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Amino sugar and nucleotide sugar metabolism

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
N-acetylmuramate_6-phosphate + H2O <=> N-acetylmuramic_acid + phosphate 3.1.3.105 N-acetyl-D-muramate 6-phosphate phosphatase

N,N''-diacetylchitobiose + phosphate <=> N-acetyl-D-glucosamine_1-phosphate + N-acetyl-D-glucosamine 2.4.1.280 N,N'-diacetylchitobiose phosphorylase

UDP-N-acetyl-D-glucosamine <=> UDP-2-acetamido-2,6-dideoxy-alpha-D-xylo-4-hexulose + H2O 4.2.1.135 UDP-N-acetylglucosamine 4,6-dehydratase (configuration-retaining)

UDP-4-amino-4,6-dideoxy-N-acetyl-beta-L-altrosamine + 2-oxoglutarate <=> UDP-2-acetamido-2,6-dideoxy-beta-L-arabino-hex-4-ulose + L-glutamate 2.6.1.92 UDP-4-amino-4,6-dideoxy-N-acetyl-beta-L-altrosamine transaminase

UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucuronate + acetyl-CoA <=> UDP-2,3-diacetamido-2,3-dideoxy-alpha-D-glucuronate + CoA + H+ 2.3.1.201 UDP-2-acetamido-3-amino-2,3-dideoxy-glucuronate N-acetyltransferase

UDP-beta-L-arabinopyranose <=> UDP-D-xylose 5.1.3.2 UDP-glucose 4-epimerase
5.1.3.5 UDP-arabinose 4-epimerase


alpha-D-glucose_6-phosphate <=> beta-D-fructose_6-phosphate 5.3.1.9 glucose-6-phosphate isomerase

CMP-N-acetylneuraminate + ferricytochrome_b5 + O2 + H+ <=> CMP-N-glycoloyl-beta-neuraminate + ferricytochrome_b5 + H2O 1.14.18.2 CMP-N-acetylneuraminate monooxygenase

UDP-glucuronate <=> UDP-L-iduronate 5.1.3
5.1.3.12 UDP-glucuronate 5'-epimerase


UDP-glucose + H2O + NAD+ <=> UDP-glucuronate + NADH + H+ 1.1.1.22 UDP-glucose 6-dehydrogenase

H+ + UDP-D-galacturonate <=> UDP-beta-L-arabinopyranose + CO2 4.1.1.67 UDP-galacturonate decarboxylase

CDP-4-dehydro-3,6-dideoxy-alpha-D-glucose + NAD+ + H2O <=> CDP-4-dehydro-6-deoxy-D-glucose + NADH + H+ 1.17.1.1 CDP-4-dehydro-6-deoxyglucose reductase

UDP-N-acetylmannosamine + NAD+ + H2O <=> UDP-N-acetyl-alpha-D-mannosaminuronate + NADH + H+ 1.1.1.336 UDP-N-acetyl-D-mannosamine dehydrogenase

D-mannose + ATP <=> D-mannose_6-phosphate + ADP + H+ 2.7.1.1 hexokinase
2.7.1.2 glucokinase
2.7.1.4 fructokinase
2.7.1.55 allose kinase
2.7.1.60 N-acylmannosamine kinase
2.7.1.7 mannokinase






GDP-mannose <=> GDP-4-dehydro-6-deoxy-D-mannose + H2O 4.2.1.47 GDP-mannose 4,6-dehydratase

UDP-N,N''-diacetylbacillosamine + H2O <=> 2,4-diacetamido-2,4,6-trideoxy-alpha-D-mannopyranose + UDP + H+ 3.2.1.184 UDP-N,N'-diacetylbacillosamine 2-epimerase (hydrolysing)

UDP-glucuronate <=> UDP-D-galacturonate 5.1.3.6 UDP-glucuronate 4-epimerase

H+ + alpha-D-glucose_1-phosphate + ATP <=> ADP-glucose + diphosphate 2.7.7.24 glucose-1-phosphate thymidylyltransferase
2.7.7.27 glucose-1-phosphate adenylyltransferase
2.7.7.9 UTP---glucose-1-phosphate uridylyltransferase



protein_Npi-phospho-L-histidine + D-glucose <=> protein_L-histidine + alpha-D-glucose_6-phosphate 2.7.1.199 protein-Npi-phosphohistidine---D-glucose phosphotransferase

