|
|
L-isoleucine + 2 reduced_flavodoxin + 2 O2 <=> (1E,2S)-2-methylbutanal_oxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.39
isoleucine N-monooxygenase
|
–
|
| |
BRENDA:
BR49376
KEGG:
R09403
|
|
|
|
UDP-glucose + phenylacetothiohydroximate <=> desulfoglucotropaeolin + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR48049
KEGG:
R03213
MetaCyc:
2.4.1.195-RXN
SABIO-RK:
3040
|
|
|
|
L-phenylalanine <=> L-homophenylalanine
|
not assigned
|
–
|
| |
KEGG:
R08690
|
|
|
|
p-hydroxyphenylacetaldoxime + L-cysteine + NADPH + O2 + H+ <=> S-(Hydroxyphenylacetothiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
| |
KEGG:
R10672
|
|
|
|
UDP-glucose + 2-(3-indolyl)acetothiohydroximate <=> desulfo-indol-3-yl-methyl_glucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR52366
KEGG:
R08164
MetaCyc:
RXN-1442
|
|
|
|
L-dihomomethionine + 2 O2 + 2 reduced_flavodoxin <=> omega-(methylthio)-(E)-alkanal_oxime + CO2 + 3 H2O + 2 flavin
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
BRENDA:
BS438372
KEGG:
R08670
|
|
|
|
4-methylsulfanyl-2-oxobutanoate + acetyl-CoA + H2O <=> 2-[(2''-methylsulfanyl)ethyl]malate + CoA + H+
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438092
KEGG:
R08619
MetaCyc:
RXN-2202
|
|
|
|
2-Oxo-9-methylthiononanoic_acid + an_L-amino_acid <=> L-pentahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08643
|
|
|
|
S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + H2O <=> an_(E)-omega-(methylthio)alkyl-thiohydroximate + pyruvate + NH3
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08667
MetaCyc:
RXN-8052
|
|
|
|
L-tyrosine + 2 O2 + 2 reduced_flavodoxin <=> p-hydroxyphenylacetaldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.36
tyrosine N-monooxygenase
1.14.14.40
phenylalanine N-monooxygenase
|
–
–
|
| |
BRENDA:
BR51798
KEGG:
R10671
|
|
|
|
2-[(6''-methylsulfanyl)hexyl]malate <=> 3-[(6''-methylsulfanyl)hexyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08641
MetaCyc:
RXNQT-4173
|
|
|
|
7-methylthio-2-oxoheptanoate + acetyl-CoA + H2O <=> H+ + 2-[(5''-methylsulfanyl)pentyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438972
KEGG:
R08631
MetaCyc:
RXNQT-4169
|
|
|
|
2-Oxo-10-methylthiodecanoic_acid + an_L-amino_acid <=> L-hexahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08647
|
|
|
|
6-methylthio-2-oxohexanoate + acetyl-CoA + H2O <=> H+ + 2-[(4''-methylsulfanyl)butyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438966
KEGG:
R08627
MetaCyc:
RXNQT-4166
|
|
|
|
8-methylthio-2-oxooctanoate + acetyl-CoA + H2O <=> H+ + 2-[(6''-methylsulfanyl)hexyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438979
KEGG:
R08640
MetaCyc:
RXNQT-4172
|
|
|
|
3-[(6''-methylsulfanyl)hexyl]malate + NAD+ <=> 9-methylthio-2-oxononanoate + CO2 + NADH
|
1.1.1
1.1.1.85
3-isopropylmalate dehydrogenase
|
–
–
|
| |
KEGG:
R08642
MetaCyc:
RXNQT-4174
|
|
|
|
L-hexahomomethionine + 2 O2 + 2 reduced_flavodoxin <=> 4-methylthiononanaldoxime + CO2 + 3 H2O + 2 flavin
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
BRENDA:
BS438375
KEGG:
R08675
|
|
|
|
L-leucine + 2 O2 + 2 NADPH + 2 H+ <=> (E/Z)-isovaleraldoxime + 3 H2O + 2 NADP+ + CO2
|
1.14.13
|
–
|
| |
KEGG:
R08664
|
|
|
|
3-(2''-Methylthio)ethylmalic_acid + NAD+ <=> 2-Oxo-5-methylthiopentanoic_acid + CO2 + NADH + H+
|
1.1.1
|
–
|
| |
KEGG:
R08621
|
|
|
|
2-[(5''-methylsulfanyl)pentyl]malate <=> 3-[(5''-methylsulfanyl)pentyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08634
MetaCyc:
RXNQT-4170
|
|
|
|
5-methylthio-2-oxopentanoate + acetyl-CoA + H2O <=> H+ + 2-[(3''-methylsulfanyl)propyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438895
KEGG:
R08623
MetaCyc:
RXNQT-4163
|
|
|
|
2-Oxo-8-methylthiooctanoic_acid + an_L-amino_acid <=> L-tetrahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08638
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-p-hydroxy-benzylglucosinolate <=> adenosine_3,5''-bisphosphate + p-hydroxybenzylglucosinolate + H+
|
2.8.2
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BS358759
KEGG:
R08662
MetaCyc:
RXN-18762
|
|
|
|
S-(Hydroxyphenylacetothiohydroximoyl)-L-cysteine + H2O <=> p-Hydroxyphenylacetothiohydroximate + pyruvate + NH3 + H+
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08660
MetaCyc:
RXN-19596
|
|
|
|
L-leucine + 2-oxoglutarate <=> L-glutamate + 4-methyl-2-oxopentanoate
|
2.6.1.1
aspartate transaminase
2.6.1.2
alanine transaminase
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.57
aromatic-amino-acid transaminase
2.6.1.6
leucine transaminase
2.6.1.67
2-aminohexanoate transaminase
2.6.1.9
histidinol-phosphate transaminase
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR47691
KEGG:
R01090
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERLEU-RXN
SABIO-RK:
1352
|
|
|
|
L-valine + 2-oxoglutarate <=> L-glutamate + 2-oxoisovalerate
|
2.6.1.39
2-aminoadipate transaminase
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.6
leucine transaminase
2.6.1.66
valine---pyruvate transaminase
|
–
–
–
–
|
| |
BRENDA:
BS356553
KEGG:
R01214
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERVAL-RXN
SABIO-RK:
1446
|
|
|
|
L-tryptophan + 2 reduced_flavodoxin + 2 O2 <=> (E,Z)-indolyl-3-acetaldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.156
tryptophan N-monooxygenase
|
–
|
| |
BRENDA:
BR49593
KEGG:
R08160
|
|
|
|
S-(Indolylmethylthiohydroximoyl)-L-cysteine + H2O <=> 2-(3-indolyl)acetothiohydroximate + pyruvate + NH3
|
4.4.1
|
–
|
| |
KEGG:
R08170
|
|
|
|
L-isoleucine + 2-oxoglutarate <=> L-glutamate + (S)-3-methyl-2-oxopentanoate
|
2.6.1.42
branched-chain-amino-acid transaminase
2.6.1.67
2-aminohexanoate transaminase
|
–
–
|
| |
BRENDA:
BS356522;
BS452227
KEGG:
R02199
MetaCyc:
BRANCHED-CHAINAMINOTRANSFERILEU-RXN
SABIO-RK:
2171;
9086
|
|
|
|
2-[(3''-methylsulfanyl)propyl]malate <=> 3-[(3''-methylsulfanyl)propyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08624
MetaCyc:
RXNQT-4164
|
|
|
|
UDP-glucose + p-Hydroxyphenylacetothiohydroximate <=> desulfo-p-hydroxy-benzylglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
KEGG:
R08661
MetaCyc:
RXN-18761
|
|
|
|
L-tetrahomomethionine + 2 O2 + 2 reduced_flavodoxin <=> 4-methylthioheptanaldoxime + CO2 + 3 H2O + 2 flavin
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
BRENDA:
BS438386
KEGG:
R08673
|
|
|
|
L-phenylalanine + 2 reduced_flavodoxin + 2 O2 <=> (E)-phenylacetaldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.40
phenylalanine N-monooxygenase
|
–
|
| |
BRENDA:
BR49589
KEGG:
R09578
|
|
|
|
L-trihomomethionine + 2 reduced_flavodoxin + 2 O2 <=> 6-Methylthiohexanaldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
KEGG:
R08672
|
|
|
|
L-pentahomomethionine + 2 O2 + 2 reduced_flavodoxin <=> 4-methylthiooctanaldoxime + CO2 + 3 H2O + 2 flavin
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
BRENDA:
BS438382
KEGG:
R08674
|
|
|
|
S-(Phenylacetothiohydroximoyl)-L-cysteine + H2O <=> phenylacetothiohydroximate + pyruvate + NH3 + H+
|
4.4.1
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
–
|
| |
KEGG:
R08654
MetaCyc:
RXN-8054
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-7-methylthioheptyl_glucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 7-methylthioheptyl_glucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
| |
BRENDA:
BS407935
KEGG:
R11887
MetaCyc:
RXNQT-4332
|
|
|
|
3-[(5''-methylsulfanyl)pentyl]malate + NAD+ <=> 8-methylthio-2-oxooctanoate + CO2 + NADH
|
1.1.1
1.1.1.85
3-isopropylmalate dehydrogenase
|
–
–
|
| |
KEGG:
R08636
MetaCyc:
RXNQT-4171
|
|
|
|
L-methionine + a_2-oxo_carboxylate <=> 4-methylsulfanyl-2-oxobutanoate + an_aliphatic_L-amino_acid
|
2.6.1.88
methionine transaminase
|
–
|
| |
BRENDA:
BR49829
KEGG:
R08618
|
|
|
|
2-Oxo-5-methylthiopentanoic_acid + an_L-amino_acid <=> L-homomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08622
|
|
|
|
2-[(4''-methylsulfanyl)butyl]malate <=> 3-[(4''-methylsulfanyl)butyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08628
MetaCyc:
RXNQT-4167
|
|
|
|
L-homomethionine + 2 reduced_flavodoxin + 2 O2 <=> an_omega-(methylthio)-(E)-alkanal_oxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
