|
|
acetyl-CoA + 7 malonyl-CoA + 7 NADH + 7 NADPH + 14 H+ <=> palmitoyl-CoA + 7 CoA + 7 CO2 + 7 NAD+ + 7 NADP+ + 7 H2O
|
2.3.1
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
|
| |
BRENDA:
BS321418
KEGG:
R12328
|
|
|
|
fatty_acid + CoA + ATP <=> stearoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.30
phenylacetate---CoA ligase
6.2.1.B3
|
–
–
–
–
–
|
| |
BRENDA:
BR82;
BS287
KEGG:
R00390;
R01280
MetaCyc:
RXN-16380;
RXN-7904;
RXN-9623
SABIO-RK:
10953;
1496
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxotetradecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04566
MetaCyc:
RXN-9536
|
|
|
|
2-decenoyl-[acyl-carrier_protein] + NADPH <=> decanoyl-[acyl-carrier_protein] + NADP+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
BRENDA:
BS258333
KEGG:
R04962
|
|
|
|
(3R)-3-hydroxypalmitoyl-[acyl-carrier_protein] <=> trans-Hexadec-2-enoyl-[acp] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
KEGG:
R04544
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxotetradecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320872
KEGG:
R04726
MetaCyc:
RXN-9535
SABIO-RK:
4382
|
|
|
|
acyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] <=> 3-oxoacyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.293
meromycolic acid 3-oxoacyl-(acyl carrier protein) synthase I
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
–
|
| |
BRENDA:
BR44042
KEGG:
R02768
|
|
|
|
acyl-[acyl-carrier_protein] + NADP+ <=> trans-2,3-dehydroacyl-[acyl-carrier_protein] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
|
–
–
–
–
|
| |
BRENDA:
BR36795
KEGG:
R01404
|
|
|
|
(3R)-3-hydroxyoctanoyl-[acyl-carrier_protein] <=> 2-octenoyl-[acyl-carrier_protein] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
BRENDA:
BR437
KEGG:
R04537
MetaCyc:
4.2.1.59-RXN
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxododecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04964
|
|
|
|
acyl-[acyl-carrier_protein] + NAD+ <=> trans-2,3-dehydroacyl-[acyl-carrier_protein] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
| |
BRENDA:
BR36835;
BS438479
KEGG:
R01403
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NAD+ <=> trans-Hexadec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
KEGG:
R04969
MetaCyc:
RXN-9663
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
| |
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
ATP + alpha,omega-dicarboxylate + CoA <=> malonyl-CoA + AMP + diphosphate
|
6.2.1
6.2.1.23
dicarboxylate---CoA ligase
|
–
–
|
| |
BRENDA:
BR75
KEGG:
R04157;
R12300
MetaCyc:
DICARBOXYLATE--COA-LIGASE-RXN;
RXN-12359
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxodecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04534
MetaCyc:
RXN-9528
|
|
|
|
(R)-3-hydroxydodecanoyl-[acyl-carrier_protein] <=> dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
KEGG:
R04965
|
|
|
|
palmitoleoyl-[acyl-carrier_protein] + H2O <=> palmitoleic_acid + [acyl-carrier_protein] + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
|
–
|
| |
BRENDA:
BS364433
KEGG:
R08162
MetaCyc:
RXN-9550
|
|
|
|
acetyl-CoA + malonyl-CoA + NADPH + H+ <=> fatty_acid + CoA + CO2 + NADP+
|
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
|
| |
BRENDA:
BR44087
KEGG:
R05188
MetaCyc:
FATTY-ACID-SYNTHASE-RXN
SABIO-RK:
4803;
6701
|
|
|
|