UDP-4-deoxy-4-formamido-beta-L-arabinopyranose + undecaprenyl_phosphate <=> 4-deoxy-4-formamido-alpha-L-arabinopyranosyl_ditrans,octacis-undecaprenyl_phosphate + UDP 2.4.2.53 undecaprenyl-phosphate 4-deoxy-4-formamido-L-arabinose transferase

N-acetylmuramate_6-phosphate + H2O <=> N-acetyl-D-glucosamine_6-phosphate + D-lactate 4.2.1.126 N-acetylmuramic acid 6-phosphate etherase

N-acetylneuraminate + 2 ferricytochrome_b5 + O2 + 2 H+ <=> N-glycolylneuraminate + 2 ferricytochrome_b5 + H2O 1.14.18.2 CMP-N-acetylneuraminate monooxygenase

N-acetyl-D-mannosamine_6-phosphate + phosphoenolpyruvate + H2O <=> N-acetylneuraminate_9-phosphate + phosphate 2.5.1.56 N-acetylneuraminate synthase
2.5.1.57 N-acylneuraminate-9-phosphate synthase


GDP + alpha-D-mannose_1-phosphate + H+ <=> phosphate + GDP-mannose 2.7.7.22 mannose-1-phosphate guanylyltransferase (GDP)
2.7.7.37 aldose-1-phosphate nucleotidyltransferase
2.7.7.69 GDP-L-galactose phosphorylase



N-acetylmuramic_acid + protein_Npi-phospho-L-histidine <=> N-Acetylmuramic_acid_6-phosphate + protein_L-histidine 2.7.1.192 protein-Npi-phosphohistidine---N-acetylmuramate phosphotransferase

alpha-D-mannose_1-phosphate <=> D-mannose_6-phosphate 5.4.2.10 phosphoglucosamine mutase
5.4.2.2 phosphoglucomutase (alpha-D-glucose-1,6-bisphosphate-dependent)
5.4.2.8 phosphomannomutase



UDP-glucose <=> UDP-galactose 5.1.3.16 UDP-glucosamine 4-epimerase
5.1.3.2 UDP-glucose 4-epimerase
5.1.3.7 UDP-N-acetylglucosamine 4-epimerase



D-glucose_6-phosphate <=> alpha-D-glucosamine_1-phosphate 5.4.2.10 phosphoglucosamine mutase
5.4.2.13 phosphogalactosamine mutase
5.4.2.2 phosphoglucomutase (alpha-D-glucose-1,6-bisphosphate-dependent)
5.4.2.3 phosphoacetylglucosamine mutase
5.4.2.8 phosphomannomutase





alpha-D-glucose_1-phosphate <=> alpha-D-glucose_6-phosphate 5.4.2.10 phosphoglucosamine mutase
5.4.2.2 phosphoglucomutase (alpha-D-glucose-1,6-bisphosphate-dependent)
5.4.2.3 phosphoacetylglucosamine mutase
5.4.2.5 phosphoglucomutase (glucose-cofactor)
5.4.2.6 beta-phosphoglucomutase
5.4.2.8 phosphomannomutase






GDP-mannose <=> GDP-beta-L-gulose 5.1.3.18 GDP-mannose 3,5-epimerase

CDP-4-dehydro-3,6-dideoxy-D-glucose_epimer + NADH + H+ <=> CDP-ascarylose + NAD+ 1.1.1
1.1.1.M47


UDP-N-acetyl-D-glucosamine + H2O <=> N-acetyl-D-mannosamine + UDP 3.2.1.183 UDP-N-acetylglucosamine 2-epimerase (hydrolysing)
5.1.3.14 UDP-N-acetylglucosamine 2-epimerase (non-hydrolysing)


