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K-252 biosynthesis
State Icon | Reaction | EC-Number | Confidence maximal confidence score from EnzymeDetector | |
---|---|---|---|---|
dTDP-L-rhamnose + staurosporine_aglycone <=> H+ + K252d + dTDP |
not assigned |
–
|
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2-imino-3-(indol-3-yl)propanoate + H2O2 <=> N-[2-(carboxylatoamino)-1,2-bis(1H-indol-3-yl)ethyl]carbamate + H2O |
1.21.98.2
dichlorochromopyrrolate synthase
|
–
|
||
staurosporine_aglycone + dTDP-2-deoxy-5-keto-dihydrostreptose <=> 2-deoxy-5-keto-dihydrostreptosyl-K252c + dTDP |
not assigned |
–
|
||
N-[2-(carboxylatoamino)-1,2-bis(1H-indol-3-yl)ethyl]carbamate + H+ <=> Chromopyrrolate + NH3 |
not assigned |
–
|
||
K252b + alkane <=> K252a + demethylated_methyl_donor |
not assigned |
–
|
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L-tryptophan + O2 <=> H+ + 2-imino-3-(indol-3-yl)propanoate + H2O2 |
1.4.3
1.4.3.23 7-chloro-L-tryptophan oxidase |
–
– |
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2-deoxy-5-keto-dihydrostreptosyl-K252c + acceptor <=> K252b + reduced_acceptor |
not assigned |
–
|
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Chromopyrrolate + O2 + NADH + H+ <=> staurosporine_aglycone + CO2 + H2O + NAD+ |
1.13.12
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–
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