|
|
5alpha-campestan-3-one + NADP+ <=> H+ + (24R)-ergost-4-en-3-one + NADPH
|
1.3.1
1.3.1.22
3-oxo-5alpha-steroid 4-dehydrogenase (NADP+)
|
–
–
|
| |
KEGG:
R07429
MetaCyc:
RXN-711
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + NADP+ <=> H+ + (22S)-22-hydroxycampest-4-en-3-one + NADPH
|
1.3.1
1.3.1.22
3-oxo-5alpha-steroid 4-dehydrogenase (NADP+)
|
–
–
|
| |
KEGG:
R07447
MetaCyc:
RXN-4229
|
|
|
|
6-deoxotyphasterol + NADPH + H+ + O2 <=> 6-Deoxocastasterone + NADP+ + H2O
|
1.14
|
–
|
| |
KEGG:
R07474
|
|
|
|
5alpha-campestan-3-one + O2 + NADPH <=> (22S,24R)-22-hydroxy-5alpha-ergostan-3-one + NADP+ + H2O
|
1.14.13
|
–
|
| |
KEGG:
R07453
|
|
|
|
24-epibrassinolide <=> 26-Hydroxybrassinolide
|
1.14
|
–
|
| |
KEGG:
R09762
|
|
|
|
campesterol + NADPH + H+ + O2 <=> 6-deoxocathasterone + NADP+ + H2O
|
1.14.13
1.14.99.B1
|
–
–
|
| |
BRENDA:
BS396649
KEGG:
R07454
SABIO-RK:
12699
|
|
|
|
typhasterol + reduced_flavodoxin + O2 <=> 7-Oxatyphasterol + flavin + H2O
|
1.14.14
|
–
|
| |
KEGG:
R08841
|
|
|
|
3-dehydro-6-deoxoteasterone + 2 O2 + 2 reduced_flavodoxin <=> 3-Dehydroteasterone + 3 H2O + 2 flavin
|
1.14
|
–
|
| |
KEGG:
R07457
|
|
|
|
(22S)-22-hydroxycampest-4-en-3-one + reduced_flavodoxin + O2 <=> (22R,23R)-22,23-dihydroxycampest-4-en-3-one + flavin + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
| |
BRENDA:
BS399135
KEGG:
R07787
|
|
|
|
campesterol <=> Campest-4-en-3beta-ol
|
5.3.3.1
steroid Delta-isomerase
|
–
|
| |
KEGG:
R07427
MetaCyc:
RXN-709
|
|
|
|
(22R,23R)-22,23-dihydroxycampest-4-en-3-one <=> 3-dehydro-6-deoxoteasterone
|
not assigned
|
–
|
| |
KEGG:
R07790
|
|
|
|
24-epicastasterone <=> 24-epibrassinolide
|
1.14
|
–
|
| |
KEGG:
R07471
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one <=> 6-deoxocathasterone
|
not assigned
|
–
|
| |
KEGG:
R07472
|
|
|
|
6alpha-Hydroxy-castasterone + O2 + reduced_flavodoxin <=> 24-epicastasterone + 2 H2O + flavin
|
1.14
|
–
|
| |
KEGG:
R07451
|
|
|
|
3-dehydro-6-deoxoteasterone <=> 6-deoxotyphasterol
|
not assigned
|
–
|
| |
KEGG:
R07473
|
|
|
|
24-epicastasterone <=> 26-Hydroxycastasterone
|
1.14
|
–
|
| |
KEGG:
R09761
|
|
|
|
campesterol + O2 + reduced_acceptor <=> 6alpha-Hydroxycampestanol + H2O + acceptor
|
1.14.99
|
–
|
| |
KEGG:
R07467
MetaCyc:
RXN-713
|
|
|
|
3-Dehydroteasterone <=> typhasterol
|
not assigned
|
–
|
| |
KEGG:
R07469
|
|
|
|
6alpha-Hydroxycampestanol <=> 6-Oxocampestanol
|
not assigned
|
–
|
| |
KEGG:
R07468
|
|
|
|
6-deoxotyphasterol + 2 O2 + 2 reduced_flavodoxin <=> typhasterol + 3 H2O + 2 flavin
|
1.14
|
–
|
| |
KEGG:
R07458
|
|
|
|