4-deoxy-4-formamido-alpha-L-arabinopyranosyl_ditrans,octacis-undecaprenyl_phosphate + H2O <=> 4-amino-4-deoxy-alpha-L-arabinopyranosyl_undecaprenyl_phosphate + formate 3.5.1

phosphoenolpyruvate + N-acetyl-D-mannosamine + H2O <=> phosphate + N-acetylneuraminate 2.5.1.56 N-acetylneuraminate synthase

D-xylose + xylan <=> xylan + H2O 3.2.1.37 xylan 1,4-beta-xylosidase

UDP-galactose + NAD+ + H2O <=> UDP-D-galacturonate + NADH 1.1.1
1.1.1.22 UDP-glucose 6-dehydrogenase


D-galacturonate + ATP <=> H+ + 1-phospho-alpha-D-galacturonate + ADP 2.7.1.44 galacturonokinase
2.7.1.6 galactokinase


Polyphosphate + alpha-D-glucose <=> Polyphosphate + alpha-D-glucose_6-phosphate 2.7.1.63 polyphosphate---glucose phosphotransferase

n UDP-D-galacturonate <=> n UDP + Pectin 2.4.1.43 polygalacturonate 4-alpha-galacturonosyltransferase

1,5-alpha-L-arabinan + H2O <=> 1,5-alpha-L-arabinan + L-arabinose 3.2.1.55 non-reducing end alpha-L-arabinofuranosidase

N-acetylneuraminate <=> N-acetyl-D-mannosamine + pyruvate 4.1.3.3 N-acetylneuraminate lyase

UDP-N-acetylmuramate + NAD+ <=> UDP-N-acetyl-3-O-(1-carboxyvinyl)-D-glucosamine + NADH + H+ 1.3.1.98 UDP-N-acetylmuramate dehydrogenase

CDP-3,6-dideoxy-D-glucose <=> CDP-3,6-dideoxy-D-mannose 5.1.3.10 CDP-paratose 2-epimerase

N-acetyl-D-glucosamine + ATP <=> N-acetyl-D-glucosamine_1-phosphate + ADP + H+ 2.7.1
2.7.1.162 N-acetylhexosamine 1-kinase
2.7.1.221 N-acetylmuramate 1-kinase



GDP-mannose <=> GDP-beta-L-galactose 5.1.3.18 GDP-mannose 3,5-epimerase

H+ + alpha-D-glucose_1-phosphate + GTP <=> GDP-glucose + diphosphate 2.7.7.13 mannose-1-phosphate guanylyltransferase
2.7.7.24 glucose-1-phosphate thymidylyltransferase
2.7.7.28 nucleoside-triphosphate-aldose-1-phosphate nucleotidyltransferase
2.7.7.30 fucose-1-phosphate guanylyltransferase
2.7.7.34 glucose-1-phosphate guanylyltransferase
2.7.7.9 UTP---glucose-1-phosphate uridylyltransferase






UDP-glucose + alpha-D-galactose_1-phosphate <=> UDP-galactose + alpha-D-glucose_1-phosphate 2.7.7.12 UDP-glucose---hexose-1-phosphate uridylyltransferase

H+ + alpha-D-glucose_1-phosphate + CTP <=> CDP-glucose + diphosphate 2.7.7.24 glucose-1-phosphate thymidylyltransferase
2.7.7.33 glucose-1-phosphate cytidylyltransferase
2.7.7.9 UTP---glucose-1-phosphate uridylyltransferase



UDP-2-acetamido-3-amino-2,3-dideoxy-alpha-D-glucuronate + 2-oxoglutarate <=> UDP-2-acetamido-2-deoxy-alpha-D-ribo-hex-3-uluronate + L-glutamate 2.6.1.98 UDP-2-acetamido-2-deoxy-ribo-hexuluronate aminotransferase

UDP-2-acetamido-2-deoxy-alpha-D-glucuronate <=> UDP-N-acetyl-D-galactosaminuronate 5.1.3

beta-D-fructose_6-phosphate + L-glutamine <=> D-glucose_6-phosphate + L-glutamate 2.6.1.16 glutamine---fructose-6-phosphate transaminase (isomerizing)