hexanoyl-[acyl-carrier_protein] + NADP+ <=> trans-Hex-2-enoyl-[acp] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
KEGG:
R04956
MetaCyc:
RXN-9521
|
|
|
|
palmitoyl-[acyl-carrier_protein] + CoA <=> palmitoyl-CoA + [acyl-carrier_protein]
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
|
| |
BRENDA:
BS456174
KEGG:
R10700
MetaCyc:
RXN3O-9780
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + NAD+ <=> trans-Tetradec-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
KEGG:
R04966
MetaCyc:
RXN-9662
|
|
|
|
palmitoyl-[acyl-carrier_protein] + NADP+ <=> trans-Hexadec-2-enoyl-[acp] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
KEGG:
R04970
MetaCyc:
RXN-9542
|
|
|
|
octanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxodecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320870
KEGG:
R04960
MetaCyc:
RXN-9527
SABIO-RK:
4598
|
|
|
|
decanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Decanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
| |
BRENDA:
BS446229
KEGG:
R08158
|
|
|
|
(3R)-3-hydroxydecanoyl-[acyl-carrier_protein] <=> 2-decenoyl-[acyl-carrier_protein] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
BRENDA:
BS2050
KEGG:
R04535
|
|
|
|
(3R)-3-hydroxymyristoyl-[acyl-carrier_protein] <=> trans-Tetradec-2-enoyl-[acp] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
KEGG:
R04568
MetaCyc:
RXN-9537
|
|
|
|
octanoyl-[acyl-carrier_protein] + NAD+ <=> 2-octenoyl-[acyl-carrier_protein] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
BRENDA:
BS258652
KEGG:
R04958
MetaCyc:
RXN-9659
|
|
|
|
cis-3-decenoyl-[acyl-carrier_protein] <=> n-7_Unsaturated_acyl-[acyl-carrier_protein]
|
not assigned
|
–
|
| |
KEGG:
R10714
|
|
|
|
3-oxooctadecanoyl-[acyl-carrier_protein] + NADPH + H+ <=> (R)-3-hydroxystearoyl-[acyl-carrier_protein] + NADP+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
|
–
–
|
| |
KEGG:
R07763
|
|
|
|
malonyl-CoA + [acyl-carrier_protein] <=> CoA + malonyl-[acyl-carrier_protein]
|
2.3.1
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
|
| |
BRENDA:
BR44039
KEGG:
R01626
MetaCyc:
MALONYL-COA-ACP-TRANSACYL-RXN
SABIO-RK:
1767
|
|
|
|
butyryl-[acyl-carrier_protein] + NADP+ <=> trans-but-2-enoyl-[acyl-carrier_protein] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
BRENDA:
BS396792
KEGG:
R04430
MetaCyc:
RXN-9515
SABIO-RK:
4117
|
|
|
|
(3R)-3-hydroxyacyl-[acyl-carrier_protein] <=> trans-2,3-dehydroacyl-[acyl-carrier_protein] + H2O
|
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
|
| |
KEGG:
R10208
MetaCyc:
3-HYDROXYDECANOYL-ACP-DEHYDR-RXN
|
|
|
|
(3R)-3-hydroxyhexanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxohexanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04953
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + NADP+ <=> trans-Tetradec-2-enoyl-[acp] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
KEGG:
R04967
MetaCyc:
RXN-9538
|
|
|
|
ATP + acetyl-CoA + HCO3- <=> ADP + phosphate + malonyl-CoA + H+
|
6.4.1.2
acetyl-CoA carboxylase
6.4.1.3
propionyl-CoA carboxylase
6.4.1.4
methylcrotonoyl-CoA carboxylase
|
–
–
–
|
| |
BRENDA:
BR6444
KEGG:
R00742
MetaCyc:
ACETYL-COA-CARBOXYLTRANSFER-RXN
SABIO-RK:
542
|
|
|
|
acetyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> [acyl-carrier_protein] + acetoacetyl-[acyl-carrier_protein] + CO2
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS376191
KEGG:
R04355
MetaCyc:
3-OXOACYL-ACP-SYNTH-BASE-RXN
SABIO-RK:
4051
|
|
|
|
(3R)-3-hydroxypalmitoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxohexadecanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04543
|
|
|
|
butyryl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxohexanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320867
KEGG:
R04952
MetaCyc:
RXN-9516
SABIO-RK:
4590
|
|
|
|
(3R)-3-hydroxybutanoyl-[acyl-carrier_protein] + NADP+ <=> acetoacetyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS186945
KEGG:
R04533
MetaCyc:
RXN-9514
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
| |
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
acetyl-CoA + malonyl-CoA + NADPH + H+ <=> stearoyl-CoA + CoA + CO2 + NADP+
|
2.3.1.86
fatty-acyl-CoA synthase system
|
–
|
| |
BRENDA:
BR44088
KEGG:
R05190
MetaCyc:
FATTY-ACYL-COA-SYNTHASE-RXN
|
|
|
|
fatty_acid + CoA + ATP <=> stearoyl-CoA + AMP + diphosphate
|
1.13.12.7
firefly luciferase
6.2.1.12
4-coumarate---CoA ligase
6.2.1.3
long-chain-fatty-acid---CoA ligase
6.2.1.30
phenylacetate---CoA ligase
6.2.1.B3
|
–
–
–
–
–
|
| |
BRENDA:
BR82;
BS287
KEGG:
R00390;
R01280
MetaCyc:
RXN-16380;
RXN-7904;
RXN-9623
SABIO-RK:
10953;
1496
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + laurate + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
| |
BRENDA:
BR2506;
BS12699
KEGG:
R04014
MetaCyc:
3.1.2.21-RXN
SABIO-RK:
3749
|
|
|
|
decanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxododecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04963
MetaCyc:
RXN-9531
SABIO-RK:
4601
|
|
|
|
(3R)-3-hydroxybutanoyl-[acyl-carrier_protein] <=> trans-but-2-enoyl-[acyl-carrier_protein] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
KEGG:
R04428
|
|
|
|
(3R)-3-hydroxyhexanoyl-[acyl-carrier_protein] <=> trans-Hex-2-enoyl-[acp] + H2O
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
4.2.1
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
| |
KEGG:
R04954
|
|
|
|
2-decenoyl-[acyl-carrier_protein] + NADH <=> decanoyl-[acyl-carrier_protein] + NAD+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
BRENDA:
BS258648
KEGG:
R04961
|
|
|
|
(3R)-3-hydroxyoctanoyl-[acyl-carrier_protein] + NADP+ <=> 3-oxooctanoyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
KEGG:
R04536
MetaCyc:
RXN-9524
|
|
|
|
acetyl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> acetoacetyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
| |
BRENDA:
BR48666
KEGG:
R10707
MetaCyc:
2.3.1.180-RXN
|
|
|
|
octanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + Octanoate
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
| |
BRENDA:
BS446327
KEGG:
R08157
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + myristic_acid + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
|
| |
BRENDA:
BS12700
KEGG:
R08159
MetaCyc:
RXN-10727
SABIO-RK:
15487
|
|
|
|
hexanoyl-[acyl-carrier_protein] + NAD+ <=> trans-Hex-2-enoyl-[acp] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
KEGG:
R04955
MetaCyc:
RXN-9658
|
|
|
|
palmitoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctadecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
–
–
|
| |
BRENDA:
BS320874;
BS377477
KEGG:
R07762
MetaCyc:
RXN-9632
SABIO-RK:
11307
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + NAD+ <=> dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + NADH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
