|
|
(3R)-3-hydroxyglutaryl-[acp]_methyl_ester + NADP+ <=> 3-Ketoglutaryl-[acp]_methyl_ester + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
MetaCyc:
RXN-11476
|
|
|
|
pimelyl-[acyl-carrier_protein]_methyl_ester + NAD+ <=> Enoylpimeloyl-[acp]_methyl_ester + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-11482
|
|
|
|
3-Hydroxypimeloyl-[acp]_methyl_ester + NADP+ <=> 3-Ketopimeloyl-[acp]_methyl_ester + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
|
–
|
|
KEGG:
R10120
MetaCyc:
RXN-11480
|
|
|
|
Glutaryl-[acp]_methyl_ester + malonyl-[acyl-carrier_protein] + H+ <=> 3-Ketopimeloyl-[acp]_methyl_ester + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
|
KEGG:
R10119
MetaCyc:
RXN-11479
|
|
|
|
3-Hydroxypimeloyl-[acp]_methyl_ester <=> Enoylpimeloyl-[acp]_methyl_ester + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
KEGG:
R10121
MetaCyc:
RXN-11481
|
|
|
|
S-adenosyl-L-methionine + malonyl-[acyl-carrier_protein] <=> malonyl-[acyl-carrier_protein]_methyl_ester + S-adenosyl-L-homocysteine
|
2.1.1.197
malonyl-[acyl-carrier protein] O-methyltransferase
|
–
|
|
BRENDA:
BR49387
KEGG:
R09543
MetaCyc:
RXN-11475
|
|
|
|
(3R)-3-hydroxyglutaryl-[acp]_methyl_ester <=> (2E)-enoylglutaryl-[acp]_methyl_ester + H2O
|
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
|
|
MetaCyc:
RXN-11477
|
|
|
|
Glutaryl-[acp]_methyl_ester + NAD+ <=> (2E)-enoylglutaryl-[acp]_methyl_ester + NADH + H+
|
1.3.1.9
enoyl-[acyl-carrier-protein] reductase (NADH)
|
–
|
|
MetaCyc:
RXN-11478
|
|
|
|
malonyl-[acyl-carrier_protein]_methyl_ester + malonyl-[acyl-carrier_protein] + H+ <=> 3-Ketoglutaryl-[acp]_methyl_ester + CO2 + [acyl-carrier_protein]
|
2.3.1.179
beta-ketoacyl-[acyl-carrier-protein] synthase II
2.3.1.41
beta-ketoacyl-[acyl-carrier-protein] synthase I
|
–
–
|
|
KEGG:
R10115
MetaCyc:
RXN-11474
|
|
|
|
pimeloyl-[acyl-carrier_protein] + L-alanine + H+ <=> (8S)-8-amino-7-oxononanoate + CO2 + [acyl-carrier_protein]
|
2.3.1.47
8-amino-7-oxononanoate synthase
|
–
|
|
BRENDA:
BR44048
KEGG:
R10124
MetaCyc:
RXN-11484
|
|
|
|
pimelyl-[acyl-carrier_protein]_methyl_ester + H2O <=> pimeloyl-[acyl-carrier_protein] + methanol + H+
|
3.1.1.85
pimelyl-[acyl-carrier protein] methyl ester esterase
|
–
|
|
BRENDA:
BR49618
KEGG:
R09725
MetaCyc:
RXN-11483
|
|