UDP-4-amino-4-deoxy-beta-L-arabinopyranose + 10-formyltetrahydrofolate <=> UDP-4-deoxy-4-formamido-beta-L-arabinopyranose + tetrahydrofolate + H+ 2.1.2.13 UDP-4-amino-4-deoxy-L-arabinose formyltransferase

CDP-4-dehydro-3,6-dideoxy-alpha-D-glucose <=> CDP-4-dehydro-3,6-dideoxy-D-glucose_epimer 5.1.3
5.1.3.M5


L-arabinopyranose + ATP <=> beta-L-arabinose_1-phosphate + ADP + H+ 2.7.1.46 L-arabinokinase

UDP-glucuronate + H+ <=> UDP-D-xylose + CO2 4.1.1.35 UDP-glucuronate decarboxylase

N-acetylneuraminate_9-phosphate + H2O <=> N-acetylneuraminate + phosphate 3.1.3.103 3-deoxy-D-glycero-D-galacto-nonulopyranosonate 9-phosphatase
3.1.3.29 N-acylneuraminate-9-phosphatase


UDP-2,3-diacetamido-2,3-dideoxy-alpha-D-glucuronate <=> UDP-2,3-diacetamido-2,3-dideoxy-alpha-D-mannuronate 5.1.3.23 UDP-2,3-diacetamido-2,3-dideoxyglucuronic acid 2-epimerase

UDP-2,4-diacetamido-2,4,6-trideoxy-beta-L-altropyranose + H2O <=> H+ + 2,4-diacetamido-2,4,6-trideoxy-beta-L-altropyranose + UDP 3.6.1.57 UDP-2,4-diacetamido-2,4,6-trideoxy-beta-L-altropyranose hydrolase

CDP-3,6-dideoxy-D-glucose + NADP+ <=> CDP-4-dehydro-3,6-dideoxy-alpha-D-glucose + NADPH + H+ 1.1.1.342 CDP-paratose synthase

GDP-6-deoxy-D-talose + NADP+ <=> GDP-4-dehydro-6-deoxy-D-mannose + NADPH + H+ 1.1.1.135 GDP-6-deoxy-D-talose 4-dehydrogenase
1.1.1.187 GDP-4-dehydro-D-rhamnose reductase


D-glucosamine + D-Glucosaminide <=> D-Glucosaminide + H2O 3.2.1.165 exo-1,4-beta-D-glucosaminidase

H+ + 1-phospho-alpha-D-galacturonate + UTP <=> UDP-D-galacturonate + diphosphate 2.7.7
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase


UDP-N-acetyl-D-glucosamine <=> UDP-N-acetyl-D-galactosamine 5.1.3.2 UDP-glucose 4-epimerase
5.1.3.7 UDP-N-acetylglucosamine 4-epimerase


UDP-N-acetyl-D-glucosamine <=> UDP-2-acetamido-2,6-dideoxy-beta-L-arabino-hex-4-ulose + H2O 4.2.1.115 UDP-N-acetylglucosamine 4,6-dehydratase (configuration-inverting)

N-acetyl-D-glucosamine + ATP <=> N-acetyl-D-glucosamine_6-phosphate + H+ + ADP 2.7.1.1 hexokinase
2.7.1.2 glucokinase
2.7.1.59 N-acetylglucosamine kinase



N-acetyl-D-glucosamine_6-phosphate <=> N-acetyl-D-glucosamine_1-phosphate 5.4.2.2 phosphoglucomutase (alpha-D-glucose-1,6-bisphosphate-dependent)
5.4.2.3 phosphoacetylglucosamine mutase
5.4.2.8 phosphomannomutase



UDP-N-acetyl-D-galactosamine + NAD+ + H2O <=> UDP-N-acetyl-D-galactosaminuronate + NADH + H+ 1.1.1
1.1.1.136 UDP-N-acetylglucosamine 6-dehydrogenase


