|
|
3,5,7,9,11,13,15-Heptaoxo-hexadecanoyl-[acp] <=> 7,9,12-Octaketide_intermediate_1
|
not assigned
|
–
|
| |
KEGG:
R09259
|
|
|
|
propionyl-CoA + 9 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-nonaoxohenicosanoyl-[acp] + 9 CO2 + 9 CoA
|
2.3.1
|
–
|
| |
KEGG:
R06644
|
|
|
|
3,5,7,9,11,13,15,17,19-Nonaoxo-eicosanoyl-[acp] <=> 7,9,12-Decaketide_intermediate_1
|
not assigned
|
–
|
| |
KEGG:
R09260
|
|
|
|
7,9,12-Decaketide_intermediate_2 <=> 7,9,12-Decaketide_intermediate_3 + 2 H2O
|
4.2.1
|
–
|
| |
KEGG:
R09266
|
|
|
|
3,5,7,9,11,13,15,17,19-nonaoxohenicosanoyl-[acp] <=> 7,9,12-Decaketide_intermediate_4
|
not assigned
|
–
|
| |
KEGG:
R09261
|
|
|
|
acetyl-CoA + 7 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-hexadecanoyl-[acp] + 7 CO2 + 7 CoA
|
2.3.1
|
–
|
| |
KEGG:
R06635
|
|
|
|
7,9,12-Decaketide_intermediate_1 + NADPH + H+ <=> 7,9,12-Decaketide_intermediate_2 + NADP+
|
1.1.1
|
–
|
| |
KEGG:
R09263
|
|
|
|
18-Carbamoyl-3,5,7,9,11,13,15,17-octaoxooctadecanoyl-[acp] + NADPH + H+ <=> C-9_Reduced_nonaketamide + NADP+
|
1.1.1
|
–
|
| |
KEGG:
R06642
|
|
|
|
7,9,12-Decaketide_intermediate_5 <=> 7,9,12-Decaketide_intermediate_6 + 2 H2O
|
4.2.1
|
–
|
| |
KEGG:
R09267
|
|
|
|
7,9,12-Octaketide_intermediate_2 <=> 7,9,12-Octaketide_intermediate_3 + 2 H2O
|
4.2.1
|
–
|
| |
KEGG:
R09265
|
|
|
|
C-9_Reduced_nonaketamide <=> Nonaketamide_monocyclic_intermediate + 2 H2O
|
4.2.1
|
–
|
| |
KEGG:
R09187
|
|
|
|
7,9,12-Decaketide_intermediate_4 + NADPH + H+ <=> 7,9,12-Decaketide_intermediate_5 + NADP+
|
1.1.1
|
–
|
| |
KEGG:
R09264
|
|
|
|
butyryl-CoA + 7 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-octadecanoyl-[acp] + 7 CO2 + 7 CoA
|
2.3.1
|
–
|
| |
KEGG:
R06637
|
|
|
|
8 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15-Heptaoxo-hexadecanoyl-[acp] + 8 CO2 + 8 CoA
|
2.3.1
|
–
|
| |
KEGG:
R09258
|
|
|
|
3,5,7,9,11,13,15,17,19-Nonaoxo-eicosanoyl-[acp] <=> 7,12-Decaketide_intermediate_1 + H2O
|
4.2.1
|
–
|
| |
KEGG:
R09268
|
|
|
|
7,9,12-Octaketide_intermediate_1 + NADPH + H+ <=> 7,9,12-Octaketide_intermediate_2 + NADP+
|
1.1.1
|
–
|
| |
KEGG:
R09262
|
|
|
|
10 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-Nonaoxo-eicosanoyl-[acp] + 10 CO2 + 10 CoA
|
2.3.1
2.3.1.235
tetracenomycin F2 synthase
|
–
–
|
| |
KEGG:
R06643
|
|
|
|
butyryl-CoA + 9 malonyl-CoA + [acyl-carrier_protein] <=> 3,5,7,9,11,13,15,17,19-Nonaoxo-docosanoyl-[acp] + 9 CO2 + 9 CoA
|
2.3.1
|
–
|
| |
KEGG:
R06645
|
|
|
|
3,5,7,9,11,13,15,17,19-Nonaoxo-eicosanoyl-[acp] <=> 9,14-Decaketide_intermediate_1 + 2 H2O
|
2.3.1.235
tetracenomycin F2 synthase
4.2.1
|
–
–
|
| |
KEGG:
R09269
|
|
|
|
Malonamoyl-[acyl-carrier_protein] + 8 malonyl-CoA <=> 18-Carbamoyl-3,5,7,9,11,13,15,17-octaoxooctadecanoyl-[acp] + 8 CO2 + 8 CoA
|
2.3.1.260
tetracycline polyketide synthase
|
–
|
| |
KEGG:
R11516
|
|
