|
|
(3R,4R)-3-(6-hydroxy-1,3-benzodioxol-5-yl)-3,4-dihydro-2H-chromene-4,7-diol + NADP+ <=> (3R)2',7-dihydroxy-dihydro-4',5'-methylenedioxyisoflavone + NADPH + H+
|
1.1.1.348
(3R)-2'-hydroxyisoflavanone reductase
|
–
|
| |
MetaCyc:
RXN-3768
|
|
|
|
(3R)2',7-dihydroxy-dihydro-4',5'-methylenedioxyisoflavone + NADP+ <=> 2''-hydroxypseudobaptigenin + NADPH + H+
|
1.3.1.45
2'-hydroxyisoflavone reductase
|
–
|
| |
BRENDA:
BS258567
KEGG:
R07751
MetaCyc:
RXN-3766
|
|
|
|
(3R,4R)-3-(6-hydroxy-1,3-benzodioxol-5-yl)-3,4-dihydro-2H-chromene-4,7-diol <=> (-)-maackiain + H2O
|
4.2.1.139
pterocarpan synthase
|
–
|
| |
MetaCyc:
RXN-13700
|
|
|
|
formononetin + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Calycosin + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
| |
MetaCyc:
RXN-3762
|
|
|
|
pseudobaptigenin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 2''-hydroxypseudobaptigenin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.89
4'-methoxyisoflavone 2'-hydroxylase
|
–
|
| |
MetaCyc:
RXN-3765
|
|
|
|
Calycosin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> pseudobaptigenin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.63
pseudobaptigenin synthase
|
–
|
| |
MetaCyc:
RXN-3763
|
|
