|
|
3-[(Z)-2-isocyanoethenyl]-1H-indole + geranyl_diphosphate <=> 3-geranyl-3-[(Z)-2-isocyanoethenyl]-1H-indole + diphosphate
|
2.5.1.146
3-geranyl-3-[(Z)-2-isocyanoethenyl]indole synthase
|
–
|
| |
BRENDA:
BR52418
KEGG:
R12089
MetaCyc:
RXN-19272
|
|
|
|
3-geranyl-3-[(Z)-2-isocyanoethenyl]-1H-indole <=> 12-epi-fischerindole_U
|
5.5.1.33
12-epi-fischerindole U synthase
|
–
|
| |
BRENDA:
BR52376
KEGG:
R12006
MetaCyc:
RXN-19282
|
|
|
|
12-epi-fischerindole_U + 2-oxoglutarate + O2 + Cl- + H+ <=> 12-epi-fischerindole_G + succinate + CO2 + H2O
|
1.14.20.14
hapalindole-type alkaloid chlorinase
|
–
|
| |
BRENDA:
BR52472
KEGG:
R12166
MetaCyc:
RXN-19283
|
|
|
|
(2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + 2-oxoglutarate + O2 + H+ <=> 3-[(Z)-2-isocyanoethenyl]-1H-indole + succinate + CO2 + H2O
|
1.14.20.11
3-[(Z)-2-isocyanoethenyl]-1H-indole synthase
|
–
|
| |
BRENDA:
BR52405
KEGG:
R12082
MetaCyc:
RXN-19268
|
|
|
|
L-tryptophan + D-ribulose_5-phosphate <=> (2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate + Hydroxyacetone + phosphate + formaldehyde + H2O + H+
|
4.1.99.25
L-tryptophan isonitrile synthase
|
–
|
| |
BRENDA:
BR52464
KEGG:
R12151
MetaCyc:
RXN-19264
|
|