–
–
|
| |
BRENDA:
BS258654
KEGG:
R04724
MetaCyc:
RXN-9661
SABIO-RK:
4380
|
|
|
|
tetradecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxohexadecanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320873
KEGG:
R04968
MetaCyc:
RXN-9539
SABIO-RK:
4606
|
|
|
|
(R)-3-hydroxystearoyl-[acyl-carrier_protein] <=> (2E)-Octadecenoyl-[acp] + H2O
|
2.3.1
4.2.1
|
–
–
|
| |
KEGG:
R07764
|
|
|
|
stearoyl-[acyl-carrier_protein] + NAD+ <=> (2E)-Octadecenoyl-[acp] + NADH + H+
|
1.3.1
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
–
|
| |
KEGG:
R07765
MetaCyc:
RXN-9635
|
|
|
|
oleoyl-[acyl-carrier_protein] + H2O <=> [acyl-carrier_protein] + oleic_acid + H+
|
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
–
|
| |
BRENDA:
BR10674
KEGG:
R02814
MetaCyc:
3.1.2.14-RXN
|
|
|
|
acetyl-CoA + [acyl-carrier_protein] <=> CoA + acetyl-[acyl-carrier_protein]
|
2.3.1
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.39
[acyl-carrier-protein] S-malonyltransferase
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
2.7.8.7
holo-[acyl-carrier-protein] synthase
|
–
–
–
–
–
–
–
|
| |
BRENDA:
BR44038;
BS455168;
BS455169
KEGG:
R01624
MetaCyc:
ACP-S-ACETYLTRANSFER-RXN
SABIO-RK:
1766
|
|
|
|
palmitoyl-[acyl-carrier_protein] + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> palmitoleoyl-[acyl-carrier_protein] + oxidized_ferredoxin + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
| |
KEGG:
R08161
MetaCyc:
RXN-8389
|
|
|
|
hexanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> 3-oxooctanoyl-[acyl-carrier_protein] + CO2 + [acyl-carrier_protein]
|
2.3.1
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
|
| |
BRENDA:
BS320869
KEGG:
R04957
MetaCyc:
RXN-9523
SABIO-RK:
4595
|
|
|
|
butyryl-[acyl-carrier_protein] + NAD+ <=> trans-but-2-enoyl-[acyl-carrier_protein] + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
2.3.1
|
–
–
|
| |
BRENDA:
BS374746
KEGG:
R04429
MetaCyc:
RXN-9657
SABIO-RK:
4116
|
|
|
|
(3R)-3-hydroxyacyl-[acyl-carrier_protein] + NADP+ <=> 3-oxoacyl-[acyl-carrier_protein] + NADPH + H+
|
1.1.1
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
–
|
| |
BRENDA:
BR29166
KEGG:
R02767
MetaCyc:
3-OXOACYL-ACP-REDUCT-RXN
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
| |
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|
|
|
stearoyl-[acyl-carrier_protein] + reduced_ferredoxin_[iron-sulfur]_cluster + O2 + H+ <=> oleoyl-[acyl-carrier_protein] + oxidized_ferredoxin + H2O
|
1.14.19.2
stearoyl-[acyl-carrier-protein] 9-desaturase
|
–
|
| |
BRENDA:
BR40398;
BS453858
KEGG:
R03370
MetaCyc:
RXN-7903
SABIO-RK:
10485
|
|
|
|
2-decenoyl-[acyl-carrier_protein] <=> cis-3-decenoyl-[acyl-carrier_protein]
|
5.3.3.14
trans-2-decenoyl-[acyl-carrier protein] isomerase
|
–
|
| |
BRENDA:
BR48706
KEGG:
R07639
|
|
|
|
dodecanoyl-[acyl-carrier_protein] + NADP+ <=> dodecenoyl-[Staphylococcus_aureus_acyl_carrier_protein] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
BRENDA:
BS397090
KEGG:
R04725
MetaCyc:
RXN-9534
SABIO-RK:
4381
|
|
|
|
octanoyl-[acyl-carrier_protein] + NADP+ <=> 2-octenoyl-[acyl-carrier_protein] + NADPH + H+
|
1.3.1
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.104
enoyl-[acyl-carrier-protein] reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
–
–
–
|
| |
KEGG:
R04959
MetaCyc:
RXN-9526
|
|
