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K-252 biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
dTDP-L-rhamnose + staurosporine_aglycone <=> H+ + K252d + dTDP not assigned

2-imino-3-(indol-3-yl)propanoate + H2O2 <=> N-[2-(carboxylatoamino)-1,2-bis(1H-indol-3-yl)ethyl]carbamate + H2O 1.21.98.2 dichlorochromopyrrolate synthase

staurosporine_aglycone + dTDP-2-deoxy-5-keto-dihydrostreptose <=> 2-deoxy-5-keto-dihydrostreptosyl-K252c + dTDP not assigned

N-[2-(carboxylatoamino)-1,2-bis(1H-indol-3-yl)ethyl]carbamate + H+ <=> Chromopyrrolate + NH3 not assigned

K252b + alkane <=> K252a + demethylated_methyl_donor not assigned

L-tryptophan + O2 <=> H+ + 2-imino-3-(indol-3-yl)propanoate + H2O2 1.4.3
1.4.3.23 7-chloro-L-tryptophan oxidase


2-deoxy-5-keto-dihydrostreptosyl-K252c + acceptor <=> K252b + reduced_acceptor not assigned

Chromopyrrolate + O2 + NADH + H+ <=> staurosporine_aglycone + CO2 + H2O + NAD+ 1.13.12

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