H+ + UDP-glucuronate <=> UDPapiose + CO2 4.1.1

UDP-N-acetyl-D-glucosamine + chitin <=> UDP + chitin 2.4.1.16 chitin synthase

chitin + H2O <=> chitin + N-acetyl-D-glucosamine 3.2.1.14 chitinase
3.2.1.52 beta-N-acetylhexosaminidase


N-acetyl-D-mannosamine <=> N-acetyl-D-glucosamine 5.1.3.8 N-acylglucosamine 2-epimerase

H+ + beta-L-arabinose_1-phosphate + UTP <=> UDP-beta-L-arabinopyranose + diphosphate 2.7.7.37 aldose-1-phosphate nucleotidyltransferase
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase


D-fructose + ATP <=> H+ + beta-D-fructose_6-phosphate + ADP 2.7.1.1 hexokinase
2.7.1.15 ribokinase
2.7.1.2 glucokinase
2.7.1.4 fructokinase




2,4-diacetamido-2,4,6-trideoxy-alpha-D-mannopyranose + phosphoenolpyruvate + H2O <=> N,N'-diacetyllegionaminate + phosphate 2.5.1.101 N,N'-diacetyllegionaminate synthase

ferricytochrome_b5 + NADH <=> ferricytochrome_b5 + NAD+ + H+ 1.6.2.2 cytochrome-b5 reductase
1.6.2.6 leghemoglobin reductase
1.6.5.4 monodehydroascorbate reductase (NADH)
1.8.1.4 dihydrolipoyl dehydrogenase




protein_Npi-phospho-L-histidine + N-acetyl-D-glucosamine <=> protein_L-histidine + N-acetyl-D-glucosamine_6-phosphate 2.7.1.193 protein-Npi-phosphohistidine---N-acetyl-D-glucosamine phosphotransferase

CDP-4-dehydro-3,6-dideoxy-alpha-D-glucose + NADP+ + H2O <=> CDP-4-dehydro-6-deoxy-D-glucose + NADPH + H+ 1.17.1.1 CDP-4-dehydro-6-deoxyglucose reductase

CDP-glucose <=> H2O + CDP-4-dehydro-6-deoxy-D-glucose 4.2.1.45 CDP-glucose 4,6-dehydratase

H+ + alpha-D-galactose_1-phosphate + UTP <=> UDP-galactose + diphosphate 2.7.7.10 UTP---hexose-1-phosphate uridylyltransferase
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase
2.7.7.9 UTP---glucose-1-phosphate uridylyltransferase



D-glucose_6-phosphate + acetyl-CoA <=> N-acetyl-D-glucosamine_6-phosphate + H+ + CoA 2.3.1.4 glucosamine-phosphate N-acetyltransferase

D-glucuronate + ATP <=> alpha-D-glucuronic_acid_1-phosphate + ADP + H+ 2.7.1.43 glucuronokinase

UDP-4-amino-4,6-dideoxy-N-acetyl-alpha-D-glucosamine + 2-oxoglutarate <=> UDP-2-acetamido-2,6-dideoxy-alpha-D-xylo-4-hexulose + L-glutamate 2.6.1.34 UDP-N-acetylbacillosamine transaminase

N-acetyl-D-mannosamine + ATP <=> H+ + N-acetyl-D-mannosamine_6-phosphate + ADP 2.7.1.2 glucokinase
2.7.1.59 N-acetylglucosamine kinase
2.7.1.60 N-acylmannosamine kinase



H+ + alpha-D-glucuronic_acid_1-phosphate + UTP <=> UDP-glucuronate + diphosphate 2.7.7.44 glucuronate-1-phosphate uridylyltransferase
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase


UDP-N-acetyl-D-glucosamine + phosphoenolpyruvate <=> UDP-N-acetyl-3-O-(1-carboxyvinyl)-D-glucosamine + phosphate 2.5.1.7 UDP-N-acetylglucosamine 1-carboxyvinyltransferase

CTP + N-glycolylneuraminate <=> diphosphate + CMP-N-glycoloylneuraminate 2.7.7.43 N-acylneuraminate cytidylyltransferase
2.7.7.92 3-deoxy-D-glycero-D-galacto-nonulopyranosonate cytidylyltransferase


