl-CoA + acetyl-CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
|
| |
BRENDA:
BS407013
KEGG:
R00927
MetaCyc:
METHYLACETOACETYLCOATHIOL-RXN
|
|
|
|
(S)-3-methyl-2-oxopentanoate + NAD+ + CoA <=> (S)-2-methylbutanoyl-CoA + NADH + CO2
|
1.2.1.25
branched-chain alpha-keto acid dehydrogenase system
|
–
|
| |
KEGG:
R03171
MetaCyc:
2KETO-3METHYLVALERATE-RXN
|
|
|
|
NAD+ + (2S,3S)-3-hydroxy-2-methylbutanoyl-CoA <=> H+ + NADH + 2-methylacetoacetyl-CoA
|
1.1.1.178
3-hydroxy-2-methylbutyryl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BR29237;
BS187429
KEGG:
R04203
MetaCyc:
1.1.1.178-RXN
SABIO-RK:
3919
|
|