6-deoxoteasterone + 2 O2 + 2 reduced_flavodoxin <=> Teasterone + 3 H2O + 2 flavin
|
1.14
|
–
|
| |
KEGG:
R07455
|
|
|
|
6-deoxocathasterone + O2 <=> 6-deoxoteasterone + H2O
|
1.14
|
–
|
| |
KEGG:
R07448
|
|
|
|
Teasterone <=> 3-Dehydroteasterone
|
1.14
|
–
|
| |
KEGG:
R07444
|
|
|
|
Cathasterone + O2 + reduced_acceptor <=> Teasterone + H2O + acceptor
|
1.14
|
–
|
| |
KEGG:
R07431
|
|
|
|
7-Oxateasterone <=> 7-Oxatyphasterol
|
not assigned
|
–
|
| |
KEGG:
R08842
MetaCyc:
RXN-11539
|
|
|
|
6-Oxocampestanol + O2 + NADPH <=> Cathasterone + NADP+ + H2O
|
1.14.13
|
–
|
| |
KEGG:
R07430
|
|
|
|
(22S)-22-hydroxycampesterol + reduced_flavodoxin + O2 <=> (22R,23R)-22,23-dihydroxycampesterol + flavin + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
| |
BRENDA:
BS399136
KEGG:
R07786
|
|
|
|
5alpha-campestan-3-one <=> campesterol
|
not assigned
|
–
|
| |
KEGG:
R07466
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one <=> 3-epi-6-deoxocathasterone
|
not assigned
|
–
|
| |
KEGG:
R07788
|
|
|
|
Teasterone + reduced_flavodoxin + O2 <=> 7-Oxateasterone + flavin + H2O
|
1.14.14
|
–
|
| |
KEGG:
R08840
|
|
|
|
(22S)-22-hydroxycampesterol <=> (22S)-22-hydroxycampest-4-en-3-one
|
not assigned
|
–
|
| |
KEGG:
R07446
|
|
|
|
campesterol + NADPH + H+ + O2 <=> (22S)-22-hydroxycampesterol + NADP+ + H2O
|
1.14.13
1.14.99.B1
|
–
–
|
| |
BRENDA:
BS396650
KEGG:
R07445
SABIO-RK:
12698
|
|
|
|
6-deoxoteasterone <=> 3-dehydro-6-deoxoteasterone
|
1.14
|
–
|
| |
KEGG:
R07449
|
|
|
|
(22S,24R)-22-hydroxy-5alpha-ergostan-3-one + reduced_flavodoxin + O2 <=> 3-dehydro-6-deoxoteasterone + flavin + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
| |
BRENDA:
BR49135
KEGG:
R07791
|
|
|
|
(22R,23R)-22,23-dihydroxycampesterol <=> (22R,23R)-22,23-dihydroxycampest-4-en-3-one
|
not assigned
|
–
|
| |
KEGG:
R07789
|
|
|
|
(24R)-ergost-4-en-3-one + NADPH + H+ + O2 <=> (22S)-22-hydroxycampest-4-en-3-one + NADP+ + H2O
|
1.14.13
1.14.99.B1
|
–
–
|
| |
BRENDA:
BS395057
KEGG:
R07452
|
|
|
|
Campest-4-en-3beta-ol + NAD+ <=> (24R)-ergost-4-en-3-one + NADH + H+
|
1.1.1.357
3alpha-hydroxysteroid 3-dehydrogenase
|
–
|
| |
KEGG:
R07428
MetaCyc:
RXN-710
|
|
|
|
3-epi-6-deoxocathasterone + reduced_flavodoxin + O2 <=> 6-deoxotyphasterol + flavin + H2O
|
1.14.14.147
3-epi-6-deoxocathasterone 23-monooxygenase
|
–
|
| |
BRENDA:
BR49134
KEGG:
R07792
|
|
|
|
6-Deoxocastasterone + O2 + reduced_flavodoxin <=> 6alpha-Hydroxy-castasterone + H2O + flavin
|
1.14
|
–
|
| |
KEGG:
R07450
|
|
|
|
typhasterol + NADPH + H+ + O2 <=> 24-epicastasterone + NADP+ + H2O
|
1.14
|
–
|
| |
KEGG:
R07470
|
|