D-glucosamine + acetyl-CoA <=> CoA + N-acetyl-D-glucosamine + H+ 2.3.1.3 glucosamine N-acetyltransferase

H2O + N-acetyl-D-glucosamine <=> D-glucosamine + acetate 3.5.1.103 N-acetyl-1-D-myo-inositol-2-amino-2-deoxy-alpha-D-glucopyranoside deacetylase
3.5.1.25 N-acetylglucosamine-6-phosphate deacetylase
3.5.1.33 N-acetylglucosamine deacetylase



chitin + H2O <=> chitosan + acetate 3.5.1.104 peptidoglycan-N-acetylglucosamine deacetylase
3.5.1.41 chitin deacetylase


L-fucose + ATP <=> L-fucose_1-phosphate + ADP + H+ 2.7.1.52 fucokinase

UDP-galactose <=> UDP-alpha-D-galactofuranose 5.4.99.9 UDP-galactopyranose mutase

N,N''-diacetylchitobiose + H2O <=> N-acetyl-D-glucosamine 3.2.1.14 chitinase
3.2.1.169 protein O-GlcNAcase
3.2.1.21 beta-glucosidase
3.2.1.52 beta-N-acetylhexosaminidase
3.5.1.41 chitin deacetylase





GDP-mannose + NAD+ + H2O <=> H+ + GDP-D-mannuronate + NADH 1.1.1.132 GDP-mannose 6-dehydrogenase

UDP-beta-L-arabinofuranose <=> UDP-beta-L-arabinopyranose 5.4.99.30 UDP-arabinopyranose mutase
5.4.99.9 UDP-galactopyranose mutase


UDP-4-amino-4,6-dideoxy-N-acetyl-beta-L-altrosamine + acetyl-CoA <=> H+ + UDP-2,4-diacetamido-2,4,6-trideoxy-beta-L-altropyranose + CoA 2.3.1.202 UDP-4-amino-4,6-dideoxy-N-acetyl-beta-L-altrosamine N-acetyltransferase

GDP-L-fucose + NADP+ <=> GDP-4-dehydro-6-deoxy-D-mannose + NADPH + H+ 1.1.1.271 GDP-L-fucose synthase

acetyl-CoA + GDP-4-amino-4,6-dideoxy-alpha-D-mannose <=> CoA + GDP-4-acetamido-4,6-dideoxy-alpha-D-mannose + H+ 2.3.1.227 GDP-perosamine N-acetyltransferase

ATP + alpha-D-glucose <=> ADP + alpha-D-glucose_6-phosphate 2.7.1.1 hexokinase
2.7.1.2 glucokinase


CDP-abequose + NADP+ <=> CDP-4-dehydro-3,6-dideoxy-alpha-D-glucose + NADPH + H+ 1.1.1.341 CDP-abequose synthase
4.2.1


GDP-6-deoxy-D-mannose + NADP+ <=> GDP-4-dehydro-6-deoxy-D-mannose + NADPH + H+ 1.1.1.187 GDP-4-dehydro-D-rhamnose reductase
1.1.1.281 GDP-4-dehydro-6-deoxy-D-mannose reductase


UDP-D-xylose + xylan <=> UDP + (1,4-beta-D-xylan)n+1 2.4.2.24 1,4-beta-D-xylan synthase

UDP-glucose <=> H2O + UDP-4-dehydro-6-deoxy-D-glucose 4.2.1.46 dTDP-glucose 4,6-dehydratase
4.2.1.76 UDP-glucose 4,6-dehydratase


GDP-6-deoxy-D-talose + NAD+ <=> GDP-4-dehydro-6-deoxy-D-mannose + NADH + H+ 1.1.1.135 GDP-6-deoxy-D-talose 4-dehydrogenase
1.1.1.187 GDP-4-dehydro-D-rhamnose reductase


UDP-4-keto-rhamnose + NADPH + H+ <=> UDP-L-rhamnose + NADP+ 1.1.1

CDP-4-dehydro-3,6-dideoxy-D-glucose_epimer + NADPH + H+ <=> CDP-ascarylose + NADP+ 1.1.1
1.1.1.M47