BRENDA:
BR52625;
BS438376
KEGG:
R08665;
R11646
|
|
|
|
3-[(4''-methylsulfanyl)butyl]malate + NAD+ <=> 7-methylthio-2-oxoheptanoate + CO2 + NADH
|
1.1.1
1.1.1.85
3-isopropylmalate dehydrogenase
|
–
–
|
| |
KEGG:
R08629
MetaCyc:
RXNQT-4168
|
|
|
|
2-Oxo-7-methylthioheptanoic_acid + an_L-amino_acid <=> L-trihomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08630
|
|
|
|
2-[(7''-methylsulfanyl)heptyl]malate <=> 3-[(7''-methylsulfanyl)heptyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08645
MetaCyc:
RXNQT-4176
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-8-methylthiooctyl_glucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 8-methylthiooctyl_glucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
| |
BRENDA:
BS407936
KEGG:
R11888
MetaCyc:
RXNQT-4333
|
|
|
|
(E)-phenylacetaldoxime + L-cysteine + NADPH + O2 + H+ <=> S-(Phenylacetothiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
|
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
|
| |
KEGG:
R10670
|
|
|
|
L-homophenylalanine + 2 O2 + 2 NADPH + 2 H+ <=> 3-Phenylpropionaldoxim + 2 NADP+ + CO2 + 3 H2O
|
1.14.13
|
–
|
| |
KEGG:
R08655
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-4-methylthiobutylglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + glucoerucin
|
2.8.2
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BS407934
KEGG:
R08671
MetaCyc:
RXNQT-4329
|
|
|
|
2-[(2''-methylsulfanyl)ethyl]malate <=> 3-[(2''-methylsulfanyl)ethyl]malate
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
KEGG:
R08620
MetaCyc:
RXN-2203
|
|
|
|
3-[(3''-methylsulfanyl)propyl]malate + NAD+ <=> 6-methylthio-2-oxohexanoate + CO2 + NADH
|
1.1.1
1.1.1.85
3-isopropylmalate dehydrogenase
|
–
–
|
| |
KEGG:
R08625
MetaCyc:
RXNQT-4165
|
|
|
|
UDP-glucose + an_(E)-omega-(methylthio)alkyl-thiohydroximate <=> H+ + an_aliphatic_desulfoglucosinolate + UDP
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
BRENDA:
BR52365
KEGG:
R08668;
R12045
MetaCyc:
RXN-2208
|
|
|
|
(E,Z)-indolyl-3-acetaldoxime + L-cysteine + NADPH + O2 + H+ <=> S-(Indolylmethylthiohydroximoyl)-L-cysteine + NADP+ + 2 H2O
|
1.14.14.43
(methylsulfanyl)alkanaldoxime N-monooxygenase
1.14.14.45
aromatic aldoxime N-monooxygenase
|
–
–
|
| |
KEGG:
R08168
SABIO-RK:
14613
|
|
|
|
9-methylthio-2-oxononanoate + acetyl-CoA + H2O <=> H+ + 2-[(7''-methylsulfanyl)heptyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438985
KEGG:
R08644
MetaCyc:
RXNQT-4175
|
|
|
|
L-valine + 2 reduced_flavodoxin + 2 O2 <=> (E/Z)-isobutyraldoxime + 2 flavin + CO2 + 3 H2O
|
1.14.14.38
valine N-monooxygenase
|
–
|
| |
BRENDA:
BR49380
KEGG:
R08663
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfoglucotropaeolin <=> adenosine_3,5''-bisphosphate + benzylglucosinolate + H+
|
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BR47919;
BS358758
KEGG:
R03214
MetaCyc:
RXN-4606
|
|
|
|
4-methylthiobutanaldoxime + L-cysteine + reduced_flavodoxin + O2 <=> S-(4-Methylthiobutylthiohydroximoyl)-L-cysteine + flavin + 2 H2O
|
1.14.14.43
(methylsulfanyl)alkanaldoxime N-monooxygenase
|
–
|
| |
KEGG:
R08666
|
|
|
|
3''-phosphoadenylyl-sulfate + an_aliphatic_desulfoglucosinolate <=> adenosine_3,5''-bisphosphate + H+ + glucoiberverin
|
2.8.2
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
KEGG:
R08669
MetaCyc:
RXN-2209
|
|
|
|
2-Oxo-6-methylthiohexanoic_acid + an_L-amino_acid <=> L-dihomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
KEGG:
R08626
|
|
|
|
3-[(7''-methylsulfanyl)heptyl]malate + NAD+ <=> 2-Oxo-10-methylthiodecanoate + CO2 + NADH
|
1.1.1
1.1.1.85
3-isopropylmalate dehydrogenase
|
–
–
|
| |
KEGG:
R08646
MetaCyc:
RXNQT-4178
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-indol-3-yl-methyl_glucosinolate <=> adenosine_3,5''-bisphosphate + glucobrassicin + H+
|
2.8.2.24
aromatic desulfoglucosinolate sulfotransferase
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
–
|
| |
BRENDA:
BR52177;
BS407937
KEGG:
R08167
MetaCyc:
RXN-1443
|
|