N-acetylneuraminate + CTP <=> CMP-N-acetylneuraminate + diphosphate 2.7.7.43 N-acylneuraminate cytidylyltransferase
2.7.7.92 3-deoxy-D-glycero-D-galacto-nonulopyranosonate cytidylyltransferase


D-glucosamine + ATP <=> D-glucose_6-phosphate + ADP + H+ 2.7.1.1 hexokinase
2.7.1.2 glucokinase
2.7.1.8 glucosamine kinase



N-acetyl-D-mannosamine_6-phosphate <=> N-acetyl-D-glucosamine_6-phosphate 5.1.3.9 N-acylglucosamine-6-phosphate 2-epimerase

chitin + H2O <=> chitobiose + chitin 3.2.1.14 chitinase

NADP+ + UDP-N-acetylmuramate <=> H+ + NADPH + UDP-N-acetyl-3-O-(1-carboxyvinyl)-D-glucosamine 1.3.1.98 UDP-N-acetylmuramate dehydrogenase

acetyl-CoA + alpha-D-glucosamine_1-phosphate <=> N-acetyl-D-glucosamine_1-phosphate + CoA + H+ 2.3.1.157 glucosamine-1-phosphate N-acetyltransferase

CTP + N,N'-diacetyllegionaminate <=> CMP-N,N''-diacetyllegionaminate + diphosphate 2.7.7.82 CMP-N,N'-diacetyllegionaminic acid synthase

GDP-4-amino-4,6-dideoxy-alpha-D-mannose + 2-oxoglutarate <=> GDP-4-dehydro-6-deoxy-D-mannose + L-glutamate 2.6.1.102 GDP-perosamine synthase

UDP-4-amino-4,6-dideoxy-N-acetyl-alpha-D-glucosamine + acetyl-CoA <=> UDP-N,N''-diacetylbacillosamine + CoA + H+ 2.3.1.203 UDP-N-acetylbacillosamine N-acetyltransferase

N-acetylmuramic_acid + ATP <=> N-acetylmuramic_acid_1-phosphate + ADP + H+ 2.7.1.221 N-acetylmuramate 1-kinase

UTP + N-acetylmuramic_acid_1-phosphate <=> UDP-N-acetylmuramate + diphosphate 2.7.7.99 N-acetyl-alpha-D-muramate 1-phosphate uridylyltransferase

N-acetyl-D-glucosamine_6-phosphate + H2O <=> D-glucose_6-phosphate + acetate 3.5.1.25 N-acetylglucosamine-6-phosphate deacetylase

UDP-4-dehydro-6-deoxy-D-glucose <=> UDP-4-keto-rhamnose 1.1.1
5.1.3


UDP-N-acetyl-D-glucosamine + NAD+ + H2O <=> UDP-2-acetamido-2-deoxy-alpha-D-glucuronate + NADH + H+ 1.1.1.136 UDP-N-acetylglucosamine 6-dehydrogenase

H+ + alpha-D-mannose_1-phosphate + GTP <=> GDP-mannose + diphosphate 2.7.7.13 mannose-1-phosphate guanylyltransferase
2.7.7.28 nucleoside-triphosphate-aldose-1-phosphate nucleotidyltransferase
2.7.7.30 fucose-1-phosphate guanylyltransferase
2.7.7.34 glucose-1-phosphate guanylyltransferase




GDP-6-deoxy-D-mannose + NAD+ <=> GDP-4-dehydro-6-deoxy-D-mannose + NADH + H+ 1.1.1.187 GDP-4-dehydro-D-rhamnose reductase
1.1.1.281 GDP-4-dehydro-6-deoxy-D-mannose reductase


5,7-bis(acetylamino)-3,5,7,9-tetradeoxy-L-glycero-alpha-L-manno-2-nonulopyranosonic_acid + CTP <=> CMP-5,7-diacetamido-3,5,7,9-tetradeoxy-L-glycero-alpha-L-manno-2-nonulopyranosonic_acid + diphosphate 2.7.7.81 pseudaminic acid cytidylyltransferase

alpha-D-glucose_1-phosphate + UTP + H+ <=> UDP-glucose + diphosphate 2.7.7.23 UDP-N-acetylglucosamine diphosphorylase
2.7.7.24 glucose-1-phosphate thymidylyltransferase
2.7.7.28 nucleoside-triphosphate-aldose-1-phosphate nucleotidyltransferase
2.7.7.33 glucose-1-phosphate cytidylyltransferase
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase
2.7.7.9 UTP---glucose-1-phosphate uridylyltransferase






phosphoenolpyruvate + 2,4-diacetamido-2,4,6-trideoxy-beta-L-altropyranose + H2O <=> 5,7-bis(acetylamino)-3,5,7,9-tetradeoxy-L-glycero-alpha-L-manno-2-nonulopyranosonic_acid + phosphate 2.5.1.97 pseudaminic acid synthase

protein_Npi-phospho-L-histidine + D-mannose <=> protein_L-histidine + D-mannose_6-phosphate 2.7.1.191 protein-Npi-phosphohistidine---D-mannose phosphotransferase

UDP-2-acetamido-2-deoxy-alpha-D-glucuronate + NAD+ <=> UDP-2-acetamido-2-deoxy-alpha-D-ribo-hex-3-uluronate + NADH + H+ 1.1.1.335 UDP-N-acetyl-2-amino-2-deoxyglucuronate dehydrogenase

D-glucose_6-phosphate + H2O <=> D-fructose_6-phosphate + NH3 3.5.99.6 glucosamine-6-phosphate deaminase

UDP-glucuronate + NAD+ <=> UDP-beta-L-threo-pentapyranos-4-ulose + CO2 + NADH 1.1.1.305 UDP-glucuronic acid dehydrogenase (UDP-4-keto-hexauronic acid decarboxylating)

D-galactose + ATP <=> H+ + alpha-D-galactose_1-phosphate + ADP 2.7.1.157 N-acetylgalactosamine kinase
2.7.1.162 N-acetylhexosamine 1-kinase
2.7.1.6 galactokinase



UDP-beta-L-arabinofuranose + 1,5-alpha-L-arabinan <=> 1,5-alpha-L-arabinan + UDP not assigned

UTP + N-acetyl-D-glucosamine_1-phosphate + H+ <=> UDP-N-acetyl-D-glucosamine + diphosphate 2.3.1.157 glucosamine-1-phosphate N-acetyltransferase
2.7.7.23 UDP-N-acetylglucosamine diphosphorylase
2.7.7.64 UTP-monosaccharide-1-phosphate uridylyltransferase
2.7.7.83 UDP-N-acetylgalactosamine diphosphorylase




chitosan + H2O <=> D-Glucosaminide + chitosan 3.2.1.132 chitosanase

UDP-sulfoquinovose + H2O <=> UDP-glucose + sulfite + H+ 3.13.1.1 UDP-sulfoquinovose synthase

L-fucose_1-phosphate + GTP + H+ <=> GDP-L-fucose + diphosphate 2.7.7.30 fucose-1-phosphate guanylyltransferase

UDP-N-acetyl-D-glucosamine <=> UDP-N-acetylmannosamine 5.1.3.14 UDP-N-acetylglucosamine 2-epimerase (non-hydrolysing)

protein_Npi-phospho-L-histidine + D-glucosamine <=> protein_L-histidine + D-glucose_6-phosphate 2.7.1

UDP-4-amino-4-deoxy-beta-L-arabinopyranose + 2-oxoglutarate <=> UDP-beta-L-threo-pentapyranos-4-ulose + L-glutamate 2.6.1.87 UDP-4-amino-4-deoxy-L-arabinose aminotransferase
2.6.1.92 UDP-4-amino-4,6-dideoxy-N-acetyl-beta-L-altrosamine transaminase


D-mannose_6-phosphate <=> beta-D-fructose_6-phosphate 5.3.1.8 mannose-6-phosphate isomerase
5.3.1.9 glucose-6-phosphate isomerase


Visualization of the pathway